Preparation of C@ZrSiO4 Black Pigment by Walnut Shell Powder as Carbon Source

Abstract

Abstract: Zirconium silicate encapsulated carbon (C@ZrSiO₄) black pigment was prepared by sol-precipitation method, using walnut shell powder, zirconium oxychloride (ZrOCl₂·8H₂O) and ethyl silicate (TEOS), etc. as raw materials. The heat effect, chemical structure, phase composition and microstructure of samples were investigated by TG-DSC, FT-IR, XRD, SEM and TEM.The effects of different heat treatment temperatures and mass ratios of walnut shell powder/ZrSiO₄(theoretical synthesis, the same below) on the phase composition and chromaticity value of pigment were studied. The results show that the C@ZrSiO₄ pigment with excellent coloring performance (L^*=31.3, a^*=+1.4 and b^*=+1.3) can be obtained when heat treatment temperature is 1 100 ℃, and the mass ratio of walnut shell powder/ZrSiO₄ is 1:3. When 5% (mass fraction) C@ZrSiO₄ is added to transparent glaze under firing temperature of 1 200 ℃, the black glaze exhibits excellent coloring performance with the color value of L^*=41.2, a^*=+1.2 and b^*=+1.7.

Key words: walnut shell powder, sol-precipitation method, C@ZrSiO₄ pigment, phase composition, microstructure, chromatic performance

CLC Number:

TQ174.4

WANG Jiwei, LI Jiake, LIU Xin, JIANG Hedong, GUO Pingchun, ZHU Hua, WANG Yanxiang. Preparation of C@ZrSiO₄ Black Pigment by Walnut Shell Powder as Carbon Source[J]. BULLETIN OF THE CHINESE CERAMIC SOCIETY, 2023, 42(2): 657-665.

References

[1] 张翔, 李治桥, 马国军, 等. 尖晶石型无钴黑色陶瓷颜料的研究进展[J]. 硅酸盐通报, 2021, 40(4): 1318-1329.
ZHANG X, LI Z Q, MA G J, et al. Research progress of spinel-type cobalt-free black ceramic pigments[J]. Bulletin of the Chinese Ceramic Society, 2021, 40(4): 1318-1329 (in Chinese).
[2] 李治桥, 张翔, 马国军, 等. Fe-Cr-Ni-Mn系黑色陶瓷颜料的制备及呈色性能分析[J]. 硅酸盐通报, 2021, 40(12): 4092-4101.
LI Z Q, ZHANG X, MA G J, et al. Preparation and coloring performance analysis of Fe-Cr-Ni-Mn system black ceramic pigment[J]. Bulletin of the Chinese Ceramic Society, 2021, 40(12): 4092-4101 (in Chinese).
[3] CALBO J, SORLÍ S, LLUSAR M, et al. Minimisation of toxicity in nickel ferrite black pigment[J]. British Ceramic Transactions, 2004, 103(1): 3-9.
[4] 杨兴卫, 杨茂立, 彭珑, 等. 核桃壳炭质燃料的性能及热解过程研究[J]. 工业加热, 2018, 47(3): 1-4+22.
YANG X W, YANG M L, PENG L, et al. Study on the pyrolysis process and properties of fuel walnut shells carbonaceous fuel[J]. Industrial Heating, 2018, 47(3): 1-4+22 (in Chinese).
[5] CHEN S L, CHENG M T, LANG Y, et al. Synthesis and chromatic properties of zircon encapsulated ceramic black pigment with carbon sphere as carbon source[J]. Journal of the European Ceramic Society, 2018, 38(4): 2218-2227.
[6] ZHANG X J, CHEN T, JIANG W H, et al. Facile synthesis of tunable polymer spheres for encapsulation pigment application[J]. Materials Letters, 2018, 216: 63-66.
[7] CHEN T, ZHANG X, JIANG W, et al. Synthesis and application of C@ZrSiO₄, inclusion ceramic pigment from cotton cellulose as a colorant[J]. Journal of the European Ceramic Society, 2016, 36(7): 1811-1820.
[8] 徐明, 邱木清. 核桃壳生物炭吸附水中铀的研究[J]. 安徽农业科学, 2021, 49(7): 70-73.
XU M, QIU M Q. Study on adsorption of U(Ⅵ) in water by walnut shell biochar[J]. Journal of Anhui Agricultural Sciences, 2021, 49(7): 70-73 (in Chinese).
[9] CHEN D Y, CHEN X J, SUN J, et al. Pyrolysis polygeneration of pine nut shell: quality of pyrolysis products and study on the preparation of activated carbon from biochar[J]. Bioresource Technology, 2016, 216: 629-636.
[10] 杨莉, 付婧, 文子伟, 等. 6种低温生物质炭的制备及结构表征[J]. 吉林农业大学学报, 2021, 43(5): 565-573.
YANG L, FU J, WEN Z W, et al. Preparation and structure characterization of six kinds of low temperature biochar[J]. Journal of Jilin Agricultural University, 2021, 43(5): 565-573 (in Chinese).
[11] CHEN T, ZHANG X J, JIANG W H, et al. Preparation of plant derived carbon and its application for inclusion pigments[J]. Advanced Powder Technology, 2018, 29(12): 3040-3048.
[12] YANG Q H, LI P, ZHANG S B. Low temperature synthesis of green submicro Cr-ZrSiO₄ ceramic pigments by solid-state method[J]. International Journal of Applied Ceramic Technology, 2021, 18(2): 345-352.
[13] SONG K Q, FAN J L, LI W, et al. Effect of ZrO₂ types on ZrSiO₄ formation[J]. Ceramics International, 2019, 45(17): 23444-23450.
[14] 林珈羽, 张越, 刘沅, 等. 控制热分解条件下制备生物炭及其表征[J]. 环境科学与技术, 2016, 39(2): 80-86.
LIN J Y, ZHANG Y, LIU Y, et al. Preparation and characterization of biochar under the controlling conditions of pyrolysis[J]. Environmental Science & Technology, 2016, 39(2): 80-86 (in Chinese).
[15] KONGWUDTHITI S, PRASERTHDAM P, TANAKULRUNGSANK W, et al. The influence of Si-O-Zr bonds on the crystal-growth inhibition of zirconia prepared by the glycothermal method[J]. Journal of Materials Processing Technology, 2003, 136(1/2/3): 186-189.
[16] CHEN S L, FU S Y, LANG Y, et al. Submicronic spherical inclusion black pigment by double-shell reaction sintering[J]. Journal of the American Ceramic Society, 2020, 103(3): 1520-1526.
[17] WANG Y Q, LAI F B, WANG Q K, et al. Synthesis and chromatic properties of high color performance Pr_x-ZrSiO₄ (x=0~0. 1) yellow pigment[J]. Journal of Alloys and Compounds, 2022, 891: 161932.
[18] AFZAL R A, PENNELLS J, YAMAUCHI Y, et al. Lignocellulosic plant cell wall variation influences the structure and properties of hard carbon derived from sorghum biomass[J]. Carbon Trends, 2022, 7: 100168.
[19] LEI B L, QIN W, KANG G L, et al. Modeling and evaluation for encapsulation efficiency of zircon-based heteromorphic encapsulation pigments[J]. Dyes and Pigments, 2015, 112: 245-254.
[20] BUAH W K, WILLIAMS P T. Granular activated carbons from palm nut shells for gold di-cyanide adsorption[J]. International Journal of Minerals, Metallurgy, and Materials, 2013, 20(2): 172-179.
[21] LENG J F, REN B H, ZHOU Q B, et al. Effect of Sc and Zr on recrystallization behavior of 7075 aluminum alloy[J]. Transactions of Nonferrous Metals Society of China, 2021, 31(9): 2545-2557.

Preparation of C@ZrSiO₄ Black Pigment by Walnut Shell Powder as Carbon Source

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