Research Progress on Surface Modification of Basalt Fiber

Abstract

Abstract: The mechanical properties of fiber reinforced composites are mainly affected by fiber properties, resin properties, and composite interface properties between fiber and resin. In practical application, fiber surface modification is the key to strengthen the binding force between fiber and matrix and expand the application field. In this paper, several modification methods of basalt fibers at home and abroad were reviewed. The mechanism and effects of various surface modification methods were summarized, and the properties and applications of basalt fiber were briefly introduced. The results show that the surface activity, strength and interface binding strength of basalt fiber after modification are improved, which is conducive to the preparation of composites with excellent performance, so as to be used in the fields of civil construction, environmental protection, automobile and ship, aerospace and etc. In addition, the main problems existing in the field of basalt fiber modification were pointed out and the future research direction of this field was prospected.

Key words: basalt fiber, surface modification, composite, modification mechanism, performance, application

CLC Number:

TQ343.41

XU Xing, ZHANG Jincai, WANG Baofeng, GUO Yanxia, CHENG Fangqin. Research Progress on Surface Modification of Basalt Fiber[J]. BULLETIN OF THE CHINESE CERAMIC SOCIETY, 2023, 42(2): 575-586.

References

[1] 霍冀川, 雷永林, 王海滨, 等. 玄武岩纤维的制备及其复合材料的研究进展[J]. 材料导报, 2006, 20(s1): 382-385.
HUO J C, LEI Y L, WANG H B, et al. Progress of study on the preparation of basalt fibet and composite material of basalt fiber[J]. Materials Review, 2006, 20(s1): 382-385 (in Chinese).
[2] YAO D W, YIN G Z, BI Q Q, et al. Basalt fiber modified ethylene vinyl acetate/magnesium hydroxide composites with balanced flame retardancy and improved mechanical properties[J]. Polymers, 2020, 12(9): 2107.
[3] LEBEDEV M P, STARTSEV O V, KYCHKIN A K. The effects of aggressive environments on the mechanical properties of basalt plastics[J]. Heliyon, 2020, 6(3): e03481.
[4] 吴智深, 汪昕, 史健喆. 玄武岩纤维复合材料性能提升及其新型结构[J]. 工程力学, 2020, 37(5): 1-14.
WU Z S, WANG X, SHI J Z. Advancement of basalt fiber-reinforced polymers (BFRPs) and the novel structures reinforced with BFRPs[J]. Engineering Mechanics, 2020, 37(5): 1-14 (in Chinese).
[5] ZHENG Y X, ZHANG P, CAI Y C, et al. Cracking resistance and mechanical properties of basalt fibers reinforced cement-stabilized macadam[J]. Composites Part B: Engineering, 2019, 165: 312-334.
[6] CHEN X F, ZHANG Y S, HUO H B, et al. Study of high tensile strength of natural continuous basalt fibers[J]. Journal of Natural Fibers, 2020, 17(2): 214-222.
[7] 刘昶江, 仝晓聪, 刘忠, 等. 玄武岩纤维原料特征分析[J]. 硅酸盐通报, 2020, 39(12): 3858-3865.
LIU C J, TONG X C, LIU Z, et al. Analysis of basalt fiber raw material characteristics[J]. Bulletin of the Chinese Ceramic Society, 2020, 39(12): 3858-3865 (in Chinese).
[8] LIU L, HUANG Y, LIU Z H. Laboratory evaluation of asphalt binder modified with crumb rubber and basalt fiber[J]. Advances in Civil Engineering, 2020, 2020: 1-10.
[9] LIU C J, TONG X C, YANG C C, et al. Preparation and dielectric properties of the amorphous basaltic glass[J]. Silicon, 2022, 14(7): 3623-3628.
[10] 张晓青, 冯静, 王仁舒, 等. 玄武岩纤维的研究进展及应用[J]. 山东化工, 2019, 48(4): 46-47.
ZHANG X Q, FENG J, WANG R S, et al. Research progress and application of basalt fiber[J]. Shandong Chemical Industry, 2019, 48(4): 46-47 (in Chinese).
[11] MITTAL G, RHEE K Y, MIŠKOVIĆ-STANKOVIĆ V, et al. Reinforcements in multi-scale polymer composites: processing, properties, and applications[J]. Composites Part B: Engineering, 2018, 138: 122-139.
[12] MONALDO E, NERILLI F, VAIRO G. Basalt-based fiber-reinforced materials and structural applications in civil engineering[J]. Composite Structures, 2019, 214: 246-263.
[13] SEGHINI M C, TOUCHARD F, SARASINI F, et al. Engineering the interfacial adhesion in basalt/epoxy composites by plasma polymerization[J]. Composites Part A: Applied Science and Manufacturing, 2019, 122: 67-76.
[14] LANDUCCI G, ROSSI F, NICOLELLA C, et al. Design and testing of innovative materials for passive fire protection[J]. Fire Safety Journal, 2009, 44(8): 1103-1109.
[15] 蔺建廷, 胡韬. 玄武岩纤维材料性能及应用[J]. 黑龙江科技信息, 2009(20): 35.
LIN J T, HU T. Properties and application of basalt fiber materials[J]. Heilongjiang Science and Technology Information, 2009(20): 35 (in Chinese).
[16] 丁宝明, 张蕾, 刘嘉麒. 中国玄武岩纤维材料产业的发展态势[J]. 中国矿业, 2019, 28(10): 1-5.
DING B M, ZHANG L, LIU J Q. Development trend of basalt fiber materials industry in China[J]. China Mining Magazine, 2019, 28(10): 1-5 (in Chinese).
[17] 董武斌, 王芳. 不同地区玄武岩品质及路用性能评价[J]. 公路交通技术, 2008, 24(1): 9-11.
DONG W B, WANG F. Evaluation on quality of basalt in different areas and their properties for use on road[J]. Technology of Highway and Transport, 2008, 24(1): 9-11 (in Chinese).
[18] DING L N, LIU Y, LIU J X, et al. Correlation analysis of tensile strength and chemical composition of basalt fiber roving[J]. Polymer Composites, 2019, 40(7): 2959-2966.
[19] LI Z N, SHEN A Q, ZENG G P, et al. Research progress on properties of basalt fiber-reinforced cement concrete[J]. Materials Today Communications, 2022, 33: 104824.
[20] 张玮, 谭艳君, 刘姝瑞, 等. 玄武岩纤维的性能及应用[J]. 纺织科学与工程学报, 2022, 39(1): 85-89.
ZHANG W, TAN Y J, LIU S R, et al. Properties and applications of basalt fiber[J]. Journal of Textile Science and Engineering, 2022, 39(1): 85-89 (in Chinese).
[21] MENG Y, LIU J X, XIA Y, et al. Preparation and characterization of continuous basalt fibre with high tensile strength[J]. Ceramics International, 2021, 47(9): 12410-12415.
[22] 张金才, 王志英, 程芳琴. 固废基无机纤维的研究进展[J]. 材料导报, 2021, 35(7): 7019-7026.
ZHANG J C, WANG Z Y, CHENG F Q. Progress on the study of solid waste based inorganic fibers[J]. Materials Reports, 2021, 35(7): 7019-7026 (in Chinese).
[23] MA Z B, TIAN X Q, LIAO H Q, et al. Improvement of fly ash fusion characteristics by adding metallurgical slag at high temperature for production of continuous fiber[J]. Journal of Cleaner Production, 2018, 171: 464-481.
[24] YANG C C, LIU Z, TONG X C, et al. Effects of raw material homogenization on the structure of basalt melt and performance of fibers[J]. Ceramics International, 2022, 48(9): 11998-12005.
[25] 刘学慧. 连续玄武岩纤维与碳纤维、芳纶、玻璃纤维的对比及其特性概述[J]. 山西科技, 2014, 29(1): 87-90.
LIU X H. Overview of the comparison of CBF (continuous basalt fiber) with CF (carbon fiber), AF (aramid fiber) and GF (glass fiber) and their properties[J]. Shanxi Science and Technology, 2014, 29(1): 87-90 (in Chinese).
[26] ZHANG J C, WEN X H, CHENG F Q. Preparation, thermal stability and mechanical properties of inorganic continuous fibers produced from fly ash and magnesium slag[J]. Waste Management, 2021, 120: 156-163.
[27] HSIEH P Y, KWONG K S, BENNETT J. Correlation between the critical viscosity and ash fusion temperatures of coal gasifier ashes[J]. Fuel Processing Technology, 2016, 142: 13-26.
[28] KONG L X, BAI J, LI W, et al. The internal and external factor on coal ash slag viscosity at high temperatures, Part 2: effect of residual carbon on slag viscosity[J]. Fuel, 2015, 158: 976-982.
[29] LOLJA S A, HAXHI H, DHIMITRI R, et al. Correlation between ash fusion temperatures and chemical composition in Albanian coal ashes[J]. Fuel, 2002, 81(17): 2257-2261.
[30] RAMESH B, ESWARI S. Mechanical behaviour of basalt fibre reinforced concrete: an experimental study[J]. Materials Today: Proceedings, 2021, 43: 2317-2322.
[31] 林希宁, 张凤林, 周玉梅. 玄武岩纤维及其复合材料的研究进展[J]. 玻璃纤维, 2013(2): 39-44.
LIN X N, ZHANG F L, ZHOU Y M. Progress of research on basalt fiber and composites[J]. Fiber Glass, 2013(2): 39-44 (in Chinese).
[32] 韩露. 面向生态车辆的聚乳酸复合材料性能与优化设计方法研究[D]. 长春: 吉林大学, 2020.
HAN L. Research on the properties of polylactic acid composites and optimal design for ecological vehicle[D]. Changchun: Jilin University, 2020 (in Chinese).
[33] 陈兴芬. 连续玄武岩纤维的高强度化研究[D]. 南京: 东南大学, 2018.
CHEN X F. Study on the high strength and performance of continuous basalt fiber[D]. Nanjing: Southeast University, 2018 (in Chinese).
[34] XING D, XI X Y, MA P C. Factors governing the tensile strength of basalt fibre[J]. Composites Part A: Applied Science and Manufacturing, 2019, 119: 127-133.
[35] VARA PRASAD V, TALUPULA S. A review on reinforcement of basalt and aramid (kevlar 129) fibers[J]. Materials Today: Proceedings, 2018, 5(2): 5993-5998.
[36] KHANDELWAL S, RHEE K Y. Recent advances in basalt-fiber-reinforced composites: tailoring the fiber-matrix interface[J]. Composites Part B: Engineering, 2020, 192: 108011.
[37] 于利超. 玄武岩纤维表面处理对其复合材料力学性能的影响[D]. 上海: 东华大学, 2015.
YU L C. Effect of basalt fiber surface treatment on composite performance[D]. Shanghai: Donghua University, 2015 (in Chinese).
[38] CECH V, PRIKRYL R, BALKOVA R, et al. Plasma surface treatment and modification of glass fibers[J]. Composites Part A: Applied Science and Manufacturing, 2002, 33(10): 1367-1372.
[39] WU M J, JIA L X, LU S L, et al. Interfacial performance of high-performance fiber-reinforced composites improved by cold plasma treatment: a review[J]. Surfaces and Interfaces, 2021, 24: 101077.
[40] 周正刚. 高性能有机纤维表面等离子体改性研究[J]. 玻璃钢/复合材料, 2009(1): 77-79+84.
ZHOU Z G. Research on plasma surface modification of organic high-performance fiber[J]. Fiber Reinforced Plastics/Composites, 2009(1): 77-79+84 (in Chinese).
[41] 李琦娴, 杨建忠, 焦海娟. 玄武岩纤维的低温等离子体表面改性研究[J]. 棉纺织技术, 2020, 48(7): 17-20.
LI Q X, YANG J Z, JIAO H J. Study on low temperature plasma surface modification of basalt fiber[J]. Cotton Textile Technology, 2020, 48(7): 17-20 (in Chinese).
[42] 靳婷婷, 申士杰, 李静, 等. 低温等离子处理对玄武岩纤维表面及复合材料性能的影响[J]. 玻璃钢/复合材料, 2015(6): 29-35.
JIN T T, SHEN S J, LI J, et al. Impact on the surface of basalt fiber and composite material properties of low-temperature plasma treatment[J]. Fiber Reinforced Plastics/Composites, 2015(6): 29-35 (in Chinese).
[43] WANG G J, LIU Y W, GUO Y J, et al. Surface modification and characterizations of basalt fibers with non-thermal plasma[J]. Surface and Coatings Technology, 2007, 201(15): 6565-6568.
[44] YU S, OH K H, HONG S H. Enhancement of the mechanical properties of basalt fiber-reinforced polyamide 6, 6 composites by improving interfacial bonding strength through plasma-polymerization[J]. Composites Science and Technology, 2019, 182: 107756.
[45] LILLI M, JURKO M, SIRJOVOVA V, et al. Basalt fibre surface modification via plasma polymerization of tetravinylsilane/oxygen mixtures for improved interfacial adhesion with unsaturated polyester matrix[J]. Materials Chemistry and Physics, 2021, 274: 125106.
[46] LILLI M, ZVONEK M, CECH V, et al. Low temperature plasma polymerization: an effective process to enhance the basalt fibre/matrix interfacial adhesion[J]. Composites Communications, 2021, 27: 100769.
[47] 杨阳. 连续玄武岩纤维表面改性及增强尼龙力学性能研究[D]. 南京: 东南大学, 2019.
YANG Y. Surface modification of continuous basalt fiber and study on mechanical properties of reinforced nylon[D]. Nanjing: Southeast University, 2019 (in Chinese).
[48] LI Z, XIAO T L, PAN Q Y, et al. Corrosion behaviour and mechanism of basalt fibres in acidic and alkaline environments[J]. Corrosion Science, 2016, 110: 15-22.
[49] 李静, 申士杰, 李伟娜, 等. 酸刻蚀对玄武岩纤维表面偶联剂吸附量及纤维/环氧树脂复合材料力学性能的影响[J]. 复合材料学报, 2014, 31(4): 888-894.
LI J, SHEN S J, LI W N, et al. Effects of acid modification on coupling agent amount of basalt fiber surface and mechanical property of BF/epoxy composites[J]. Acta Materiae Compositae Sinica, 2014, 31(4): 888-894 (in Chinese).
[50] 李伟娜. 玄武岩纤维表面酸刻蚀处理对其复合材料性能的影响[D]. 北京: 北京林业大学, 2013.
LI W N. Effect of acid modification on basalt fiber surface used for composites[D]. Beijing: Beijing Forestry University, 2013 (in Chinese).
[51] 邓穆玲, 张扬, 潘大卫, 等. 碱刻蚀玄武岩纤维对地质聚合物基木材胶黏剂胶接性能的影响[J]. 硅酸盐通报, 2021, 40(6): 2062-2069.
DENG M L, ZHANG Y, PAN D W, et al. Effect of basalt fiber by alkali etching on bonding properties of geopolymer-based wood adhesives[J]. Bulletin of the Chinese Ceramic Society, 2021, 40(6): 2062-2069 (in Chinese).
[52] 解玉洁, 张晓颖, 吴智仁, 等. 改性玄武岩纤维制备及其在微生物载体的应用[J]. 合成纤维, 2019, 48(3): 19-22.
XIE Y J, ZHANG X Y, WU Z R, et al. The preparation of modified basalt fiber and its utilization on microorganism carrier media[J]. Synthetic Fiber in China, 2019, 48(3): 19-22 (in Chinese).
[53] NI H C, WANG C C, ARSLAN M, et al. Enhanced wastewater treatment by modified basalt fiber bio-carriers: effect of etching and surface functionalization[J]. Journal of Cleaner Production, 2022, 343: 130927.
[54] VARLEY R J, TIAN W, LEONG K H, et al. The effect of surface treatments on the mechanical properties of basalt-reinforced epoxy composites[J]. Polymer Composites, 2013, 34(3): 320-329.
[55] CHOI S, MAUL S, STEWART A, et al. Effect of silane coupling agent on the durability of epoxy adhesion for structural strengthening applications[J]. Polymer Engineering & Science, 2013, 53(2): 283-294.
[56] XIE Y J, HILL C A S, XIAO Z F, et al. Silane coupling agents used for natural fiber/polymer composites: a review[J]. Composites Part A: Applied Science and Manufacturing, 2010, 41(7): 806-819.
[57] 刘亚兰, 申士杰, 李龙, 等. 偶联剂处理玻璃纤维表面的研究进展[J]. 绝缘材料, 2010, 43(4): 34-39.
LIU Y L, SHEN S J, LI L, et al. The research progress on the treatment of glass fiber surface by coupling agent[J]. Insulating Materials, 2010, 43(4): 34-39 (in Chinese).
[58] 柳力, 刘朝晖, 向宇, 等. 硅烷偶联剂改性玄武岩纤维的机理及其路用性能[J]. 建筑材料学报, 2017, 20(4): 623-629.
LIU L, LIU Z H, XIANG Y, et al. Mechanism and road performance of basalt fiber modified by silane coupling agent[J]. Journal of Building Materials, 2017, 20(4): 623-629 (in Chinese).
[59] 宋秋霞, 刘华武, 钟智丽, 等. 硅烷偶联剂处理对玄武岩单丝拉伸性能的影响[J]. 天津工业大学学报, 2010, 29(1): 19-22.
SONG Q X, LIU H W, ZHONG Z L, et al. Effect of silane coupling agent treatment on tensile properties of single basalt filament[J]. Journal of Tianjin Polytechnic University, 2010, 29(1): 19-22 (in Chinese).
[60] JIA H, LIU C, QIAO Y, et al. Enhanced interfacial and mechanical properties of basalt fiber reinforced poly(aryl ether nitrile ketone) composites by amino-silane coupling agents[J]. Polymer, 2021, 230: 124028.
[61] ARSLAN C, DOGAN M. The effects of silane coupling agents on the mechanical properties of basalt fiber reinforced poly(butylene terephthalate) composites[J]. Composites Part B: Engineering, 2018, 146: 145-154.
[62] VARELIDIS P C, MCCULLOUGH R L, PAPASPYRIDES C D. The effect on the mechanical properties of carbon/epoxy composites of polyamide coatings on the fibers[J]. Composites Science and Technology, 1999, 59(12): 1813-1823.
[63] ZHANG X Y, ZHOU X T, XIE Y J, et al. A sustainable bio-carrier medium for wastewater treatment: modified basalt fiber[J]. Journal of Cleaner Production, 2019, 225: 472-480.
[64] PREDA N, COSTAS A, LILLI M, et al. Functionalization of basalt fibers with ZnO nanostructures by electroless deposition for improving the interfacial adhesion of basalt fibers/epoxy resin composites[J]. Composites Part A: Applied Science and Manufacturing, 2021, 149: 106488.
[65] HAO B, FÖRSTER T, MÄDER E, et al. Modification of basalt fibre using pyrolytic carbon coating for sensing applications[J]. Composites Part A: Applied Science and Manufacturing, 2017, 101: 123-128.
[66] CAI D L, MA P C. Hydrogel-coated basalt fibre with superhydrophilic and underwater superoleophobic performance for oil-water separation[J]. Composites Communications, 2019, 14: 1-6.
[67] WANG Z T, LUO H J, ZHANG J, et al. Water-soluble polysiloxane sizing for improved heat resistance of basalt fiber[J]. Materials Chemistry and Physics, 2021, 272: 125024.
[68] WANG Z T, LUO H J, ZHANG L, et al. Mechanical properties of basalt fiber improved by starch phosphates sizing agent[J]. Applied Surface Science, 2020, 521: 146196.
[69] ZHENG Y, SUN D, FENG Q, et al. Nano-SiO₂ modified basalt fiber for enhancing mechanical properties of oil well cement[J]. Colloids and Surfaces A: Physicochemical and Engineering Aspects, 2022, 648: 128900.
[70] 别依诺, 朱四荣, 贺攀, 等. 纳米SiO₂-硅烷协同改性对玄武岩纤维/环氧树脂复合材料力学性能及蠕变性能的影响[J]. 复合材料学报, 2022, 39(8): 3723-3732.
BIE Y N, ZHU S R, HE P, et al. Effect of nano-SiO₂ particles-silane synergistic modification on mechanical properties and creep properties of basalt fiber/epoxy composites[J]. Acta Materiae Compositae Sinica, 2022, 39(8): 3723-3732 (in Chinese).
[71] WEI B, SONG S H, CAO H L. Strengthening of basalt fibers with nano-SiO₂-epoxy composite coating[J]. Materials & Design, 2011, 32(8/9): 4180-4186.
[72] LIU S Q, WU G H, YU J J, et al. Surface modification of basalt fiber (BF) for improving compatibilities between BF and poly lactic acid (PLA) matrix[J]. Composite Interfaces, 2019, 26(4): 275-290.
[73] HUGHES E, DAS S, VAN ENGELEN N, et al. Concrete girders retrofitted with basalt fibre fabric-A feasibility study using lab tests and field application[J]. Engineering Structures, 2021, 238: 112223.
[74] GAO F Y, ZHOU X T, MA Y T, et al. Calcium modified basalt fiber bio-carrier for wastewater treatment: investigation on bacterial community and nitrogen removal enhancement of bio-nest[J]. Bioresource Technology, 2021, 335: 125259.
[75] 魏晨, 郭荣辉. 玄武岩纤维的性能及应用[J]. 纺织科学与工程学报, 2019, 36(3): 89-94.
WEI C, GUO R H. Properties and application of basalt fiber[J]. Journal of Textile Science and Engineering, 2019, 36(3): 89-94 (in Chinese).
[76] ÖZTÜRK B, ARSLAN F, ÖZTÜRK S. Hot wear properties of ceramic and basalt fiber reinforced hybrid friction materials[J]. Tribology International, 2007, 40(1): 37-48.
[77] 宋平, 高欢, 汪灵, 等. 玄武岩纤维基本特征及应用前景分析[J]. 矿产保护与利用, 2022, 42(4): 173-178.
SONG P, GAO H, WANG L, et al. Basic characteristics and application prospect analysis of basalt fiber[J]. Conservation and Utilization of Mineral Resources, 2022, 42(4): 173-178 (in Chinese).
[78] BALAJI K V, KAMYAR S, GURU S R, et al. Surface treatment of basalt fiber for use in automotive composites[J]. Materials Today Chemistry, 2020, 17: 100334.
[79] LIU C B, FAN X Q, ZHU M H. Regulating the grinding performance of grindstones via using basalt fibers[J]. Tribology International, 2022, 173: 107611.