Sintering Process of Granite Scrap Mud Building Ceramics

Abstract

Abstract: In order to promote the comprehensive utilization of bulk solid waste and reduce the environmental pollution caused by granite scrap mud, this paper explores a method of preparing ceramic bodies by high temperature sintering using granite scrap mud, high alumina clay and a small amount of additives. The effects of raw material ratio and additive content on the mechanical properties and microstructure of sintered ceramic tiles were studied. The results show that the plasticity of the granulation powder can be improved by adding polyvinyl alcohol (PVA) solution to the ball milling raw material, and the proportion of the granite scrap mud in the body greatly increases. High alumina clay can improve the sintering characteristics of granite scrap mud and the comprehensive mechanical properties of finished products. Among them, the sintering temperature of the finished product with granite scrap mud content of 80% (mass fraction) and clay content of 20% (mass fraction) is about (1 160±30) ℃, the bulk density of the finished product is 2.43 g/cm³, the water absorption rate is 1%, the bending strength is 54 MPa, and the compressive strength is 341 MPa. The comprehensive utilization rate of granite scrap mud is high, and the comprehensive cost is low, which provides an efficient and feasible scheme for the comprehensive utilization of saw mud.

Key words: granite scrap, solid waste utilization, environmental protection, sintering, strengthening mechanism

CLC Number:

TU523

GENG Zhenhua, LI Kai, BI Zhiying, LIU Wenhua, LI Haijian, SUN Gaomeilin, WU Ping. Sintering Process of Granite Scrap Mud Building Ceramics[J]. BULLETIN OF THE CHINESE CERAMIC SOCIETY, 2023, 42(12): 4482-4489.

References

[1] 中国石材协会, 中国建筑材料工业规划研究院. 石材行业“十四五”发展规划(征求意见稿)[J]. 石材, 2022(7): 1-13.
China Stone Association, China Building Materials Industry Planning and Research Institute. Development plan of stone industry in the tenth five-year plan (draft for comment)[J]. Stone, 2022(7): 1-13 (in Chinese).
[2] 华瑜. 石材加工行业环境污染控制研究[J]. 皮革制作与环保科技, 2021, 2(16): 46-47.
HUA Y. Study on environmental pollution control of stone processing industry[J]. Leather Manufacture and Environmental Technology, 2021, 2(16): 46-47 (in Chinese).
[3] 陈国本. 部分国家利用石材废料的研究概述(一)[J]. 石材, 2015(10): 45-54.
CHEN G B. Overview of research on utilization of stone waste in some countries (I)[J]. Stone, 2015(10): 45-54 (in Chinese).
[4] FIGUEIREDO F, FIGUEIREDO G, BOTERO E, et al. Analysis of partial substitution of cement with marble and granite powders in concrete production[J]. ACI Materials Journal, 2022: 211-219.
[5] SHWETHA K, MAHESH K C, DALAWAI V N, et al. Comparative study on strengthening of concrete using granite waste[J]. Materials Today: Proceedings, 2022, 62: 5317-5322.
[6] KIRAN K N, DAMODHARA R B, SASIDHAR C. Compressive strength and durability properties of M35 grade concrete by replacing sand partially with vermiculite and granite powder and coarse aggregate by re-cycled aggregate[J]. IOP Conference Series: Materials Science and Engineering, 2020, 1006(1): 012030.
[7] KIM J, LEE D, SIÁKOVÁ A, et al. Utilization of different forms of demolished clay brick and granite wastes for better performance in cement composites[J]. Buildings, 2023, 13(1): 165.
[8] RAVI G, PRASANNA P K, SATISH S. The Role of granite waste powder on mechanical and durability performance of GGBS and metakaoline based concrete[J]. IOP Conference Series: Earth and Environmental Science, 2023, 1130(1): 012008.
[9] SHIRANI K, REISI M, SAVADKOOHI M S. Eco-friendly high-strength refractory concrete containing calcium alumina cement by reusing granite waste as aggregate[J]. International Journal of Concrete Structures and Materials, 2021, 15(1): 1-21.
[10] VIJAYALAKSHMI M, SEKAR A S S, GANESH P G. Strength and durability properties of concrete made with granite industry waste[J]. Construction and Building Materials, 2013, 46: 1-7.
[11] 钟路生, 刘峰, 马镇耀, 等. 石材锯泥在发泡陶瓷生产中的技术运用[J]. 佛山陶瓷, 2021, 31(7): 25-28.
ZHONG L S, LIU F, MA Z Y, et al. Technical application of stone saw mud in foamed ceramics production[J]. Foshan Ceramics, 2021, 31(7): 25-28 (in Chinese).
[12] 周艳华, 潘泽真, 张伟伟, 等. 轻质发泡陶瓷砖的制备研究[J]. 中国陶瓷, 2021, 57(10): 56-61+67.
ZHOU Y H, PAN Z Z, ZHANG W W, et al. Study on the preparation of lightweight foamed ceramic tiles[J]. China Ceramics, 2021, 57(10): 56-61+67 (in Chinese).
[13] 董祎然, 赵成琳, 郭伟, 等. 花岗岩锯泥和大理石废石粉制备发泡陶瓷[J]. 硅酸盐通报, 2023, 42(3): 939-947+969.
DONG Y R, ZHAO C L, GUO W, et al. Preparation of foamed ceramics from granite scrap and marble scrap[J]. Bulletin of the Chinese Ceramic Society, 2023, 42(3): 939-947+969 (in Chinese).
[14] 潘红, 麦俊明, 高子栋, 等. 利用花岗岩锯泥制备发泡陶瓷多孔保温材料的研究[J]. 砖瓦, 2022(4): 29-33.
PAN H, MAI J M, GAO Z D, et al. Study on preparation of porous foamed ceramic based on granite saw mud[J]. Brick-Tile, 2022(4): 29-33 (in Chinese).
[15] REDDY R M, REDDY B M, REDDY P V, et al. Granite Powder influence on the static mechanical properties of tapsi fiber-reinforced hybrid composites: a comparative study[J]. Journal of Natural Fibers, 2022, 19(16): 12688-12704.
[16] MUHAMMAD N, SAMINA I, EHSAN U H, et al. Improved water retention and positive behavior of silica based geopolymer utilizing granite powder[J]. Silicon, 2021. 1-13.
[17] YILMAZ M, TUĞRUL A. Usability of granitic rock wastes as asphalt aggregate in proceedings of the international conference sustainable aggregates resource management[J]. Ljubljana, Slovenia, 2011, 20, 135-141.
[18] SHILAR F, QUADRI S S. Performance evaluation of interlocking bricks using granite waste powder[J]. International Journal of Engineering Applied Sciences and Technology, 2019, 4(2): 82-87.
[19] LUO Y, WU Y H, MA S H, et al. An eco-friendly and cleaner process for preparing architectural ceramics from coal fly ash: pre-activation of coal fly ash by a mechanochemical method[J]. Journal of Cleaner Production, 2019, 214: 419-428.
[20] TORRES P, FERNANDES H R, OLHERO S, et al. Incorporation of wastes from granite rock cutting and polishing industries to produce roof tiles[J]. Journal of the European Ceramic Society, 2009, 29(1): 23-30.
[21] VASIĆ M V, MIJATOVIĆ N, RADOJEVIĆ Z. Aplitic granite waste as raw material for the production of outdoor ceramic floor tiles[J]. Materials, 2022, 15(9): 3145.
[22] NGAYAKAMO B, BELLO A, ONWUALU A P. Valorization of granite waste powder as a secondary flux material for sustainable production of ceramic tiles[J]. Cleaner Materials, 2022, 4: 100055.
[23] TORRES P, FERNANDES H R, OLHERO S, et al. Incorporation of wastes from granite rock cutting and polishing industries to produce roof tiles[J]. Journal of the European Ceramic Society, 2009, 29(1): 23-30.
[24] ACCHAR W, AVELINO K A, SEGADÃES A M. Granite waste and coffee husk ash synergistic effect on clay-based ceramics[J]. Advances in Applied Ceramics, 2016, 115(4): 236-242.
[25] 马铁成. 陶瓷工艺学[M]. 2版. 北京: 中国轻工业出版社, 2011.
MA T C. Ceramic technology[M]. 2nd ed. Beijing: China Light Industry Press, 2011 (in Chinese).
[26] 中华人民共和国国家质量监督检验检疫总局, 中国国家标准化管理委员会. 陶瓷砖: GB/T 4100—2015[S]. 北京: 中国标准出版社, 2015.
General Administration of Quality Supervision, Inspection and Quarantine of the People’s Republic of China, State Standardization Administration of China. Ceramic tiles: GB/T 4100—2015[S]. Beijing: China Standards Publishing House, 2015 (in Chinese).
[27] 李明浩. 氢氟酸腐蚀硅酸盐矿物的实验研究[J]. 云南化工, 2017, 44(6): 35-38.
LI M H. Research on the erosion of hydrofluoric acid to silicate mineral[J]. Yunnan Chemical Technology, 2017, 44(6): 35-38 (in Chinese).
[28] EVANS A G. The strength of brittle materials containing second phase dispersions[J]. Philosophical Magazine, 1972, 26: 1327-1344.
[29] 张金升, 张银燕, 王美婷, 等. 陶瓷材料显微结构与性能[M]. 北京: 化学工业出版社, 2007.
ZHANG J S, ZHANG Y Y, WANG M T, et al. Microstructure and properties of ceramic materials[M]. Beijing: Chemical Industry Press, 2007 (in Chinese).