Effect of Al2O3 Content on Crystallization Behavior and Sintering Performance of PbO-CaO-B2O3-SiO2 Glass

Abstract

Abstract: PbO-CaO-B₂O₃-SiO₂ glass powder is the main component of low temperature co-fired ceramics (LTCC) raw green tape with high overload resistance. The crystallization behavior of glass powder affects the sintering performance, and then determines the performance of substrate. The effect of Al₂O₃ content on crystallization behavior and sintering performance of PbO-CaO-B₂O₃-SiO₂ glass was studied. The results show that the addition of Al₂O₃ into PbO-CaO-B₂O₃-SiO₂ glass can reduce the trend of crystallization, prevent the precipitation of high expansion crystalline phase and improve the sintering density of glass. The crystallization peak temperature of PbO-CaO-B₂O₃-SiO₂ glass powder without Al₂O₃ is 862 ℃, and cristobalite phase precipitates during sintering, which makes the average coefficient of linear expansion reach 260.8×10^-7 ℃^-1 at 20~200 ℃. The addition of 2.1% (mass fraction) Al₂O₃ into PbO-CaO-B₂O₃-SiO₂ glass can significantly reduce the crystallization capability of glass, and the expansion coefficient decreases to 72.9×10^-7 ℃^-1 after sintering at 700 ℃, with significantly increased dielectric constant from 6.30 to 7.02.

Key words: PbO-CaO-B₂O₃-SiO₂ glass, glass powder, Al₂O₃, sintering performance, crystallization behavior, low temperature co-fired ceramics

CLC Number:

TQ171

HAI Yun, XU Bo, YIN Xianyin, ZHU Baojing, HAN Bin, ZU Chengkui. Effect of Al₂O₃ Content on Crystallization Behavior and Sintering Performance of PbO-CaO-B₂O₃-SiO₂ Glass[J]. BULLETIN OF THE CHINESE CERAMIC SOCIETY, 2022, 41(11): 3997-4002.

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Effect of Al₂O₃ Content on Crystallization Behavior and Sintering Performance of PbO-CaO-B₂O₃-SiO₂ Glass

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