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BULLETIN OF THE CHINESE CERAMIC SOCIETY ›› 2022, Vol. 41 ›› Issue (11): 3952-3959.

Special Issue: 玻璃

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Effects of Different Refining Agents on Clarification Effect of Neutral Pharmaceutical Glass

ZHANG Xiaoyu1,2, LI Changqing1,2, ZHAO Fengyang1,2, SHI Lifen1,2, ZHONG Zhaojin1,2, GAO Qiang1,2   

  1. 1. State Key Laboratory of Advanced Technology for Float Glass, CNBM Research Institute for Advanced Glass Materials Group Co., Ltd., Bengbu 233010, China;
    2. Silica-Based Materials Laboratory of Anhui Province, Bengbu 233010, China
  • Received:2022-08-15 Revised:2022-09-15 Online:2022-11-15 Published:2022-12-12

Abstract: Due to its excellent chemical stability and thermal stability, neutral pharmaceutical glass is widely used in pharmaceutical, food and other packaging fields. In this paper, the effects of oxide refining agent CeO2, halide refining agent NaCl, and compound refining agent NaCl-CeO2 and NaCl-CeO2-NaNO3 on the clarification effect of neutral pharmaceutical glass were studied. The changes of area fraction, number of bubbles, and mean bubble size were quantitatively analyzed, and the refining agent suitable for neutral medical glass was explored. The research results show that after adding NaCl-CeO2-NaNO3 to the neutral pharmaceutical glass liquid, the area fraction and number of bubbles are smaller, and the mean bubble size is larger. Thus, the clarification effect of adding NaCl-CeO2-NaNO3 is better than adding NaCl and CeO2. When 0.4% (mass fraction) NaCl-0.20% (mass fraction) CeO2-0.005 0% (mass fraction) NaNO3 is added, within 3 h after the temperature raising to 1 550 ℃, the area fraction of neutral pharmaceutical glass is reduced to 0.6%, the number of bubbles is reduced to 3, and the mean bubble size is 0.60 mm, the clarification effect is better.

Key words: neutral pharmaceutical glass, refining agent, area fraction, number of bubbles, mean bubble size

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