Influence of Mixed Alkali Effect on Structure and Thermal Expansion Properties of Li2O-Al2O3-SiO2 Glass

Abstract

Abstract: In this paper, the Li₂O-Al₂O₃-SiO₂ high alumina glass was melted by traditional high temperature melting method, and the mole ratio of alkali metal oxide n(Li₂O)/n(Na₂O) was changed. The influence of mixed alkali metal effect on the structure and thermal expansion performance of Li₂O-Al₂O₃-SiO₂ glass was investigated by Archimedes drainage method, thermal expansion instrument, DSC, Fourier transform infrared spectroscopy and Raman spectroscopy. The effects on the structure and thermal expansion properties of Li₂O-Al₂O₃-SiO₂ glasses are different. Results show that with the increase of n(Li₂O)/n(Na₂O) mole ratio, the mixed alkali metal effect has the same effect on the density and thermal expansion coefficient of Li₂O-Al₂O₃-SiO₂ glass, which increases first and then decreases, When R=0.25(R=n(Li₂O)/[n(Li₂O)+n(Na₂O)], mole ratio) has a maximum value, the maximum density is 2.447 4 g/cm³, and the maximum thermal expansion coefficient is 7.811 7×10^-6/℃. The influence on the characteristic temperature of glass gradually weakens and disappears with the increase of temperature. It can promote the crystallization behavior of glass to some extent.The influences on the silicon-oxygen tetrahedron Qⁿ in the three-dimensional skeleton structure of glass are also different.

Key words: alkali metal oxide, silicon-oxygen tetrahedron, thermal expansion, characteristic temperature, mixed alkali effect, Li-Al-Si glass

CLC Number:

TQ171

ZENG Lin, HUANG Shoujia, LIN Hongjian, ZHAO Huifeng, JIANG Hong, MA Yanping. Influence of Mixed Alkali Effect on Structure and Thermal Expansion Properties of Li₂O-Al₂O₃-SiO₂ Glass[J]. BULLETIN OF THE CHINESE CERAMIC SOCIETY, 2021, 40(11): 3813-3821.

References

[1] 胡伟,谈宝权,覃文城,等.化学强化玻璃的发展现状及研究展望[J].玻璃与搪瓷,2018,46(3):44-50.
HU W, TAN B Q, QIN W C, et al. Development and prospects of chemically strengthened glasses[J]. Glass & Enamel, 2018, 46(3): 44-50 (in Chinese).
[2] WILKINSON C J, POTTER A R, WELCH R S, et al. Topological origins of the mixed alkali effect in glass[J]. The Journal of Physical Chemistry B, 2019, 123(34): 7482-7489.
[3] SUBHASHINI, SHASHIKALA H D, UDAYASHANKAR N K. Investigation of mixed alkali effect on mechanical, structural and thermal properties of three-alkali borate glass system[J]. Journal of Alloys and Compounds, 2016, 658: 996-1002.
[4] 张璐.化学组成对高碱铝硅酸盐玻璃微观结构影响作用规律研究[D].北京:北京工业大学,2018.
ZHANG L. Study on the effect of chemical composition on the microstructure of high-alkali aluminosilicate glass[D]. Beijing: Beijing University of Technology, 2018 (in Chinese).
[5] 元田委,袁坚,郑伟宏,等.碱金属氧化物引入量对MgO-Al₂O₃-SiO₂微晶玻璃结构及其化学增强效果的影响[J].硅酸盐通报,2019,38(5):1522-1526+1555.
YUAN T W, YUAN J, ZHENG W H, et al. Effect of the introduction of alkali metal oxides on the structure and chemical enhancement process of MgO-Al₂O₃-SiO₂ glass-ceramics[J]. Bulletin of the Chinese Ceramic Society, 2019, 38(5): 1522-1526+1555 (in Chinese).
[6] 李俊杰,田英良,宫汝华,等.超薄屏幕保护玻璃组成与性能关系[J].玻璃与搪瓷,2019,47(2):11-15+32.
LI J J, TIAN Y L, GONG R H, et al. Effect of glass composition on the properties of ultra thin screen cover glass[J]. Glass & Enamel, 2019, 47(2): 11-15+32 (in Chinese).
[7] HOU Y, ZHANG G H, CHOU K C. Mixed alkali effect in SiO₂-CaO-Al₂O₃-TiO₂-R2O (R=Li, Na) glass ceramics[J]. Journal of Alloys and Compounds, 2021, 856: 158239.
[8] HE Y, SHEN X F, JIANG Y, et al. Effects of Li₂O replacing Na₂O on glass forming, structure and properties of Na₂O-MgO-Al₂O₃-SiO₂ glass and glass-ceramics[J]. Materials Chemistry and Physics, 2021, 258: 123865.
[9] KOJIMA S. Mixed-alkali effect in borate glasses: thermal, elastic, and vibrational properties[J]. Solids, 2020, 1(1): 16-30.
[10] MONEY B, HARIHARAN K. Mixed alkali effect on crystallization kinetics of xNa₂O:(50-x)Li₂O:50P₂O₅[J]. Solid State Ionics, 2014, 262: 824-828.
[11] EDUKONDALU A, PURNIMA M, SRINIVASY C, et al. Mixed alkali effect in physical and optical properties of Li₂O-Na₂O-WO₃-B₂O₃ glasses[J]. Journal of Non-Crystalline Solids, 2012, 358(18/19): 2581-2588.
[12] 周新艳,程金树,康俊峰,等.碱金属氧化物对CaO-MgO-Al₂O₃-SiO₂玻璃黏度和析晶性能的影响[J].武汉理工大学学报,2015,37(3):8-12.
ZHOU X Y, CHENG J S, KANG J F, et al. Effect of alkali mental oxides on viscosity and crystallization behavior of Ca O-Mg O-Al₂O₃-SiO₂ glass-ceramics[J]. Journal of Wuhan University of Technology, 2015, 37(3): 8-12 (in Chinese).
[13] 刘明,许晓颖,刘缙,等.碱金属氧化物对硼硅酸盐系玻璃/Al₂O₃材料性能的影响[J].电子元件与材料,2014,33(8):42-45+48.
LIU M, XU X Y, LIU J, et al. Effect of alkalis on properties of borosilicate glass/Al₂O₃ system material[J]. Electronic Components and Materials, 2014, 33(8): 42-45+48 (in Chinese).
[14] 殷先印,韩滨,祖成奎,等.碱金属氧化物对SiO₂-R₂O₃-R₂O-RO系铁封玻璃性能的影响[J].玻璃与搪瓷,2013,41(2):6-9+17.
YIN X Y, HAN B, ZU C K, et al. Influence of alkali metal oxides on properties of SiO₂-R₂O₃-R₂O-RO system iron-sealing glass[J]. Glass & Enamel, 2013, 41(2): 6-9+17 (in Chinese).
[15] 张兵,陈奇,侯凤珍,等.R₂O对ZnO-Sb₂O₃-P₂O₅低熔玻璃性能的影响[J].玻璃与搪瓷,2007,35(6):12-16+36.
ZHANG B, CHEN Q, HOU F Z, et al. Effect of R₂O on the properties of ZnO-Sb₂O₃-P₂O₅ low-melting glasses[J]. Glass & Enamel, 2007, 35(6): 12-16+36 (in Chinese).
[16] MOHAJERANI A, ZWANZIGER J W. Mixed alkali effect on Vickers hardness and cracking[J]. Journal of Non-Crystalline Solids, 2012, 358(12/13): 1474-1479.
[17] 刘会媛.碱金属氧化物稳定性的讨论[J].唐山师范学院学报,2001,23(2):32-33.
LIU H Y. The discuss of the stability of alkali metal oxide[J]. Journal of Tangshang Teachers College, 2001, 23(2): 32-33 (in Chinese).
[18] CALAHOO C, XIA Y, ZHOU R. Influence of glass network ionicity on the mixed-alkali effect[J]. International Journal of Applied Glass Science, 2020, 11(3): 396-414.
[19] ANZAR N, HASAN R, TYAGI M, et al. Carbon nanotube: a review on synthesis, properties and plethora of applications in the field of biomedical science[J]. Sensors International, 2020, 1: 100003.
[20] 邹雯,张垠,洪重荣,等.碱金属氧化物对P₂O₅-ZnO-R₂O玻璃物化性能的影响[J].化工新型材料,2015,43(6):166-168.
ZOU W, ZHANG Y, HONG C R et al. Influence of alkali metal oxides on property of P₂O₅-ZnO-R₂O glass[J]. New Chemical Materials, 2015, 43(6): 166-168 (in Chinese).
[21] KJELDSEN J, SMEDSKJAER M M, MAURO J C, et al. On the origin of the mixed alkali effect on indentation in silicate glasses[J]. Journal of Non-Crystalline Solids, 2014, 406: 22-26.
[22] IQBAL A A, SAKIB N, IQBAL A K M P, et al. Graphene-based nanocomposites and their fabrication, mechanical properties and applications[J]. Materialia, 2020, 12: 100815.
[23] HOU Y, ZHANG G H, CHOU K C, et al. Mixed alkali effect in viscosity of CaO-SiO₂-Al₂O₃-R₂O melts[J]. Metallurgical and Materials Transactions B, 2020, 51(3): 985-1002.

Influence of Mixed Alkali Effect on Structure and Thermal Expansion Properties of Li₂O-Al₂O₃-SiO₂ Glass

PDF (PC)

Knowledge

Abstract

Cite this article

share this article

References

Related Articles 15

Recommended Articles

Metrics

Comments

[1]	ZHANG Baodong, XU Junfeng, CHANG Fang'e. Preparation of Ge₂₀Sb₁₀Se₆₅Te₅ Chalcogenide Glass and Impurity Removal Mechanism of Ti Wire [J]. BULLETIN OF THE CHINESE CERAMIC SOCIETY, 2021, 40(9): 3145-3151.
[2]	LI Shuming, ZHENG Xinguo, LIU Jing, XIE Yongjiang, HU Jialin, ZHANG Xu. Deformation Performance of Steel Tube Self-Compacting Lightweight Aggregate Concrete [J]. BULLETIN OF THE CHINESE CERAMIC SOCIETY, 2021, 40(5): 1497-1502.
[3]	ZHANG Pan, ZHANG Qinyu, JIANG Hong, MA Yanping. Effect of B₂O₃ on Structure and Properties of Low Expansion Borosilicate Glass [J]. BULLETIN OF THE CHINESE CERAMIC SOCIETY, 2021, 40(5): 1685-1691.
[4]	MEI Tao, HUANG Qizhong, WANG Shaobin, PAN Fuqiang, FENG Xiupeng, LI Hongxue. Effect of Alkali Metal Oxide Na₂O on Performance of Vitrified Bond Diamond Abrasive Tools [J]. BULLETIN OF THE CHINESE CERAMIC SOCIETY, 2021, 40(3): 978-983.
[5]	ZHAO Zhifang, WU Xu, ZHANG Zhenyu, QI Jieyi, ZHANG Guangbo, XU Jiaming. Thermal Expansion Coefficient of Carbon Nanotubes Reinforced Face Slab Concrete of Rockfill Dam at Early Age [J]. BULLETIN OF THE CHINESE CERAMIC SOCIETY, 2021, 40(2): 465-472.
[6]	LI Jinwei, WANG Weiwei, ZHONG Zhaojin, WANG Pingping, SHI Lifen, GUAN Min, YU Tao, CAO Xin. Effects of Alkali Metal Oxides on Structure and Properties of Sealing Glass with Low-Dielectric Constant [J]. BULLETIN OF THE CHINESE CERAMIC SOCIETY, 2021, 40(11): 3807-3812.
[7]	DIAO Jinlong, YU Tianlai, MO Dahong, ZHENG Tao, GUO Yanyan, LYU Jingwen. Effect of SnO on Structure and Performance ofSnF₂-P₂O₅-WO₃ Glass System [J]. BULLETIN OF THE CHINESE CERAMIC SOCIETY, 2021, 40(1): 266-270.
[8]	ZHU Jiaqi, MAO Hanqi, ZHANG Zhengjun, SUN Jianning, LI Jingwen, LIN Yanjian, QIAO Fangjian, ZHANG Huan. Effect of ZrO₂ on Structure and Properties of Lead Silicon Glass for Microchannel Plate [J]. BULLETIN OF THE CHINESE CERAMIC SOCIETY, 2020, 39(12): 4010-4015.
[9]	DU Tao;TIAN Ying-liang;LI Yong-ming;SU Yin;WANG Yong-qing;LU Ping. Effect of ZrO2 on Structure and Properties of Pharmaceutically Medium Borosilicate Glass [J]. BULLETIN OF THE CHINESE CERAMIC SOCIETY, 2017, 36(4): 1288-1292.
[10]	ZHANG Zhi-ping;ZHANG Jia-cheng;LIU Hong-fei;YANG Lu;CHEN Xiao-bing. Preparation and Negative Thermal Expansion of Er2W3O12 Ceramics [J]. BULLETIN OF THE CHINESE CERAMIC SOCIETY, 2017, 36(3): 1071-1074.
[11]	ZHU Kui;CHENG Jin-shu;LU Ping;GUO Zhen-qiang. Effect of Al2 O3 on Structure and Properties of Borosilicate Glass [J]. BULLETIN OF THE CHINESE CERAMIC SOCIETY, 2017, 36(1): 396-400.
[12]	SUN Xiu-juan;CHENG Xiao-nong;YANG Juan;LIU Qin-qin. Influence of Different Acid Solvents on the Morphology of ZrW2 O8 Powders by Hydrothermal Method [J]. BULLETIN OF THE CHINESE CERAMIC SOCIETY, 2016, 35(9): 2909-2912.
[13]	LU Guo-feng. Thermophysical Properties of C/PyC/Si-C-N Composite [J]. BULLETIN OF THE CHINESE CERAMIC SOCIETY, 2016, 35(4): 1015-1019.
[14]	WANG Lin-lin;HE Feng;WANG Li-ge;MEI Shu-xia;JIN Ming-fang;XIE Jun-lin. Effect of BaO on Structure and Properties of Silicate Sealing Glass of SOFC [J]. BULLETIN OF THE CHINESE CERAMIC SOCIETY, 2016, 35(1): 267-274.
[15]	TANG Bo;LI Bo;XU Ming-jiang. Effect of CaO Doping on Properties of BaO-B2O3-SiO2 Glass-ceramics [J]. BULLETIN OF THE CHINESE CERAMIC SOCIETY, 2014, 33(8): 2016-2020.