Preparation and Electrochemical Performance of SnO2 Supported on Porous Bamboo Charcoal

Abstract

Abstract: Porous bamboo charcoal is amorphous carbon with abundant pore structure, and the pore size ranges from 1 nm to 6 nm, with a large pore volume (1.21 cm³/g). Using porous bamboo charcoal as the carrier, the B₂O₃-SnO₂/C composite material was prepared by the sol-gel method. SEM and TEM results show that SnO₂ and B₂O₃ are uniformly distributed on the surface of the porous bamboo charcoal. The porous bamboo charcoal and B₂O₃ effectively accommodate the volume change of the reversible reaction of SnO₂ and improve the cycling stability of SnO₂. The lithium-ion batteries were assembled by B₂O₃-SnO₂/C composite materials as anode, and the electrochemical performance was tested. After 200 cycles, the discharge specific capacity still reaches 649.9 mAh/g at 1 C (1 C=372 mA/g) rate, and the discharge specific capacity retention rate is as high as 58.6%. The charge-discharge process of B₂O₃-SnO₂/C porous composites is controlled by diffusion and capacitance behavior, and the contribution rate of capacitance control increases with the increase of scan rate.

Key words: B₂O₃-SnO₂/C composite, cycling stability, lithium-ion battery, anode material, porous bamboo charcoal, sol-gel method

CLC Number:

TQ152

WU Hong, CHEN Qianlin, LI Cuiqin. Preparation and Electrochemical Performance of SnO₂ Supported on Porous Bamboo Charcoal[J]. BULLETIN OF THE CHINESE CERAMIC SOCIETY, 2021, 40(11): 3740-3749.

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Preparation and Electrochemical Performance of SnO₂ Supported on Porous Bamboo Charcoal

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