Effect of ZnO-B2O3 Glass on Low Temperature Sintering and Properties of Li2Zn3Ti4O12-CaTiO3 Composite Ceramics

Abstract

Abstract: The 0.94Li₂Zn₃Ti₄O₁₂-0.06CaTiO₃ (LZT-CT) composite ceramics were prepared by the traditional solid-state reaction method, and ZnO-B₂O₃(ZB) glass was synthesized by high temperature melting method. The sintering characteristics, phase compositions, microstructures and microwave dielectric properties of LZT-CT composite ceramics with different mass fraction (x=0.5%, 1.0%, 1.5%, 2.0% and 2.5%) of ZB glass were investigated in detail. The results indicate that, the ZB glass effectively decreases the sintering temperature of the LZT-CT composite ceramics from 1 175 ℃ to 875 ℃ and also promotes the densifiction. There are no new phases in addition to the LZT and CT phase when ZB glass addition x≤2.5%. With the increase of ZB glass addition, the densification temperature of composite ceramics decreases gradually, the bulk density, relative permittivity (ε_r), quality factor (Q×f) initially increase and then decrease, and the temperature coefficient of resonance frequency (τ_f) is stable, fluctuated between -2.25×10^-6/℃ and 4.51×10⁶/℃. When added 2.0%ZB glass, LZT-CT composite ceramics sintered at 875 ℃ for 2 h obtained maximun bulk density of 4.22 g/cm³, and excellent microwave dielectric properties: ε_r=23.9, Q×f=58 595 GHz, τ_f=-0.14×10^-6/℃.

Key words: ZnO-B₂O₃ glass, 0.94Li₂Zn₃Ti₄O₁₂-0.06CaTiO₃ composite ceramics, low temperature sintering, microwave dielectric property

CLC Number:

TQ174

SHU Guojin, YUAN Shifeng, PANG Jinbiao, DOU Zhanming, YANG Jun, LIU Kai, HAN Guangxue. Effect of ZnO-B₂O₃ Glass on Low Temperature Sintering and Properties of Li₂Zn₃Ti₄O₁₂-CaTiO₃ Composite Ceramics[J]. BULLETIN OF THE CHINESE CERAMIC SOCIETY, 2021, 40(10): 3305-3310.

References

[1] CAVA R J. Dielectric materials for applications in microwave communications[J]. Journal of Materials Chemistry, 2001, 11(1): 54-62.
[2] OHSATO H. Research and development of microwave dielectric ceramics for wireless communications[J]. Journal of the Ceramic Society of Japan, 2005, 113(1323): 703-711.
[3] SEBASTIAN M T. Acknowledgment[M]//Dielectric Materials for Wireless Communication. Amsterdam: Elsevier, 2008: 83-108.
[4] SEBASTIAN M T, WANG H, JANTUNEN H. Low temperature co-fired ceramics with ultra-low sintering temperature: a review[J]. Current Opinion in Solid State and Materials Science, 2016, 20(3): 151-170.
[5] SHU G J, ZHANG Q, YANG F, et al. Low temperature sintering and microwave dielectric properties of Li₂ZnTi₃O₈-TiO₂ ceramics doped with BaO-B₂O₃-ZnO glass[J]. Journal of Materials Science: Materials in Electronics, 2018, 29(19): 17008-17015.
[6] ZHOU H F, LIU X B, CHEN X L, et al. ZnLi_2/3Ti_4/3O₄: a new low loss spinel microwave dielectric ceramic[J]. Journal of the European Ceramic Society, 2012, 32(2): 261-265.
[7] GEORGE S, SEBASTIAN M T. Low-temperature sintering and microwave dielectric properties of Li₂ATi₃O₈ (A=Mg, Zn) ceramics[J]. International Journal of Applied Ceramic Technology, 2011, 8(6): 1400-1407.
[8] PANG L X, ZHOU D. Microwave dielectric properties of low-firing Li₂MO₃ (M=Ti, Zr, Sn) ceramics with B₂O₃-CuO addition[J]. Journal of the American Ceramic Society, 2010, 93(11): 3614-3617.
[9] THOMAS D, SEBASTIAN M T. Temperature-compensated LiMgPO₄: a new glass-free low-temperature cofired ceramic[J]. Journal of the American Ceramic Society, 2010, 93(11): 3828-3831.
[10] LIU X B, ZHOU H F, CHEN X L, et al. Phase structure and microwave dielectric properties of (1-x)Li₂Zn₃Ti₄O_12-xTiO₂ ceramics[J]. Journal of Alloys and Compounds, 2012, 515: 22-25.
[11] QUAN T T, SHU G J, HAO L, et al. Phase compositions, microstructures, and microwave dielectric properties of Li₂Zn₃Ti₄O₁₂-based temperature stable materials modified by CaTiO₃ additions[J]. Journal of Materials Science: Materials in Electronics, 2019, 30(22): 20160-20165.
[12] ZHANG T W, ZUO R Z, WANG Y. Li₂Zn₃Ti₄O₁₂-Ba₃(VO₄)₂ microwave dielectric ceramics sintered at a low temperature without glass addition[J]. Journal of Materials Science: Materials in Electronics, 2014, 25(12): 5570-5575.
[13] SAYYADI-SHAHRAKI A, TAHERI-NASSAJ E, HASSANZADEH-TABRIZI S A, et al. Low temperature cofirable Li₂Zn₃Ti₄O₁₂ microwave dielectric ceramic with Li₂O-ZnO-B₂O₃ glass additive[J]. Journal of Materials Science: Materials in Electronics, 2014, 25(1): 355-360.
[14] REN H S, JIANG S H, DANG M Z, et al. Investigating on sintering mechanism and adjustable dielectric properties of BLMT glass/Li₂Zn₃Ti₄O₁₂ composites for LTCC applications[J]. Journal of Alloys and Compounds, 2018, 740: 1188-1196.
[15] 唐骅,伍海浜,孟范成.H₃BO₃对Li₂Zn₃Ti₄O₁₂微波介质陶瓷低温烧结与微波介电性能的影响[J].硅酸盐通报,2017,36(3):1090-1093+1100.
TANG H, WU H B, MENG F C. Effect of H₃BO₃ on the low temperature sintering and microwave dielectric properties of Li₂Zn₃Ti₄O₁₂ ceramics[J]. Bulletin of the Chinese Ceramic Society, 2017, 36(3): 1090-1093+1100 (in Chinese).
[16] WU Y, ZHOU D, GUO J, et al. Microwave dielectric properties and low temperature firing of (1-x)Li₂Zn₃Ti₄O₁₂-xLi₂TiO₃ (0.2≤x≤0.8) ceramics with B₂O₃-CuO addition[J]. Journal of Materials Science: Materials in Electronics, 2013, 24(5): 1505-1510.
[17] LIANG J, LU W Z. Microwave dielectric properties of Li₂TiO₃ ceramics doped with ZnO-B₂O₃ frit[J]. Journal of the American Ceramic Society, 2009, 92(4): 952-954.
[18] DOU G, ZHOU D X, GONG S P, et al. Low temperature sintering and microwave dielectric properties of Li₂ZnSiO₄ ceramics with ZB glass[J]. Journal of Materials Science: Materials in Electronics, 2013, 24(5): 1601-1607.
[19] LEI S H, FAN H Q, CHEN W N, et al. Structure, microwave dielectric properties, and novel low-temperature sintering of xSrTiO₃-(1-x)LaAlO₃ ceramics with LTCC application[J]. Journal of the American Ceramic Society, 2017, 100(1): 235-246.
[20] 张文娟.La₂O₃-B₂O₃玻璃添加对Zn_0.5Ti_0.5NbO₄微波介质陶瓷结构及性能影响[J].电子元件与材料,2020,39(3):39-43+51.
ZHANG W J. Effects of La₂O₃-B₂O₃ glass addition on structure and properties of Zn_0.5Ti_0.5NbO₄ microwave dielectric ceramics[J]. Electronic Components and Materials, 2020, 39(3): 39-43+51 (in Chinese)

Effect of ZnO-B₂O₃ Glass on Low Temperature Sintering and Properties of Li₂Zn₃Ti₄O₁₂-CaTiO₃ Composite Ceramics

PDF (PC)

Knowledge

Abstract

Cite this article

share this article

References

Related Articles 8

Recommended Articles

Metrics

Comments

[1]	TANG Hua;WU Hai-bang;MENG Fan-cheng. Effect of H3BO3 on the Low Temperature Sintering and Microwave Dielectric Properties of Li2Zn3Ti4O12 Ceramics [J]. BULLETIN OF THE CHINESE CERAMIC SOCIETY, 2017, 36(3): 1090-1093.
[2]	CUI Xiang-hong;GENG Zhen-hua. Effect of B2O3 Doping on Low Temperature Sintering and Microwave Dielectric Properties of α-CaSiO3/Al2O3 Ceramics [J]. BULLETIN OF THE CHINESE CERAMIC SOCIETY, 2017, 36(11): 3659-3663.
[3]	SUN Cai-xia;GAO Jing-xia;ZHANG Jin-ping;WANG Er-ping;ZHANG Yang-yang. Microwave Properties of(1-x) Ba3 (VO4) 2-xLi2 MoO4 Microwave Dielectric Ceramics Sintered at Low Temperature [J]. BULLETIN OF THE CHINESE CERAMIC SOCIETY, 2016, 35(9): 2793-2797.
[4]	QIN Shuai-shuai;LUO Guo-shi;LIU Yang;XIAO Teng;ZHENG Xing-hua. Effect of CuO-B2O3 Addition on Sintering Behaviors and Microwave Dielectric Properties of Ba4Sm9.33Ti18O54 Ceramics [J]. BULLETIN OF THE CHINESE CERAMIC SOCIETY, 2016, 35(6): 1711-1715.
[5]	ZHANG Kang;YUAN Cui;FU Yin-ping;LI Wei. Effect of CaTiO3 Additives on the Sintering, Microstructure and Microwave Dielectric Properties of Alumina Ceramic [J]. BULLETIN OF THE CHINESE CERAMIC SOCIETY, 2015, 34(9): 2614-2618.
[6]	JIN Biao;WANG Xiao;YANG Liu-shuan;LI Qian. Low Temperature Sintering Ba2Ti9O20 Microwave Dielectric Ceramics Prepared by CuO Coated Powder [J]. BULLETIN OF THE CHINESE CERAMIC SOCIETY, 2014, 33(7): 1631-1635.
[7]	FU Zhi-fen;MA Jian-li;TANG Yong-xin;LIU Peng;GAO Juan. Low Temperature Sintering and Property of Mg4Nb2O9-0.75wt％ V2O5-1.5wt％ Li2CO3 Microwave Dielectric Ceramics [J]. BULLETIN OF THE CHINESE CERAMIC SOCIETY, 2014, 33(4): 787-790.
[8]	ZHANG Bin;LI Yue-ming;ZHANG Hua;LIAO Run-hua. Research on Low-temperature Sintering and Properties of Ca_(0.3)(Li_(0.5)Sm_(0.5))_(0.7)TiO_3 Microwave Dielectric Ceramics with Composite Sintering Additive [J]. BULLETIN OF THE CHINESE CERAMIC SOCIETY, 2010, 29(1): 162-166.