Research Progress on Preparation, Characterization and Application of Modified Bentonite Materials

doi:10.16552/j.cnki.issn1001-1625.2025.0122

Abstract

Abstract: Bentonite is a natural non-metallic mineral resource. Transforming it into valuable products through advanced technological means and applying them in various fields of social production such as industry, agriculture and environmental governance is an important way to achieve resource recycling and reduce negative environmental impacts. This paper reviews the current preparation methods, characterization techniques and application status of modified bentonite materials at home and abroad, summarizes the methods and principles for improving the performance of bentonite and the characterization and testing methods, analyzes the application potential and shortcomings of modified bentonite in soil improvement, remediation agents, fertilizer additives, pesticide adsorbents and fields such as electronics, automobiles and aerospace, and looks forward to the future development direction of modified bentonite materials, providing useful references and inspirations for the research and development of high-performance modified bentonite materials.

Key words: bentonite, composite material, intelligent material, sensing technology, environmental governance, modification, characterization

CLC Number:

TB321

YI Shirong, ZHANG Miaomiao, CHEN Sisi, WANG Linlin, NI Yuhang, HAN Zhiwei, ZHAO Dan. Research Progress on Preparation, Characterization and Application of Modified Bentonite Materials[J]. BULLETIN OF THE CHINESE CERAMIC SOCIETY, 2025, 44(9): 3255-3271.

References

[1] 黄荣强, 阙绍娟. 我国膨润土资源开发应用现状[J]. 西部资源, 2010(5): 36-38.
HUANG R Q, QUE S J. Development and application status of bentonite resources in China[J]. Western Resources, 2010(5): 36-38 (in Chinese).
[2] 夏意峻. 富水砂层顶管泥浆减阻特性研究[D]. 北京: 中国地质大学(北京), 2023.
XIA Y J. Study on drag reduction characteristics of pipe jacking mud in water-rich sand layer[D]. Beijing: China University of Geosciences (Beijing), 2023 (in Chinese).
[3] 刘承帅, 万洪富, 侯梅芳, 等. 我国主要产地膨润土颗粒组成和蒙脱石含量研究[J]. 非金属矿, 2005, 28(1): 40-43.
LIU C S, WAN H F, HOU M F, et al. Study on particle size distribution & montmorillonite content of bentonite in main deposits of China[J]. Non-metallic Mines, 2005, 28(1): 40-43 (in Chinese).
[4] 郭传杰, 祝琳华. 插层膨润土复合材料制备及应用的研究进展[J]. 硅酸盐通报, 2011, 30(1): 125-128.
GUO C J, ZHU L H. Development in preparation and application of bentonite composites by intercalation[J]. Bulletin of the Chinese Ceramic Society, 2011, 30(1): 125-128 (in Chinese).
[5] 古丽娜尔·巴合提别克, 王瑛, 苏金娟, 等. 膨润土-甘草渣复合材料保水效应[J]. 新疆农业科学, 2021, 58(2): 361-374.
GULINAER B, WANG Y, SU J J, et al. Study on water retention effect of bentonite and licorice residue composites material[J]. Xinjiang Agricultural Sciences, 2021, 58(2): 361-374 (in Chinese).
[6] 孙艳, 张士荣, 丁效东, 等. 肥料添加剂NAM对盐渍土壤理化性质及水稻氮肥农学利用效率的影响[J]. 山东农业科学, 2020, 52(4): 86-91.
SUN Y, ZHANG S R, DING X D, et al. Effects of fertilizer additive NAM on physical and chemical properties of saline soil and agronomic utilization efficiency of nitrogen fertilizer in rice[J]. Shandong Agricultural Sciences, 2020, 52(4): 86-91 (in Chinese).
[7] AL-ZAYADI L R S, ALI HUSSEIN A. The impact of adding bentonite and organic fertilizer on the growth and yield of sorghum in desert soil under the conditions of the badia Al-samawa[J]. IOP Conference Series: Earth and Environmental Science, 2024, 1371(8): 082007.
[8] 张梅琪, 娄现芬, 陈利标, 等. 丙草胺在有机膨润土的等温吸附和吸附动力学研究[J]. 广西大学学报(自然科学版), 2022, 47(3): 756-762.
ZHANG M Q, LOU X F, CHEN L B, et al. Isotherms and kinetics of pretilachlor adsorption onto organobentonites[J]. Journal of Guangxi University (Natural Science Edition), 2022, 47(3): 756-762 (in Chinese).
[9] SHISHKIN R, ARKHIPOVA V, ZHIRENKINA N, et al. Exploring graphite-based thermal greases for optimal microelectronic device cooling[J]. International Journal of Thermophysics, 2024, 45(10): 141.
[10] 曹明伦. 助分散剂极性对膨润土润滑脂性能的影响[J]. 合成润滑材料, 2024, 51(2): 17-22.
CAO M L. The influence of the polarity of auxiliary dispersant on the performance of bentonite-based lubricating greases[J]. Synthetic Lubricants, 2024, 51(2): 17-22 (in Chinese).
[11] 郑长文, 管俊芳, 郑佳敏, 等. 矿业领域膨润土应用的研究进展[J]. 矿产综合利用, 2020(3): 22-27.
ZHENG C W, GUAN J F, ZHENG J M, et al. Progress in the application of bentonite in mining industry[J]. Multipurpose Utilization of Mineral Resources, 2020(3): 22-27 (in Chinese).
[12] SHEN Z. Performance analysis of bentonite-PVA fiber cement-based composites for building based on BP neural network[J]. Key Engineering Materials, 2020, 852: 209-219.
[13] 郭宏斌. 膨润土浆液配比对软土地层CSM水泥土搅拌墙成墙质量影响[J]. 建筑施工, 2024, 46(3): 317-321.
GUO H B. Effect of bentonite slurry ratio on the quality of CSM cement-soil mixing wall in soft soil layer[J]. Building Construction, 2024, 46(3): 317-321 (in Chinese).
[14] DINIZ C V, NASCIMENTO J V, BINATTI I, et al. Hybrid catalysts based on waste electrical and electronic equipment supported on bentonite for the removal of contaminants compounds in liquid phase[J]. Catalysis Today, 2020, 344: 75-83.
[15] 周萍, 李明, 武元鹏. 聚合物/膨润土纳米复合材料的研究进展[J]. 功能材料, 2022, 53(7): 7058-7068.
ZHOU P, LI M, WU Y P. Research progress of polymer/bentonite nanocomposites[J]. Journal of Functional Materials, 2022, 53(7): 7058-7068 (in Chinese).
[16] 姜璐莎, 李超越, 卢光华, 等. 聚合物改性膨润土在阻隔屏障中酸碱盐条件下的防渗效果[J]. 太原理工大学学报, 2023, 54(6): 959-968.
JIANG L S, LI C Y, LU G H, et al. Hydraulic performance of polymer-modified bentonite in containment barriers under aggressive conditions[J]. Journal of Taiyuan University of Technology, 2023, 54(6): 959-968 (in Chinese).
[17] SCALIA J IV, BENSON C H, BOHNHOFF G L, et al. Long-term hydraulic conductivity of a bentonite-polymer composite permeated with aggressive inorganic solutions[J]. Journal of Geotechnical and Geoenvironmental Engineering, 2014, 140(3): 04013025.
[18] ONIKATA M, KONDO M, HAYASHI N, et al. Complex formation of cation-exchanged montmorillonites with propylene carbonate: osmotic swelling in aqueous electrolyte solutions[J]. Clays and Clay Minerals, 1999, 47(5): 672-677.
[19] DI EMIDIO G. Hydraulic and chemico-osmotic performance of polymer treated clays[D]. Ghent: Ghent University, 2010.
[20] MAZZIERI F, DI EMIDIO G, VAN IMPE P O. Diffusion of calcium chloride in a modified bentonite: impact on osmotic efficiency and hydraulic conductivity[J]. Clays and Clay Minerals, 2010, 58(3): 351-363.
[21] KOLSTAD D C, BENSON C H, EDIL T B. Hydraulic conductivity and swell of nonprehydrated geosynthetic clay liners permeated with multispecies inorganic solutions[J]. Journal of Geotechnical and Geoenvironmental Engineering, 2004, 130(12): 1236-1249.
[22] MUHAMMAD N, SIDDIQUA S. Calcium bentonite vs sodium bentonite: the potential of calcium bentonite for soil foundation[J]. Materials Today: Proceedings, 2022, 48: 822-827.
[23] 陆启财, 陈铁军, 罗艳红, 等. 低品位膨润土改性及其在球团中的应用研究[J]. 烧结球团, 2021, 46(3): 39-46.
LU Q C, CHEN T J, LUO Y H, et al. Research on modification of low-grade bentonite and its application in pellets[J]. Sintering and Pelletizing, 2021, 46(3): 39-46 (in Chinese).
[24] 马俊英, 杨静, 蔺尾燕, 等. 盐酸改性膨润土处理含镉废水的研究[J]. 应用化工, 2019, 48(2): 357-360.
MA J Y, YANG J, LIN W Y, et al. Study on treatment of cadmium wastewater by the acid modified bentonite[J]. Applied Chemical Industry, 2019, 48(2): 357-360 (in Chinese).
[25] 苏成政. 膨润土的改性及吸湿性能研究[J]. 中国非金属矿工业导刊, 2023(3): 55-57+60.
SU C Z. Modification and humidity adsorption property of bentonite[J]. China Non-metallic Minerals Industry, 2023(3): 55-57+60 (in Chinese).
[26] 武雷杰, 杨秀娟, 张路, 等. 聚合氯化铝(PAC)改性膨胀土的胀缩特性试验研究[J]. 长江科学院院报, 2020, 37(1): 84-89.
WU L J, YANG X J, ZHANG L, et al. Experimental study on swelling and shrinkage of polyaluminum chloride (PAC) modified expansive soil[J]. Journal of Yangtze River Scientific Research Institute, 2020, 37(1): 84-89 (in Chinese).
[27] 马锋锋, 牛雪妍. 磁性膨润土对甲基橙的吸附特性研究[J]. 水处理技术, 2023, 49(8): 71-76+81.
MA F F, NIU X Y. Adsorption of methyl orange on magnetic bentonite from aqueous solution[J]. Technology of Water Treatment, 2023, 49(8): 71-76+81 (in Chinese).
[28] MOCKOVĞIAKOVÁ A, OROLÍNOVÁ Z, ŠKVARLA J. Enhancement of the bentonite sorption properties[J]. Journal of Hazardous Materials, 2010, 180(1/2/3): 274-281.
[29] LACERDA E, MONTEIRO F C, KLOSS J R, et al. Bentonite clay modified with Nb₂O₅: an efficient and reused photocatalyst for the degradation of reactive textile dye[J]. Journal of Photochemistry and Photobiology A: Chemistry, 2020, 388: 112084.
[30] SONG R M, LI Z M, LI W L, et al. Improved adsorption and desorption behavior of Cd on thiol-modified bentonite grafted with cysteamine hydrochloride[J]. Research on Chemical Intermediates, 2022, 48(6): 2721-2744.
[31] GHEZALI S, MAHDAD-BENZERDJEB A, AMERI M, et al. Adsorption of 2,4,6-trichlorophenol on bentonite modified with benzyldimethyltetradecylammonium chloride[J]. Chemistry International, 2018, 4(1): 24-32.
[32] HE H J, XU E P, QIU Z H, et al. Phenol adsorption mechanism of organically modified bentonite and its microstructural changes[J]. Sustainability, 2022, 14(3): 1318.
[33] 蔡杰慧, 杨英全, 李致宝, 等. 改性蔗渣纤维素-海藻酸钙-膨润土微球制备及吸附[J]. 化学工程, 2024, 52(5): 39-45.
CAI J H, YANG Y Q, LI Z B, et al. Preparation and adsorption of modified bagasse cellulose-calcium alginate-bentonite microspheres[J]. Chemical Engineering (China), 2024, 52(5): 39-45 (in Chinese).
[34] EMIDIO G, MAZZIERI F, VERASTEGUI-FLORES R D, et al. Polymer-treated bentonite clay for chemical-resistant geosynthetic clay liners[J]. Geosynthetics International, 2015, 22(1): 125-137.
[35] CHIKWE T N, EWUZIE H E, NGOBIRI N C, et al. Competitive adsorption of xylene and toluene on modified and unmodified magnesium exchanged bentonite clay mineral[J]. Journal of Applied Sciences and Environmental Management, 2018, 22(3): 298.
[36] ABDELKRIM S, MOKHTAR A, DJELAD A, et al. Chitosan/Ag-bentonite nanocomposites: preparation, characterization, swelling and biological properties[J]. Journal of Inorganic and Organometallic Polymers and Materials, 2020, 30(3): 831-840.
[37] 范日东, 吴俊楠, 杨爱武, 等. 苯酚作用下有机改性膨润土化学相容性试验研究[J/OL]. 土木工程学报, 2023: 1-10 (2023-11-15) [2025-01-01]. https://kns.cnki.net/KCMS/detail/detail.aspx?filename=TMGC20231113005&dbname=CJFD&dbcode=CJFQ.
FAN R D, WU J N, YANG A W, et al. Experimental study on chemical compatibility of organically modified bentonite under the action of phenol[J/OL]. China Industrial Economics, 2023: 1-10 (2023-11-15) [2025-01-01]. https://kns.cnki.net/KCMS/detail/detail.aspx?filename=TMGC20231113005&dbname=CJFD&dbcode=CJFQ (in Chinese).
[38] 江旭, 刘全军, 纪慧超, 等. 不同改性膨润土对含磷废水的吸附试验研究[J]. 非金属矿, 2018, 41(2): 20-22.
JIANG X, LIU Q J, JI H C, et al. Adsorption experiment of different modified bentonites on wastewater containing phosphorus[J]. Non-Metallic Mines, 2018, 41(2): 20-22 (in Chinese).
[39] 许小龙, 刘兰俊. 膨润土钠化改性无机柱撑研究进展及应用[J]. 当代化工, 2013, 42(9): 1261-1263.
XU X L, LIU L J. Research progress and application of sodium modified and inorganic pillared bentonite[J]. Contemporary Chemical Industry, 2013, 42(9): 1261-1263 (in Chinese).
[40] 慕利梅, 王图锦, 曹琳, 等. 改性膨润土对水中磷和藻类的同步去除[J]. 环境污染与防治, 2023, 45(3): 310-315+321.
MU L M, WANG T J, CAO L, et al. Simultaneous removal of phosphorus and algae in water by modified bentonite[J]. Environmental Pollution & Control, 2023, 45(3): 310-315+321 (in Chinese).
[41] EL-NAGAR D A, SARY D H. Synthesis and characterization of nano bentonite and its effect on some properties of sandy soils[J]. Soil and Tillage Research, 2021, 208: 104872.
[42] 张泽雨, 周仲魁, 张益硕, 等. CTAB改性铁柱撑膨润土的制备及其对废水中低浓度铀(Ⅵ)的吸附性能研究[J]. 湿法冶金, 2023, 42(5): 522-531.
ZHANG Z Y, ZHOU Z K, ZHANG Y S, et al. Preparation of iron-pillared montmorillonite modified with CTAB and its adsorption properties for uranium(Ⅵ) adsorption from low-concentration wastewater[J]. Hydrometallurgy of China, 2023, 42(5): 522-531 (in Chinese).
[43] TANGESTANIFARD M, GHAZIASKAR H. Arenesulfonic acid-functionalized bentonite as catalyst in glycerol esterification with acetic acid[J]. Catalysts, 2017, 7(7): 211.
[44] MOTSHEKGA S C, RAY S S, ONYANGO M S, et al. Microwave-assisted synthesis, characterization and antibacterial activity of Ag/ZnO nanoparticles supported bentonite clay[J]. Journal of Hazardous Materials, 2013, 262: 439-446.
[45] 何建雄, 潘浣钰, 叶竹林, 等. 膨润土吸蓝量测定方法的改进[J]. 广东化工, 2017, 44(4): 116-117.
HE J X, PAN H Y, YE Z L, et al. Improvement on bentonite blue suction quantity determination method[J]. Guangdong Chemical Industry, 2017, 44(4): 116-117 (in Chinese).
[46] 吴涛, 韩书华, 张春光, 等. 电导法测定粘土矿物的阳离子交换容量[J]. 油田化学, 2002, 19(3): 205-207+221.
WU T, HAN S H, ZHANG C G, et al. Determination of cationic exchange capacity of clay minerals by conductometric titration[J]. Oilfield Chemistry, 2002, 19(3): 205-207+221 (in Chinese).
[47] 胡梦颖, 张鹏鹏, 徐进力, 等. CEC前处理系统——凯氏定氮仪快速测定土壤中的阳离子交换量[J]. 物探与化探, 2023, 47(2): 458-463.
HU M Y, ZHANG P P, XU J L, et al. Rapid determination of soil cation exchange capacity using a cation exchange capacity pretreatment system and a Kjeldahl apparatus[J]. Geophysical and Geochemical Exploration, 2023, 47(2): 458-463 (in Chinese).
[48] ABDULLAHI S, AUDU A. Comparative analysis on chemical composition of bentonite clays obtained from Ashaka and tango deposits in Gombe State, Nigeria[J]. ChemSearch Journal, 2017, 8(2): 35-40.
[49] 王泽龙, 李顺义, 吴朕君. 膨润土改性和复配及在废水处理中的应用进展[J]. 工业水处理, 2022, 42(2): 11-18.
WANG Z L, LI S Y, WU Z J. Application development of modification and compounding of bentonite in wastewater[J]. Industrial Water Treatment, 2022, 42(2): 11-18 (in Chinese).
[50] 曹春艳, 赵莹莹. 羟基铁柱撑膨润土处理含磷废水的研究[J]. 环境科学与技术, 2013, 36(4): 164-167+194.
CAO C Y, ZHAO Y Y. Disposal of phosphorus wastewater by hydroxyl Fe pillared bentonite[J]. Environmental Science & Technology, 2013, 36(4): 164-167+194 (in Chinese).
[51] KUMARARAJA P, SUVANA S, SARASWATHY R, et al. Mitigation of eutrophication through phosphate removal by aluminium pillared bentonite from aquaculture discharge water[J]. Ocean & Coastal Management, 2019, 182: 104951.
[52] MAHADEVAN H, ANOOP KRISHNAN K, PILLAI R R, et al. Stirring-ageing technique to develop zirconium-pillared bentonite clay along with its surface profiling using various spectroscopic techniques[J]. Research on Chemical Intermediates, 2020, 46(1): 639-660.
[53] RAVARI M H, SARRAFI A, TAHMOORESI M. Synthesizing and characterizing the mixed Al, Cu-pillared and copper doped Al-pillared bentonite for electrocatalytic reduction of CO₂[J]. South African Journal of Chemical Engineering, 2020, 31: 1-6.
[54] SUZUKI R. Effect of adding bentonite to porous silica via the sol-gel method[J]. ACS Omega, 2024, 9(9): 10577-10582.
[55] ROSTAMI-VARTOONI A, ALIZADEH M, BAGHERZADEH M. Green synthesis, characterization and catalytic activity of natural bentonite-supported copper nanoparticles for the solvent-free synthesis of 1-substituted 1H-1, 2, 3, 4-tetrazoles and reduction of 4-nitrophenol[J]. Beilstein Journal of Nanotechnology, 2015, 6: 2300-2309.
[56] GARCÍA-GARCÍA F A, CRISTIANI-URBINA E, MORALES-BARRERA L, et al. Spectroscopic and microestructural evidence for T-2 toxin adsorption mechanism by natural bentonite modified with organic cations[J]. Toxins, 2023, 15(7): 470.
[57] KLIMEK A, GAWEŁ A, GÓRNIAK K, et al. CO₂ sorption on Ti-, Zr-, and [Ti, Zr]-pillared montmorillonites[J]. Materials, 2024, 17(16): 4036.
[58] AUMNATE C, LIMPANART S, SOATTHIYANON N, et al. PP/organoclay nanocomposites for fused filament fabrication (FFF) 3D printing[J]. Express Polymer Letters, 2019, 13(10): 898-909.
[59] 姜葱葱, 高子栋, 李国忠. 用于墙体建筑节能的复合相变材料的试验研究[J]. 砖瓦, 2010(12): 10-12.
JIANG C C, GAO Z D, LI G Z. Study on composite phase change material in the energy-conservation wall[J]. Block-Brick-Tile, 2010(12): 10-12 (in Chinese).
[60] 李明珠. 砂型铸造发动机缸体表面粘砂研究[D]. 哈尔滨: 哈尔滨工业大学, 2017: 43-44.
LI M Z. Surface bonding sand of sand casting cylinder block[D]. Harbin: Harbin Institute of Technology, 2017: 43-44 (in Chinese).
[61] 马清亮. 磁性膨润土改性吸附材料的制备及其应用研究[D]. 太原: 太原理工大学, 2016: 69-70.
MA Q L. Synthesis of magnetic modified bentonite Adsorbents and its application[D]. Taiyuan: Taiyuan University of Technology, 2016: 69-70 (in Chinese).
[62] GHIDIU M, LUKATSKAYA M R, ZHAO M Q, et al. Conductive two-dimensional titanium carbide ‘clay’ with high volumetric capacitance[J]. Nature, 2014, 516(7529): 78-81.
[63] 刘冰. 改性膨润土对土壤中有机质的固定作用及其生物效应研究[D]. 泰安: 山东农业大学, 2023: 20-21.
LIU B. Study on the fixation effect of modified bentonite on soil organic matter and biological effects[D]. Taian: Shandong Agricultural University, 2023: 20-21 (in Chinese).
[64] 陈卫琴, 黄树梅, 李杨, 等. 改性膨润土对污水中重金属离子吸附实验研究[J]. 矿产综合利用, 2024(3): 50-57.
CHEN W Q, HUANG S M, LI Y, et al. Experimental study on the adsorption of heavy metal ions in wastewater by modified bentonite[J]. Multipurpose Utilization of Mineral Resources, 2024(3): 50-57 (in Chinese).
[65] 晏全香, 房博, 蓝灿文, 等. 改性膨润土矿物材料制备试验[J]. 福州大学学报(自然科学版), 2020, 48(2): 257-262.
YAN Q X, FANG B, LAN C W, et al. Preparation of modified bentonite mineral materials[J]. Journal of Fuzhou University (Natural Science Edition), 2020, 48(2): 257-262 (in Chinese).
[66] WERSIN P, HADI J, KICZKA M, et al. Unravelling the corrosion processes at steel/bentonite interfaces in in situ tests[J]. Materials and Corrosion, 2023, 74(11/12): 1716-1727.
[67] ADEBOJE A O, KUPOLATI W K, SADIKU E R, et al. Experimental investigation of modified bentonite clay-crumb rubber concrete[J]. Construction and Building Materials, 2020, 233: 117187.
[68] LI Z F, DONG H P, ZHANG Y L, et al. Enhanced removal of Ni(II) by nanoscale zero valent iron supported on Na-saturated bentonite[J]. Journal of Colloid and Interface Science, 2017, 497: 43-49.
[69] JÚNIOR R M S, DE OLIVEIRA T A, ARAQUE L M, et al. Thermal behavior of biodegradable bionanocomposites: influence of bentonite and vermiculite clays[J]. Journal of Materials Research and Technology, 2019, 8(3): 3234-3243.
[70] REITZEL K, ANDERSEN F Ø, EGEMOSE S, et al. Phosphate adsorption by lanthanum modified bentonite clay in fresh and brackish water[J]. Water Research, 2013, 47(8): 2787-2796.
[71] 强瑀. EDTA钙基膨润土的制备及其对铅锌矿区土壤重金属的修复效果[D]. 贵阳: 贵州师范大学, 2022.
QIANG Y. Preparation of EDTA calcium-based bentonite and its remediation effect on soil heavy metals in lead-zinc mine area[D]. Guiyang: Guizhou Normal University, 2022 (in Chinese).
[72] 孟兴锐. 巯基膨润土对水稻土中镉形态转化的影响研究[D]. 成都: 成都理工大学, 2019.
MENG X R. Effect of mercaptobentonite on speciation transformation of cadmium in paddy soil[D]. Chengdu: Chengdu University of Technology, 2019 (in Chinese).
[73] 张梦雪. 生物炭、膨润土、有机肥改良风沙土对土壤微生物量的影响研究[D]. 阜新: 辽宁工程技术大学, 2020.
ZHANG M X. Effect of biochar, organic fertilizer and bentonite on oil microbial iomass of aeolian sandy soil[D]. Fuxin: Liaoning Technical University, 2020 (in Chinese).
[74] 汤家喜, 李玉, 朱永乐, 等. 生物炭与膨润土对辽西北风沙土理化性质的影响研究[J]. 干旱区资源与环境, 2022, 36(3): 143-150.
TANG J X, LI Y, ZHU Y L, et al. Effect of biochar and bentonite on physicochemical properties of sandy soil in northwestern Liaoning province[J]. Journal of Arid Land Resources and Environment, 2022, 36(3): 143-150 (in Chinese).
[75] 李婧男, 孙向阳, 张贺, 等. 暗管排盐条件下园林废弃物与膨润土对滨海盐土的改良效果研究[J]. 应用基础与工程科学学报, 2021, 29(3): 562-574.
LI J N, SUN X Y, ZHANG H, et al. Study on the amelioration effect of garden waste and bentonite on coastal saline soil under subsurface drainage[J]. Journal of Basic Science and Engineering, 2021, 29(3): 562-574 (in Chinese).
[76] 马帅. 纳米级膨润土的改性制备及其性能研究[D]. 阜新: 辽宁工程技术大学, 2022.
MA S. Study on the modification, preparation and properties of nanoscale bentonite[D]. Fuxin: Liaoning Technical University, 2022 (in Chinese).
[77] 章青芳. 磁性膨润土的制备及其在水处理中的应用研究[D]. 太原: 太原理工大学, 2016.
ZHANG Q F. Study on modified preparation and properties of nano-bentonite[D]. Taiyuan: Taiyuan University of Technology, 2016 (in Chinese).
[78] VU T T T, NGUYEN N T T, DUONG L H, et al. Coaggregation assisted by cationic polyelectrolyte and clay minerals as a strategy for the removal of polystyrene microplastic particles from aqueous solutions[J]. Applied Clay Science, 2023, 233: 106820.
[79] HOU Y Z, WANG Y G, ZHU L, et al. Different inhibitory mechanisms of flexible and rigid clay minerals on the transport of microplastics in marine porous media[J]. Environmental Pollution, 2024, 356: 124246.
[80] HAN F, WANG Y, AN S Y, et al. Poly(dimethyldiallylammonium chloride)-modified magnetic bentonite for removal of polystyrene nanoplastics[J]. Journal of Environmental Chemical Engineering, 2024, 12(5): 114013.
[81] PUSCH R. Highly compacted sodium bentonite for isolating rock-deposited radioactive waste products[J]. Nuclear Technology, 1979, 45(2): 153-157.
[82] 叶为民, 王琼, 陈永贵, 等. 缓冲/回填材料: 砂-膨润土混合物研究进展[J]. 铀矿地质, 2010, 26(2): 95-100.
YE W M, WANG Q, CHEN Y G, et al. Advances in the research on buffer/backfilling materials: sand-bentonite mixture[J]. Uranium Geology, 2010, 26(2): 95-100 (in Chinese).
[83] 王文. 不同阳离子基膨润土在盐分作用下的膨胀特性[D]. 桂林: 桂林理工大学, 2021.
WANG W. Swelling characteristics of different cationic bentonites under salt solutions[D]. Guilin: Guilin University of Technology, 2021 (in Chinese).
[84] 陈龙. 复杂化学环境下膨润土膨胀变形研究[D]. 绵阳: 西南科技大学, 2021.
CHEN L. Study on the swelling deformation of bentonite in complex chemical environment[D]. Mianyang: Southwest University of Science and Technology, 2021 (in Chinese).
[85] 张东浩, 陈汉林, 蒋明俊, 等. 基于有机膨润土稠化剂润滑脂的制备工艺研究[J]. 重庆理工大学学报(自然科学), 2015, 29(8): 48-54.
ZHANG D H, CHEN H L, JIANG M J, et al. Study on preparation processes of bentonite grease based on ammonium-modified bentonite thickener[J]. Journal of Chongqing University of Technology (Natural Science), 2015, 29(8): 48-54 (in Chinese).
[86] 张卓翔. 膨润土和玄武岩纤维改性水泥砂浆性能的试验研究[D]. 重庆: 西南大学, 2022.
ZHANG Z X. Experimental study on properties of bentonite and basalt fiber modified cement mortar[D]. Chongqing: Southwest University, 2022 (in Chinese).
[87] 郑振. 水泥-膨润土复合固化污泥的强度及重金属迁移特性研究[D]. 抚州: 东华理工大学, 2022.
ZHENG Z. Study on the strength and heavy metal migration characteristics of cement-bentonite composite solidified sludge[D]. Fuzhou: East China Institute of Technology, 2022 (in Chinese).
[88] 廖松泽. 羟乙基纤维素丙烯酰胺改性膨润土钻井液的研制[D]. 抚顺: 辽宁石油化工大学, 2020.
LIAO S Z. Development of bentonite drilling fluid modified by hydroxyethyl cellulose acrylamide[D]. Fushun: Liaonign Shihua University, 2020 (in Chinese).
[89] 米红英, 郭小川, 杨庭栋, 等. 新型膨润土润滑脂的研制[J]. 石油学报(石油加工), 2009, 25(增刊1): 26-31.
MI H Y, GUO X C, YANG T D, et al. The development of a new bentonite grease[J]. Acta Petrolei Sinica (Petroleum Processing Section), 2009, 25(supplement 1): 26-31 (in Chinese).
[90] 张洁. 膨润土柔性防渗材料缓膨特性研究[D]. 天津: 天津大学, 2017.
ZHANG J. Research on delaying expansion of flexible anti-seepage materials with bentonite[D]. Tianjin: Tianjin University, 2017 (in Chinese).
[91] JAVED U, KHUSHNOOD R A, ALI MEMON S, et al. Sustainable incorporation of lime-bentonite clay composite for production of ecofriendly bricks[J]. Journal of Cleaner Production, 2020, 263: 121469.
[92] 胡倩, 景宜. 壳聚糖-膨润土微粒助留助滤体系性能的影响因素研究[J]. 中国造纸学报, 2019, 34(2): 25-32.
HU Q, JING Y. Research on factors affecting the efficiency of chitosan-bentonite microparticle retention system[J]. Transactions of China Pulp and Paper, 2019, 34(2): 25-32 (in Chinese).
[93] 袁明昆, 周景辉. (CSPI-PEI)-膨润土微粒助留助滤体系在废纸造纸中的应用[J]. 中国造纸, 2016, 35(4): 12-17.
YUAN M K, ZHOU J H. Application of CSPI-PEI-bentonite microparticle retention and drainage system in deinked pulp[J]. China Pulp & Paper, 2016, 35(4): 12-17 (in Chinese).
[94] FAVERO J, SANTOS V, WEISS-ANGELI V, et al. Evaluation and characterization of Melo Bentonite clay for cosmetic applications[J]. Applied Clay Science, 2019, 175: 40-46.
[95] BABAHOUM N, OULD HAMOU M. Characterization and purification of Algerian natural bentonite for pharmaceutical and cosmetic applications[J]. BMC Chemistry, 2021, 15(1): 50.
[96] 温鹏. 基于膨润土的保水型缓释氮肥的制备及其性能研究[D]. 石河子: 石河子大学, 2017.
WEN P. Synthesis and characterization of bentonite-based slow-release nitrogen fertilizers with the function of water retention[D]. Shihezi: Shihezi University, 2017 (in Chinese).
[97] AN X F, WU Z S, YU J Z, et al. Copyrolysis of biomass, bentonite, and nutrients as a new strategy for the synthesis of improved biochar-based slow-release fertilizers[J]. ACS Sustainable Chemistry & Engineering, 2020, 8(8): 3181-3190.
[98] YOMGIROVNA R G. Agrobiological properties of bentonite in agriculture[J]. Gospodarka I Innowacje, 2023, 40: 179-183.
[99] 王红斌, 冯桂权, 陈海云, 等. 金银花提取物缓释固体分散体的表征和释放行为研究[J]. 云南大学学报(自然科学版), 2011, 33(4): 458-462.
WANG H B, FENG G Q, CHEN H Y, et al. Characterization and releasing profile of extraction of honeysuckle sustained release solid dispersions[J]. Journal of Yunnan University (Natural Sciences Edition), 2011, 33(4): 458-462 (in Chinese).
[100] 姜丰艳. 含钠基膨润土的新方阿司匹林片的研制及其对胃黏膜保护作用研究[D]. 乌鲁木齐: 新疆医科大学, 2011.
JIANG F Y. New preseription aspirin with sodium bentonite tablets and its protective effect of gastric mucosa[D]. Urumqi: Xinjiang Medical University, 2011 (in Chinese).
[101] SHETTI N P, MALODE S J, NAYAK D S, et al. Hetero-nanostructured iron oxide and bentonite clay composite assembly for the determination of an antiviral drug acyclovir[J]. Microchemical Journal, 2020, 155: 104727.
[102] PRASHANTH S N, TERADAL N L, SEETHARAMAPPA J, et al. Fabrification of electroreduced graphene oxide-bentonite sodium composite modified electrode and its sensing application for linezolid[J]. Electrochimica Acta, 2014, 133: 49-56.
[103] ALI B, YUSUP S, QUITAIN A T, et al. Synthesis of novel graphene oxide/bentonite bi-functional heterogeneous catalyst for one-pot esterification and transesterification reactions[J]. Energy Conversion and Management, 2018, 171: 1801-1812.
[104] MOFRAD B, REZAEI M, HAYATI-ASHTIANI M. Preparation and characterization of Ni catalysts supported on pillared nanoporous bentonite powders for dry reforming reaction[J]. International Journal of Hydrogen Energy, 2019, 44(50): 27429-27444.
[105] ZHENG M, TAJVIDI M, TAYEB A H, et al. Effects of bentonite on physical, mechanical and barrier properties of cellulose nanofibril hybrid films for packaging applications[J]. Cellulose, 2019, 26(9): 5363-5379.
[106] RAZAVI S H, KAVUSSI A. The role of nanomaterials in reducing moisture damage of asphalt mixes[J]. Construction and Building Materials, 2020, 239: 117827.
[107] WANG Z, CHEN G H, WANG X R, et al. Removal of hexavalent chromium by bentonite supported organosolv lignin-stabilized zero-valent iron nanoparticles from wastewater[J]. Journal of Cleaner Production, 2020, 267: 122009.
[108] LI A, FENG W Q, CHEN Z J, et al. Investigation and analysis of the macro- and micro-responses of bentonite-sand mixtures to temperature[J]. Geomechanics for Energy and the Environment, 2024, 38: 100565.
[109] IACOB M, TIRON V, STIUBIANU G T, et al. Bentonite as an active natural filler for silicone leading to piezoelectric-like response material[J]. Journal of Materials Research and Technology, 2022, 17: 79-94.
[110] KHANSILI N, KRISHNA P M. Curcumin functionalized TiO₂ modified bentonite clay nanostructure for colorimetric Aflatoxin B1 detection in peanut and corn[J]. Sensing and Bio-Sensing Research, 2022, 35: 100480.