Effect of CeO2 Doping on Structure, Optical and Mechanical Properties of Bi2O3-B2O3-ZnO Glass Coatings

doi:10.16552/j.cnki.issn1001-1625.2025.0019

Abstract

Abstract: In order to improve the shielding range of Bi₂O₃-B₂O₃-ZnO glass coating in long-wave ultraviolet, and increase its surface hardness and modulus to achieve better protective effect, CeO₂ doped Bi₂O₃-B₂O₃-ZnO glass coating was prepared. The surface morphology of the coating was evaluated by DSC, SEM, Raman, FTIR, XPS and other test methods. The effects of different CeO₂ doping concentrations on the structure, optical and mechanical properties of Bi₂O₃-B₂O₃-ZnO glass coating were studied. The results show that when the doping concentration of CeO₂ is 0%~1.0% (molar fraction), the microhardness of coating reaches 6.9 GPa and the modulus reaches 84.0 GPa. When the CeO₂ doping concentration is 1.0%~2.5%, the polarization of Ce⁴⁺ and Ce³⁺ contained in CeO₂ reduces the microhardness and modulus of coating. At the same time, due to the change of glass structure, the conversion between Ce⁴⁺ and Ce³⁺ is promoted, and the ultraviolet shielding band of coatings with different CeO₂ doping concentrations is significantly different.

Key words: CeO₂, Bi₂O₃-B₂O₃-ZnO, glass coating, UV protection, hardness, modulus

CLC Number:

TQ171

SHAO Minglu, SHI Wangming, ZHANG Liang, LUO Lida, WANG Qingwei. Effect of CeO₂ Doping on Structure, Optical and Mechanical Properties of Bi₂O₃-B₂O₃-ZnO Glass Coatings[J]. BULLETIN OF THE CHINESE CERAMIC SOCIETY, 2025, 44(7): 2638-2646.

References

[1] SONG H. CASC released 2021 blue book of China aerospace science and technology[J]. Aerospace China, 2021, 22(4): 49-52.
[2] 四健. 星链计划的发展现状及其影响[J]. 电脑与信息技术, 2023, 31(3): 65-67.
SI J. The development status and impact of the starlink project[J]. Computer and Information Technology, 2023, 31(3): 65-67 (in Chinese).
[3] 刘嫒荣, 熊永清, 惠建江, 等. SpaceX星链卫星发布星历的研究[J]. 天文学报, 2024, 65(6): 42-61.
LIU A R, XIONG Y Q, HUI J J, et al. Research on starlink ephemeris published by SpaceX[J]. Acta Astronomica Sinica, 2024, 65(6): 42-61 (in Chinese).
[4] 乔佳, 胡旺旺. 原子氧和紫外辐射效应对空间光学系统沸石分子筛吸附性能的影响[J]. 航空材料学报, 2024, 44(3): 35-42.
QIAO J, HU W W. Effects of atomic oxygen and ultraviolet radiation on adsorption properties of zeolite in space optical system[J]. Journal of Aeronautical Materials, 2024, 44(3): 35-42 (in Chinese).
[5] QIU J Y, MONTECILLO R, CHEN P Y, et al. Development of the Al₂O₃-B₂O₃-SiO₂ glass for thermal barrier coating[J]. Journal of Non-Crystalline Solids, 2024, 626: 122785.
[6] FREDERICCI C, YOSHIMURA H N, MOLISANI A L, et al. Effect of TiO₂ addition on the chemical durability of Bi₂O₃-SiO₂-ZnO-B₂O₃ glass system[J]. Journal of Non-Crystalline Solids, 2008, 354(42/43/44): 4777-4785.
[7] BOBKOVA N M. Study of the properties of bismuth-borate systems toward low-melting lead-free glasses[J]. Glass Physics and Chemistry, 2012, 38(1): 180-183.
[8] AHMED S A, RAJIYA S, SAMEE M A, et al. Density of bismuth boro zinc glasses using machine learning techniques[J]. Journal of Inorganic and Organometallic Polymers and Materials, 2022, 32(3): 941-953.
[9] HE F, WANG J, DENG D. Effect of Bi₂O₃ on structure and wetting studies of Bi₂O₃-ZnO-B₂O₃ glasses[J]. Journal of Alloys and Compounds, 2011, 509: 6332-6336.
[10] SAYYED M I, MHAREB M H A, BETÜL CEVIZ Ş, et al. Experimental investigation of structural and radiation shielding features of Li₂O-BaO-ZnO-B₂O₃-Bi₂O₃ glass systems[J]. Radiation Physics and Chemistry, 2024, 218: 111640.
[11] FAN H Y, WANG G N, HU L L. Infrared, Raman and XPS spectroscopic studies of Bi₂O₃-B₂O₃-Ga₂O₃ glasses[J]. Solid State Sciences, 2009, 11(12): 2065-2070.
[12] 章健良, 聂秋华, 戴世勋, 等. Bi₂O₃-B₂O₃-Ga₂O₃玻璃的光学折射率和带隙研究[J]. 硅酸盐通报, 2010, 29(2): 340-344+351.
ZHANG J L, NIE Q H, DAI S X, et al. Refractive index and band gap investigation in Bi₂O₃-B₂O₃-Ga₂O₃ glass[J]. Bulletin of the Chinese Ceramic Society, 2010, 29(2): 340-344+351 (in Chinese).
[13] 康涛, 熊春荣, 符有杰, 等. m(ZnO)/m(B₂O₃)质量比对低熔点封接玻璃Bi₂O₃-B₂O₃-ZnO结构、性能与润湿性的影响[J]. 硅酸盐通报, 2024, 43(4): 1341-1349.
KANG T, XIONG C R, FU Y J, et al. Effect of m(ZnO)/m(B₂O₃) mass ratio on structure, properties and wettability of low melting point sealing glass Bi₂O₃-B₂O₃-ZnO[J]. Bulletin of the Chinese Ceramic Society, 2024, 43(4): 1341-1349 (in Chinese).
[14] ZAID M H M, MATORI K A, NAZRIN S N, et al. Synthesis, mechanical characterization and photon radiation shielding properties of ZnO-Al₂O₃-Bi₂O₃-B₂O₃ glass system[J]. Optical Materials, 2021, 122: 111640.
[15] YANG L, ZHU Y C, HUO J C, et al. Solubility and valence variation of Ce in low-alkali borosilicate glass and glass network structure analysis[J]. Materials, 2023, 16(14): 5063.
[16] EFIMOV A M, IGNATIEV A I, NIKONOROV N V, et al. Quantitative UV-Vis spectroscopic studies of photo-thermo-refractive glasses. II. manifestations of Ce³⁺ and Ce(IV) valence states in the UV absorption spectrum of cerium-doped photo-thermo-refractive matrix glasses[J]. Journal of Non-Crystalline Solids, 2013, 361: 26-37.
[17] SONTAKKE A D, UEDA J, TANABE S. Effect of synthesis conditions on Ce³⁺ luminescence in borate glasses[J]. Journal of Non-Crystalline Solids, 2016, 431: 150-153.
[18] SINGH G, KAUR P, KAUR S, et al. Investigation of structural, physical and optical properties of CeO₂-Bi₂O₃-B₂O₃ glasses[J]. Physical B: Condensed Matter, 2012, 407(21): 4168-4172.
[19] YU P, WANG R J, ZHAO D Q, et al. Anomalous temperature dependent elastic moduli of Ce-based bulk metallic glass at low temperatures[J]. Applied Physics Letters, 2007, 91(20): 201911.
[20] WHEELER D W, ZEKONYTE J, WOOD R J K. Mechanical properties of cerium and a cerium-5% lanthanum alloy by nanoindentation and ultrasonic velocity measurements[J]. Materials Science and Engineering: A, 2013, 578: 294-302.
[21] DU A D, LATTANZI L, JARFORS A W E, et al. On the hardness and elastic modulus of phases in SiC-reinforced Al composite: role of La and Ce addition[J]. Materials, 2021, 14(21): 6287.
[22] CHAHINE A, ET-TABIROU M, PASCAL J. FTIR and Raman spectra of the Na₂O-CuO-Bi₂O₃-P₂O₅ glasses[J]. Materials Letters, 2004, 58: 2776-2780.
[23] OPREA B, RADU T, SIMON S. XPS investigation of atomic environment changes on surface of B₂O₃-Bi₂O₃ glasses[J]. Journal of Non-Crystalline Solids, 2013, 379: 35-39.
[24] HINNEN C, MARCUS P. A comparative X-ray photoemission study of Bi₂Sr₂CaCu₂O_8+δ and Bi_1.6Pb_0.4Sr₂CaCu₂O_8+δ[J]. Journal of Electron Spectroscopy and Related Phenomena, 1995, 73 (3): 293-304.
[25] 赵田贵, 刘昆, 刘溧, 等. 汽车玻璃油墨用无铅低熔点玻璃的研究与制备[J]. 硅酸盐通报, 2023, 42(8): 2936-2944.
ZHAO T G, LIU K, LIU L, et al. Research and preparation of lead-free low-melting point glass for automobile glass enamel[J]. Bulletin of the Chinese Ceramic Society, 2023, 42(8): 2936-2944 (in Chinese).
[26] SANDHU A, SINGH N, KAUR R. Structural and optical properties of bismuth borosilicate glasses: effect of CeO₂ doping[J]. Applied Physics A, 2024, 130: 328.
[27] AZOOZ M A, SADDEEK Y B, ALY K A, et al. Optical, infrared spectral and mechanical investigations of CeO₂-doped borosilicate glasses containing Bi₂O₃ and TeO₂[J]. Journal of Inorganic and Organometallic Polymers and Materials, 2019, 29(5): 1680-1687.
[28] WANG P K, YE Y T, ZHAO G Y, et al. Understanding of distribution model and coordination structure of Dy³⁺ in B₂O₃-Bi₂O₃-SiO₂ glass based on Raman, infrared and XPS analysis[J]. Journal of Non-Crystalline Solids, 2024, 628: 122848.
[29] DYAMANT I, ITZHAK D, HORMADALY J. Thermal properties and glass formation in the SiO₂-B₂O₃-Bi₂O₃-ZnO quaternary system[J]. Journal of Non-Crystalline Solids, 2005, 351(43/44/45): 3503-3507.
[30] JIANG Y, WANG L, ZHANG W, et al. Dual-valence Ce doped UV-shielding glasses with high transparency and stability [J]. Ceramics International, 2020, 46(10): 16032-16037.
[31] SINGH S P, CHAKRADHAR R P S, RAO J L, et al. EPR, FTIR, optical absorption and photoluminescence studies of Fe₂O₃ and CeO₂ doped ZnO-Bi₂O₃-B₂O₃ glasses[J]. Journal of Alloys and Compounds, 2010, 493(1/2): 256-262.

Effect of CeO₂ Doping on Structure, Optical and Mechanical Properties of Bi₂O₃-B₂O₃-ZnO Glass Coatings

PDF (PC)

Knowledge

Abstract

Cite this article

share this article

References

Related Articles 15

Recommended Articles

Metrics

Comments

[1]	ZHANG Pu, QI Dongyou, WANG Xiaoke, CHEN Heyuan, HE Changyu, ZHANG Wei, XIE Yabin, ZHANG Dong. Mechanical and Microscopic Properties of Ferroaluminate Cement Concrete under Action of Seawater Dry-Wet Cycle [J]. BULLETIN OF THE CHINESE CERAMIC SOCIETY, 2025, 44(7): 2429-2436.
[2]	LIU Lin, SHAO Xin, PANG Kun, ZHENG Hongchen. Analysis of Factors Influencing Compressive Strength and Elastic Modulus of Alkali-Activated Slag-Fly Ash Concrete Based on Machine Learning [J]. BULLETIN OF THE CHINESE CERAMIC SOCIETY, 2025, 44(4): 1398-1407.
[3]	SU Zhuangfei, CHENG Yao, LIU Ze. Macroscopic Properties and Microscopic Properties of Slag-Modified Alkali-Activated Silicon-Manganese SlagCementitious Materials [J]. BULLETIN OF THE CHINESE CERAMIC SOCIETY, 2025, 44(4): 1276-1287.
[4]	CHEN Kaoxiang, WANG Mingzhong, RAO Yu, CUI Jialin, TAO Haizheng, LU Ping. Effect of ZnO on Crystallization and Properties of Spinel Glass-Ceramics [J]. BULLETIN OF THE CHINESE CERAMIC SOCIETY, 2024, 43(9): 3446-3454.
[5]	WANG Haitao, LIN Chen, FAN Zimin, TANG Mingqiang, ZHAO Fang, LE Chen, CHEN Yihua, HUANG Yuancheng. Effect of SiC Content on Properties of Aluminum Matrix Composite Materials [J]. BULLETIN OF THE CHINESE CERAMIC SOCIETY, 2024, 43(6): 2256-2261.
[6]	FANG Wanxian, ZENG Chen, ZHANG Ze, ZHANG Mingyu, HUANG Qizhong, GAO Ying. Sintering Property and Anti-Ablation Resistance of ZrB₂-SiC Ceramics Modified by CeO₂/MoSi₂ [J]. BULLETIN OF THE CHINESE CERAMIC SOCIETY, 2024, 43(5): 1937-1949.
[7]	ZHENG Weihong, LIU Guofeng, ZHANG Hao, WANG Qidong, ZHANG Menghao, YUAN Jian. Effect of Li₂O/Na₂O on Structure, Crystallization and Mechanical Properties of YAS Glass-Ceramics [J]. BULLETIN OF THE CHINESE CERAMIC SOCIETY, 2024, 43(4): 1292-1300.
[8]	KANG Tao, XIONG Chunrong, FU Youjie, CAI Banghui, WEI Shuguang, LI Junge, JIANG Hong. Effect of m(ZnO)/m(B₂O₃) Mass Ratio on Structure, Properties and Wettability of Low Melting Point Sealing Glass Bi₂O₃-B₂O₃-ZnO [J]. BULLETIN OF THE CHINESE CERAMIC SOCIETY, 2024, 43(4): 1341-1349.
[9]	MAO Jingyi, LIU Bing, GUO Zhenqiang, ZHANG Jiachang, YUAN Jian. Chemical Strengthening and Mechanical Properties of Flexible Glass [J]. BULLETIN OF THE CHINESE CERAMIC SOCIETY, 2024, 43(4): 1359-1365.
[10]	CHU Liusheng, ZHANG Peng, HE Yuexi, YUAN Chengfang, CHENG Zhanqi. Durability of Recycled Brick Powder ECC under Salt-Freezing Coupling Environment [J]. BULLETIN OF THE CHINESE CERAMIC SOCIETY, 2024, 43(3): 1012-1020.
[11]	XU Ye, TAO Junlin, LI Hongxiang. Prediction Model of Impact Splitting Tensile Strength of Concrete after Freeze-Thaw Cycle [J]. BULLETIN OF THE CHINESE CERAMIC SOCIETY, 2024, 43(2): 448-455.
[12]	TIAN Yingliang, HAN Jinlong, XU Bo, WEN Yulin, LI Peihao, HE Feng, ZHAO Zhiyong. Effect of Composition on Crystallization Properties of Yttrium Zirconate Nanocrystals in Sodium-Aluminum-Silicate Glass [J]. BULLETIN OF THE CHINESE CERAMIC SOCIETY, 2024, 43(2): 710-718.
[13]	XU Chenyang, ZHANG Zhizhu, ZHANG Pengfei, LI Qiuyi, KONG Zhe, GUO Yuanxin, CHEN Mingxu. Effect of Curing Process on Properties of Sand-Free Macroporous Recycled Concrete [J]. BULLETIN OF THE CHINESE CERAMIC SOCIETY, 2024, 43(11): 4019-4026.
[14]	PANG Jianyong, ZHENG Ruiqi, HU Xiuyue, SUN Jian, XU Guoping, SU Yongqiang. Effect of Cooling Method after High Temperature on Mechanical Properties of Basalt Fiber Reinforced Concrete [J]. BULLETIN OF THE CHINESE CERAMIC SOCIETY, 2024, 43(1): 92-101.
[15]	TIAN Yingliang, YUAN Zhichun, ZHAO Zhiyong, MU Guanghan, HE Feng. Preparation of Low Expansion Borosilicate Glass Based on Regeneration of Waste Liquid Crystal Glass and Its Physicochemical Properties [J]. BULLETIN OF THE CHINESE CERAMIC SOCIETY, 2024, 43(1): 354-362.