硝酸钙与柠檬酸复掺对铁铝酸盐水泥水化过程的影响

doi:10.16552/j.cnki.issn1001-1625.2025.0684

硅酸盐通报 ›› 2025, Vol. 44 ›› Issue (11): 4071-4079.DOI: 10.16552/j.cnki.issn1001-1625.2025.0684

硝酸钙与柠檬酸复掺对铁铝酸盐水泥水化过程的影响

李润康¹, 廖宜顺^1,2,3, 冯登宇¹, 周琦⁴, 李文华⁴, 李凌云⁴

1.武汉科技大学城市建设学院,武汉 430065;
2.城市更新湖北省工程研究中心,武汉 430065;
3.武汉科技大学高性能工程结构研究院,武汉 430065;
4.宜城安达特种水泥有限公司,襄阳 441415

收稿日期:2025-07-14 修订日期:2025-09-04 出版日期:2025-11-15 发布日期:2025-12-04
通信作者: 廖宜顺,博士,教授。E-mail:liaoyishun@wust.edu.cn
作者简介:李润康(2001—),男,硕士研究生。主要从事特种水泥的研究。E-mail:871855677@qq.com
基金资助:
国家重点研发计划(2025YFE0110200);湖北省青年科技人才项目(2023DJC182)

Composite Effect of Calcium Nitrate and Citric Acid on Hydration Process of Ferroaluminate Cement

LI Runkang¹, LIAO Yishun^1,2,3, FENG Dengyu¹, ZHOU Qi⁴, LI Wenhua⁴, LI Lingyun⁴

1. School of Urban Construction, Wuhan University of Science and Technology, Wuhan 430065, China;
2. Hubei Provincial Engineering Research Center of Urban Regeneration, Wuhan 430065, China;
3. Institute of High-Performance Engineering Structure, Wuhan University of Science and Technology, Wuhan 430065, China;
4. Yicheng Anda Special Cement Co., Ltd., Xiangyang 441415, China

Received:2025-07-14 Revised:2025-09-04 Published:2025-11-15 Online:2025-12-04

摘要/Abstract

摘要： 为实现铁铝酸盐水泥基材料早期强度快速发展并避免过快凝结,本研究探讨了硝酸钙与柠檬酸复掺对铁铝酸盐水泥水化过程与物理力学性能的影响。通过水化热、电阻率、流动度、凝结时间、抗压强度、水化产物和孔溶液电导率等分析测试,探讨了不同柠檬酸掺量对铁铝酸盐水泥水化的作用机理。结果表明,硝酸钙和柠檬酸复掺时,随着柠檬酸掺量增加,水泥浆体流动度显著提高,凝结时间延长,水化放热速率与电阻率增加速率降低,而孔溶液电导率显著高于空白组。当柠檬酸掺量从0.1%(质量分数)增大到0.3%时,硬化水泥浆体的28 d抗压强度从54.0 MPa减小到49.0 MPa,钙矾石(AFt)生成量显著减少。

关键词: 铁铝酸盐水泥, 硝酸钙, 柠檬酸, 抗压强度, 水化热, 电阻率

Abstract: In order to realize the rapid development of early strength of ferroaluminate cement-based materials and avoid excessive setting, this study investigated the effect of calcium nitrate and citric acid compound on the hydration process and physical-mechanical properties of ferroaluminate cement. Through the analysis and test of hydration heat, resistivity, fluidity, setting time, compressive strength, hydration products and pore solution conductivity, the mechanism of action of different citric acid content on the hydration of ferroaluminate cement was discussed. The results show that when calcium nitrate and citric acid are mixed, with the increase of citric acid content, the fluidity of cement paste increases significantly, the setting time is gradually prolonged, the hydration heat release rate and resistivity increase rate decrease, and the conductivity of pore solution is significantly higher than that of the control sample. When the content of citric acid increases from 0.1% (mass fraction) to 0.3%, the 28 d compressive strength of hardened cement paste decreases from 54.0 MPa to 49.0 MPa, and the formation of ettringite (AFt) decreases significantly.

Key words: ferroaluminate cement, calcium nitrate, citric acid, compressive strength, hydration heat, electrical resistivity

中图分类号:

TU528

李润康, 廖宜顺, 冯登宇, 周琦, 李文华, 李凌云. 硝酸钙与柠檬酸复掺对铁铝酸盐水泥水化过程的影响[J]. 硅酸盐通报, 2025, 44(11): 4071-4079.

LI Runkang, LIAO Yishun, FENG Dengyu, ZHOU Qi, LI Wenhua, LI Lingyun. Composite Effect of Calcium Nitrate and Citric Acid on Hydration Process of Ferroaluminate Cement[J]. BULLETIN OF THE CHINESE CERAMIC SOCIETY, 2025, 44(11): 4071-4079.

参考文献

[1] 郭东利, 齐冬有, 邱开建, 等. 铁铝酸盐水泥与高性能外加剂在核电工程中的适应性研究[J]. 混凝土与水泥制品, 2024(10): 53-57.
GUO D L, QI D Y, QIU K J, et al. Study on the adaptability of ferroaluminate cement and high performance admixture in nuclear power engineering[J]. China Concrete and Cement Products, 2024(10): 53-57 (in Chinese).
[2] 赵信达, 齐冬有, 侯刚连, 等. 矿物掺合料对铁铝酸盐水泥力学性能影响研究[J]. 中国建材科技, 2023, 32(6): 8-12.
ZHAO X D, QI D Y, HOU G L, et al. Effect of mineral admixture on mechanical properties of ferroaluminate cement[J]. China Building Materials Technology, 2023, 32(6): 8-12 (in Chinese).
[3] 廖宜顺, 叶建, 汤盛文. 海水拌和与偏高岭土对铁铝酸盐水泥水化的影响[J]. 硅酸盐学报, 2023, 51(11): 2834-2845.
LIAO Y S, YE J, TANG S W. Effect of mixing with seawater and metakaolin on hydration of ferroaluminate cement [J]. Journal of the Chinese Ceramic Society, 2023, 51(11): 2834-2845 (in Chinese).
[4] 刘斌. 玄武岩纤维改性铁铝酸盐水泥砂浆力学性能试验研究[J]. 铁道建筑技术, 2025(7): 58-61.
LIU B. Study on mechanical properties of ferroaluminate cement mortar modified by basalt fiber[J]. Railway Construction Technology, 2025(7): 58-61 (in Chinese).
[5] ZHANG Y H, WANG Y L, LI T B, et al. Effects of lithium carbonate on performances of sulphoaluminate cement-based dual liquid high water material and its mechanisms[J]. Construction and Building Materials, 2018, 161: 374-380.
[6] TAN H B, LI M G, HE X Y, et al. Effect of wet grinded lithium slag on compressive strength and hydration of sulphoaluminate cement system[J]. Construction and Building Materials, 2021, 267: 120465.
[7] CAU DIT COUMES C, DHOURY M, CHAMPENOIS J B, et al. Combined effects of lithium and borate ions on the hydration of calcium sulfoaluminate cement[J]. Cement and Concrete Research, 2017, 97: 50-60.
[8] BAJOLLE H, LAGADIC M, LOUVET N. The future of lithium-ion batteries: exploring expert conceptions, market trends, and price scenarios[J]. Energy Research & Social Science, 2022, 93: 102850.
[9] SUN X, OUYANG M G, HAO H. Surging lithium price will not impede the electric vehicle boom[J]. Joule, 2022, 6(8): 1738-1742.
[10] BOUDACHE S, LOUKILI A, IZORET L, et al. Investigating the role played by portlandite and C-A-S-H in the degradation response of pozzolanic and slag cements to external sulphate attack[J]. Journal of Building Engineering, 2023, 67: 106053.
[11] CHINDAPRASIRT P, KAMPALA A, JITSANGIAM P, et al. Effects of sulfate attack under wet and dry cycles on strength and durability of cement-stablized laterite[J]. Construction and Building Materials, 2023, 365: 129968.
[12] KIČAITĖ A, PUNDIENĖ I, SKRIPKIŨNAS G. The influence of calcium nitrate on setting and hardening rate of Portland cement concrete at different temperatures[J]. IOP Conference Series: Materials Science and Engineering, 2017, 251: 012017.
[13] KARAGÖL F, DEMIRBOĞA R, KAYGUSUZ M A, et al. The influence of calcium nitrate as antifreeze admixture on the compressive strength of concrete exposed to low temperatures[J]. Cold Regions Science and Technology, 2013, 89: 30-35.
[14] 李鹏飞, 赵天宏, 徐朝春. 缓凝剂对铁铝酸盐水泥性能的影响分析[J]. 浙江交通职业技术学院学报, 2022, 23(3): 16-20.
LI P F, ZHAO T H, XU C C. Analysis of the effect of retarder on the properties of ferroaluminate cement[J]. Journal of Zhejiang Institute of Communications, 2022, 23(3): 16-20 (in Chinese).
[15] 张普, 齐冬有, 王小可, 等. 海水干湿循环作用下铁铝酸盐水泥混凝土的力学性能和微观性能研究[J]. 硅酸盐通报, 2025, 44(7): 2429-2436.
ZHANG P, QI D Y, WANG X K, et al. Mechanical and microscopic properties of ferroaluminate cement concrete under action of seawater dry-wet cycle[J]. Bulletin of the Chinese Ceramic Society, 2025, 44(7): 2429-2436 (in Chinese).
[16] ZAJAC M, SKOCEK J, BULLERJAHN F, et al. Effect of retarders on the early hydration of calcium-sulpho-aluminate (CSA) type cements[J]. Cement and Concrete Research, 2016, 84: 62-75.
[17] 杜鹏, 叶正茂, 程新. 改性硼酸延缓硫铝酸盐水泥的凝结[J]. 济南大学学报, 2011, 25(2): 115-118.
DU P, YE Z M, CHENG X. Modified boracic acid retarding the set of sulphoaluminate cement[J]. Journal of Jinan University, 2011, 25(2): 115-118 (in Chinese).
[18] 巴明芳, 梁新奇, 卢梦洁, 等. 复合调凝组分对硫铝酸盐水泥性能的影响及机理[J]. 材料导报, 2015, 29(10): 133-136+142.
BA M F, LIANG X Q, LU M J,et al. Effects of composite coagulator on sulphoaluminate cement and the corresponding mechanism[J]. Materials Reports, 2015, 29(10): 133-136+142 (in Chinese).
[19] DAMION T, CEPURITIS R, CHAUNSALI P. Sulfuric acid and citric acid attack of calcium sulfoaluminate-based binders[J]. Cement and Concrete Composites, 2022, 130: 104524.
[20] 万子恒, 金子豪, 苏英, 等. 缓凝剂对磷石膏-硫铝酸盐水泥复合胶凝体系性能影响[J]. 硅酸盐通报, 2023, 42(6): 2131-2139.
WAN Z H, JIN Z H, SU Y, et al. Effects of retarders on properties of phosphogypsum-sulfoaluminate cement composite cementitious system[J]. Bulletin of the Chinese Ceramic Society, 2023, 42(6): 2131-2139 (in Chinese).
[21] HU Y Y, LI W F, MA S H, et al. Influence of borax and citric acid on the hydration of calcium sulfoaluminate cement[J]. Chemical Papers, 2017, 71(10): 1909-1919.
[22] 姚燕, 王宏霞, 刁桂芝, 等. 硝酸钙对铝酸盐水泥强度及水化性能的影响[J]. 硅酸盐学报, 2019, 47(2): 207-213.
YAO Y, WANG H X, DIAO G Z, et al. Effect of calcium nitrate on strength and hydration of calcium aluminate cement[J]. Journal of the Chinese Ceramic Society, 2019, 47(2): 207-213 (in Chinese).
[23] TAO Y X, RAHUL A V, MOHAN M K, et al. Recent progress and technical challenges in using calcium sulfoaluminate (CSA) cement[J]. Cement and Concrete Composites, 2023, 137: 104908.
[24] BULLERJAHN F, ZAJAC M, BEN HAHA M, et al. Factors influencing the hydration kinetics of ye’elimite; effect of mayenite[J]. Cement and Concrete Research, 2019, 116: 113-119.
[25] TANG S W, ZHU H G, LI Z J, et al. Hydration stage identification and phase transformation of calcium sulfoaluminate cement at early age[J]. Construction and Building Materials, 2015, 75: 11-18.
[26] WANG J R, ZHANG H B, GUO Y N, et al. Effect of different lime-anhydrite ratios on the hydration process of sulfoaluminate cement[J]. Journal of Materials in Civil Engineering, 2022, 34(10): 04022242.
[27] 周健, 李伟华, 皮振宇, 等. 硫铝酸盐水泥基材料抗碳化性能研究进展[J]. 硅酸盐通报, 2024, 43(8): 2711-2725.
ZHOU J, LI W H, PI Z Y, et al. Research progress on carbonation resistance of calcium sulfoaluminate cement-based materials[J]. Bulletin of the Chinese Ceramic Society, 2024, 43(8): 2711-2725 (in Chinese).
[28] 廖宜顺, 王思纯, 廖国胜, 等. 葡萄糖酸钠对硫铝酸盐水泥水化历程影响[J]. 材料导报, 2023, 37(9): 131-136.
LIAO Y S, WANG S C, LIAO G S, et al. Effect of sodium gluconate on hydration process of calcium sulfoaluminate cement[J]. Materials Reports, 2023, 37(9): 131-136 (in Chinese).
[29] ZHU H B, ZHOU H Y, GOU H X. Evaluation of carbon fiber dispersion in cement-based materials using mechanical properties, conductivity, mass variation coefficient, and microstructure[J]. Construction and Building Materials, 2021, 266: 120891.
[30] CHEN Y, ZHANG Y, ŠAVIJA B, et al. Fresh properties of limestone-calcined clay-slag cement pastes[J]. Cement and Concrete Composites, 2023, 138: 104962.
[31] 张琰, 黄业胜, 刘佳龙, 等. 硫铝酸盐水泥对硅酸盐水泥早期水化和力学性能的影响[J]. 硅酸盐通报, 2024, 43(10): 3552-3560+359.
ZHANG Y, HUANG Y S, LIU J L, et al. Effect of sulphoaluminate cement on early hydration and mechanical properties of Portland cement[J]. Bulletin of the Chinese Ceramic Society, 2024, 43(10): 3552-3560+359 (in Chinese).
[32] CHEN Z, LIAO Y S, DENG F, et al. Effect of calcium nitrate on hydration properties and strength development of calcium sulfoaluminate cement[J]. Construction and Building Materials, 2024, 421: 135770.

硝酸钙与柠檬酸复掺对铁铝酸盐水泥水化过程的影响

Composite Effect of Calcium Nitrate and Citric Acid on Hydration Process of Ferroaluminate Cement

PDF (PC)

可视化

摘要/Abstract

引用本文

使用本文

参考文献

相关文章 15

编辑推荐

Metrics

本文评价

[1]	李相国, 史湘琴, 安万东, 龚志雄, 张呈山, 吕阳. 铁相调控对高贝利特铁铝酸盐水泥性能的影响[J]. 硅酸盐通报, 2025, 44(9): 3127-3136.
[2]	蒋昊洋, 胡志德, 赵思勰, 张寒松, 许春霞. 环境温度对磷酸镁水泥水化温升的影响[J]. 硅酸盐通报, 2025, 44(9): 3147-3155.
[3]	叶纪盛, 马英, 李淯伟, 邰安, 王家豪. 早期CO₂养护对钢渣固废胶凝材料性能的影响[J]. 硅酸盐通报, 2025, 44(9): 3326-3336.
[4]	李义胜, 吕伟, 吴赤球, 余正康, 何静, 水中和. 高掺量磷石膏胶凝材料硬化体制备及其性能调节[J]. 硅酸盐通报, 2025, 44(8): 2944-2954.
[5]	杨阔, 王里, 李之建. 粘结剂喷射3D打印水泥基材料强度与精度协同优化研究[J]. 硅酸盐通报, 2025, 44(8): 2741-2751.
[6]	李杰, 李顺凯, 赵欢, 曾秦威. 纳米TiO₂改性发泡剂对泡沫混凝土性能的影响[J]. 硅酸盐通报, 2025, 44(8): 2839-2848.
[7]	胡建林, 李智林, 周永祥, 冷发光, 杜修力. 生石灰激发高炉矿渣-粉煤灰地质聚合物固化土力学特性研究[J]. 硅酸盐通报, 2025, 44(8): 2912-2923.
[8]	黄从斌, 邰洪生, 罗居刚. 预湿生物炭对超高性能混凝土自收缩和抗压强度的影响[J]. 硅酸盐通报, 2025, 44(7): 2458-2464.
[9]	吴庆勇, 赵爽, 韩斌, 王伟, 乔敏, 杜爽, 陈俊松. 铝硅复合微胶囊的制备及其在水泥基材料中的应用[J]. 硅酸盐通报, 2025, 44(7): 2388-2395.
[10]	张普, 齐冬有, 王小可, 陈鹤元, 何昌毓, 张巍, 谢亚斌, 张冬. 海水干湿循环作用下铁铝酸盐水泥混凝土的力学性能和微观性能研究[J]. 硅酸盐通报, 2025, 44(7): 2429-2436.
[11]	李志全, 张广田, 张艳佳, 贾彪, 刘东基, 张彪. 碱渣掺量对固废基胶凝材料性能的影响[J]. 硅酸盐通报, 2025, 44(7): 2597-2607.
[12]	房延凤, 马雪, 丁向群, 佟钰. 纳米C-A-S-H与DEIPA复掺对不同温度下水泥早期水化的影响[J]. 硅酸盐通报, 2025, 44(6): 1996-2004.
[13]	余海龙, 白文鼎, 刘梅芳, 胡力群, 暴英波. 玄武岩纤维对悬浮密实结构水泥稳定碎石力学性能的影响[J]. 硅酸盐通报, 2025, 44(6): 2343-2352.
[14]	马令勇, 刘艳东, 刘洋, 姜伟, 李清, 杜彬, 符恩民, 李栋. 水温与双氧水对发泡水泥性能及孔结构的影响[J]. 硅酸盐通报, 2025, 44(6): 1979-1987.
[15]	高永红, 李佳好, 金清平, 彭梦蜜. 高温后玄武岩纤维增强高强砂浆力学性能及抗氯离子渗透性能研究[J]. 硅酸盐通报, 2025, 44(6): 2016-2025.