基于响应面法的多固废基地聚合物配比优化及其表征

doi:10.16552/j.cnki.issn1001-1625.2024.0937

摘要/Abstract

摘要： 以燃煤渣、花岗岩石粉和高钙粉煤灰为主要原料,NaOH为激发剂制备地聚合物,在单因素试验的基础上,采用响应面法中的Box-Behnken Design模型,分析了不同固废质量掺比对地聚合物抗压强度的影响,并采用XRD、FTIR和SEM对地聚合物的物相组成与微观结构进行分析。研究表明,各固废质量掺比对响应值的影响顺序由大到小为高钙粉煤灰、燃煤渣、花岗岩石粉。其中花岗岩石粉与高钙粉煤灰交互作用显著。通过响应面优化后得到的最佳原料配比参数为燃煤渣质量掺比1.8、花岗岩石粉质量掺比0.8、高钙粉煤灰质量掺比7.0,该配比下地聚合物早期(7 d)平均抗压强度可达22.73 MPa。燃煤渣、花岗岩石粉和高钙粉煤灰通过地聚合反应相互协同生成无定形凝胶相与沸石类矿物,为地聚合物提供强度。花岗岩石粉和高钙粉煤灰的级配效应使地聚合物的结构更致密,该研究可为大宗量、多固废的协同处置应用提供参考。

关键词: 地聚合物, 响应面法, 抗压强度, 固废配比, 微观形貌

Abstract: In this paper, coal slag, granite powder and high calcium fly ash were used as the main raw materials, and NaOH was used as the activator to prepare geopolymer. On the basis of single factor experiment, the Box-Behnken Design model in response surface method was used to analyze the effects of different solid waste mass blending ratios on the compressive strength of geopolymer. The phase composition and microstructure of the geopolymer were analyzed by XRD, FTIR and SEM. The results show that the order of the influence of the mass ratio of each solid waste on the response value is high calcium fly ash, coal-fired slag, granite powder. The interaction between granite powder and high calcium fly ash is significant. The optimal raw material ratio parameters obtained by response surface optimization are as follows: the mass ratio of coal slag is 1.8, the mass ratio of granite powder is 0.8, and the mass ratio of high calcium fly ash is 7.0. Under this ratio, the average compressive strength of geopolymer at early stage (7 d) can reach 22.73 MPa. Coal slag, granite powder and high calcium fly ash cooperate with each other to form amorphous gel phase and zeolite minerals through geopolymerization reaction, which provides strength for geopolymer. The grading effect of granite powder and high calcium fly ash makes the structure of geopolymer denser. This study can provide a reference for the synergistic disposal of bulk and multi-solid waste.

Key words: geopolymer, response surface method, compressive strength, solid-waste ratio, microtopography

中图分类号:

X705

黄梓谕, 丁之尧, 曹丹, 沈锭, 姚瞬雨, 陈益人, 任衍增, 包申旭. 基于响应面法的多固废基地聚合物配比优化及其表征[J]. 硅酸盐通报, 2025, 44(2): 569-578.

HUANG Ziyu, DING Zhiyao, CAO Dan, SHEN Ding, YAO Shunyu, CHEN Yiren, REN Yanzeng, BAO Shenxu. Ratio Optimization and Characterization of Multi-Solid Waste-Based Geopolymer by Response Surface Method[J]. BULLETIN OF THE CHINESE CERAMIC SOCIETY, 2025, 44(2): 569-578.

参考文献

[1] 李博琦, 谢贤, 吕晋芳, 等. 粉煤灰资源化综合利用研究进展及展望[J]. 矿产保护与利用, 2020, 40(5): 153-160.
LI B Q, XIE X, LYU J F, et al. Progress and prospect of research on comprehensive utilization of fly ash[J]. Conservation and Utilization of Mineral Resources, 2020, 40(5): 153-160 (in Chinese).
[2] 王浩, 王晓佳, 桂峰, 等. 高炉矿渣资源化利用现状及展望[J]. 化工矿物与加工, 2021, 50(11): 48-53.
WANG H, WANG X J, GUI F, et al. The status and prospect of blast furnace slag resource utilization[J]. Industrial Minerals & Processing, 2021, 50(11): 48-53 (in Chinese).
[3] 廖桥, 彭博, 李碧雄. 炉渣建材资源化利用现状[J]. 重庆建筑, 2018, 17(3): 53-57.
LIAO Q, PENG B, LI B X. A review of resource utilization of slag building material[J]. Chongqing Architecture, 2018, 17(3): 53-57 (in Chinese).
[4] AMULYA G, ALI BAIG MOGHAL A, ALMAJED A. A state-of-the-art review on suitability of granite dust as a sustainable additive for geotechnical applications[J]. Crystals, 2021, 11(12): 1526.
[5] SAKA M B, HASHIM M H B M. Critical assessment of the effectiveness of different dust control measures in a granite quarry[J]. Journal of Public Health Policy, 2024, 45(2): 212-233.
[6] 黄涛, 张明, 吴保才, 等. 燃煤渣和花岗岩石粉协同制备地聚合物研究[J]. 非金属矿, 2022, 45(6): 86-89.
HUANG T, ZHANG M, WU B C, et al. Study on the co-preparation of geopolymer from burnt coal cinder and granite powder[J]. Non-Metallic Mines, 2022, 45(6): 86-89 (in Chinese).
[7] 刘森, 齐莉娜, 王泽祥, 等. 改性高钙粉煤灰水泥的各项性能研究[J]. 硅酸盐通报, 2018, 37(4): 1139-1145.
LIU S, QI L N, WANG Z X, et al. Properties of modified high calcium fly ash cement[J]. Bulletin of the Chinese Ceramic Society, 2018, 37(4): 1139-1145 (in Chinese).
[8] HUANG M Y, BAO S X, ZHANG Y M, et al. The combined effects of calcium oxide and phosphate on burnt coal cinder-based cementitious materials[J]. Construction and Building Materials, 2023, 362: 129720.
[9] ŞAHIN M, MAHYAR M, ERDOĞAN S T. Mutual activation of blast furnace slag and a high-calcium fly ash rich in free lime and sulfates[J]. Construction and Building Materials, 2016, 126: 466-475.
[10] JI Z H, PEI Y S. Bibliographic and visualized analysis of geopolymer research and its application in heavy metal immobilization: a review[J]. Journal of Environmental Management, 2019, 231: 256-267.
[11] LIU X M, LIU E P. The synergistic mechanism and stability evaluation of phosphogypsum and recycled fine powder-based multi-source solid waste geopolymer[J]. Polymers, 2023, 15(12): 2696.
[12] LI L, WEI Y J, LI Z L, et al. Rheological and viscoelastic characterizations of fly ash/slag/silica fume-based geopolymer[J]. Journal of Cleaner Production, 2022, 354: 131629.
[13] TURKANE S D, CHOUKSEY S K. Application of response surface method for optimization of stabilizer dosages in soil stabilization[J]. Innovative Infrastructure Solutions, 2021, 7(1): 106.
[14] LUO X, XU J Y, LI W M. Response surface design of solid waste based geopolymer[J]. RSC Advances, 2015, 5(2): 1598-1604.
[15] SILVA L C, DOS REIS FERREIRA R A, DE CASTRO MOTTA L A, et al. Optimization of metakaolin-based geopolymer composite using sisal fibers, response surface methodology, and canonical analysis[J]. International Journal of Advanced Engineering Research and Science, 2019, 6(4): 32-44.
[16] PEREZ J V D, NADRES E T, NGUYEN H N, et al. Response surface methodology as a powerful tool to optimize the synthesis of polymer-based graphene oxide nanocomposites for simultaneous removal of cationic and anionic heavy metal contaminants[J]. RSC Advances, 2017, 7(30): 18480-18490.
[17] MOHAMMED B S, HARUNA S, MUBARAK BN ABDUL WAHAB M, et al. Optimization and characterization of cast in situ alkali-activated pastes by response surface methodology[J]. Construction and Building Materials, 2019, 225: 776-787.
[18] DE OLIVEIRA L G, DE PAIVA A P, BALESTRASSI P P, et al. Response surface methodology for advanced manufacturing technology optimization: theoretical fundamentals, practical guidelines, and survey literature review[J]. The International Journal of Advanced Manufacturing Technology, 2019, 104(5): 1785-1837.
[19] ZHENG Z, MA X, ZHANG Z H, et al. In-situ transition of amorphous gels to Na-P1 zeolite in geopolymer: mechanical and adsorption properties[J]. Construction and Building Materials, 2019, 202: 851-860.
[20] 李胜, 张红日, 王桂尧, 等. 基于响应面法的碱激发地聚物固化淤泥质土试验研究[J]. 硅酸盐通报, 2023, 42(12): 4438-4448.
LI S, ZHANG H R, WANG G Y, et al. Experimental study of alkali-activated geopolymer cured silty soil based on response surface method[J]. Bulletin of the Chinese Ceramic Society, 2023, 42(12): 4438-4448 (in Chinese).
[21] 陈瑜, 丁婧雯, 吴思华. 基于响应面法的地聚合物预混料制备工艺优化[J]. 科学技术与工程, 2022, 22(17): 7119-7126.
CHEN Y, DING J W, WU S H. Optimization of preparation process of geopolymer premix based on response surface method[J]. Science Technology and Engineering, 2022, 22(17): 7119-7126 (in Chinese).
[22] 郭晓潞, 施惠生, 夏明. 不同钙源对地聚合物反应机制的影响研究[J]. 材料研究学报, 2016, 30(5): 348-354.
GUO X L, SHI H S, XIA M. Effect of different calcium resouces on reaction mechanism of geopolymer[J]. Chinese Journal of Materials Research, 2016, 30(5): 348-354 (in Chinese).
[23] 林弟, 刘大庆, 刘方, 等. 花岗岩石粉对水泥浆体流变特性的影响研究[J]. 建材世界, 2021, 42(5): 6-11.
LIN D, LIU D Q, LIU F, et al. Study on the influence of granite powder on rheological properties of cement paste[J]. The World of Building Materials, 2021, 42(5): 6-11 (in Chinese).
[24] 王威, 刘润清, 商晓阳. 超高性能混凝土的石英砂级配效应研究[J]. 混凝土, 2024(1): 128-133.
WANG W, LIU R Q, SHANG X Y. Quartz sand gradation effect of ultra-high performance concrete[J]. Concrete, 2024(1): 128-133 (in Chinese).
[25] MA Z M, DAN H C, TAN J W, et al. Optimization design of MK-GGBS based geopolymer repairing mortar based on response surface methodology[J]. Materials, 2023, 16(5): 1889.
[26] 翁履谦, SAGOE-CRENTSIL KWESI, 宋申华, 等. 地质聚合物合成中铝酸盐组分的作用机制[J]. 硅酸盐学报, 2005, 33(3): 276-280.
WENG L, KWESI S, SONG S H, et al. Hydrolysis kinetics of aluminates in geopolymers synthesis[J]. Journal of the Chinese Ceramic Society, 2005, 33(3): 276-280 (in Chinese).
[27] GUO X L, SHI H S, LIN M S, et al. Effects of calcium contents in class C fly ash geopolymer[J]. Advanced Materials Research, 2013, 687: 508-513.
[28] 胡芳芳, 张一敏, 陈铁军, 等. 石煤提钒尾渣制备地聚合物的试验研究[J]. 硅酸盐通报, 2013, 32(12): 2449-2454.
HU F F, ZHANG Y M, CHEN T J, et al. Experimental study on alkali-activated stone coal aciding vanadium tailings based geopolymer[J]. Bulletin of the Chinese Ceramic Society, 2013, 32(12): 2449-2454 (in Chinese).
[29] LEE W K W, VAN DEVENTER J S J. The effects of inorganic salt contamination on the strength and durability of geopolymers[J]. Colloids and Surfaces A: Physicochemical and Engineering Aspects, 2002, 211(2/3): 115-126.
[30] NATH S K. Geopolymerization behavior of ferrochrome slag and fly ash blends[J]. Construction and Building Materials, 2018, 181: 487-494.
[31] NATH S K, KUMAR S. Role of particle fineness on engineering properties and microstructure of fly ash derived geopolymer[J]. Construction and Building Materials, 2020, 233: 117294.
[32] 郑戈弋, 周海林, 黄青叶, 等. 燃煤渣花岗岩粉基地质聚合物的制备[J]. 有色金属(冶炼部分), 2022(9): 133-139.
ZHENG G Y, ZHOU H L, HUANG Q Y, et al. Preparation and performance characterization of granite powder-burnt coal cinder-based geoploymer[J]. Nonferrous Metals (Extractive Metallurgy), 2022(9): 133-139 (in Chinese).
[33] 范利丹, 杨杰, 余永强, 等. 基于响应面法的地聚合物注浆材料配合比优化及其微观结构分析[J]. 工业建筑, 2023, 53(6): 194-201.
FAN L D, YANG J, YU Y Q, et al. Mix proportion optimization and microstructure analysis for geopolymer grouting material based on response surface methodology[J]. Industrial Construction, 2023, 53(6): 194-201 (in Chinese).

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