钛酸钡与铌酸钾钠无铅压电陶瓷研究进展

硅酸盐通报 ›› 2024, Vol. 43 ›› Issue (2): 649-658.

所属专题：陶瓷

钛酸钡与铌酸钾钠无铅压电陶瓷研究进展

许明浩^1,2, 花开慧^1,3, 曾群², 邸博^1,3, 郑愚^1,3, 汪洪祥⁴, 张国祥⁴

1.东莞理工学院生态环境与建筑工程学院,东莞 523008;
2.华南师范大学信息光电子科技学院,广州 510006;
3.广东省城市生命线工程智慧防灾与应急技术重点实验室,东莞 523008;
4.中国港湾工程有限责任公司,北京 100027

收稿日期:2023-08-31 修订日期:2023-10-16 出版日期:2024-02-15 发布日期:2024-02-05
通信作者: 花开慧,博士,副教授。E-mail:huakh@dgut.edu.cn
作者简介:许明浩(1999—),男,硕士研究生。主要从事压电材料与器件的研究。E-mail:2399574546@qq.com
基金资助:
东莞市社会发展科技项目(重点项目)(20211800905302);粤澳科技创新联合资助(2022A0505020030);广东省基础与应用基础研究基金(19201910260000040);广东省联合培养研究生示范基地人才培养项目(粤教研函[2021]2号,粤教研函[2023]3号);松山湖科技特派员项目(20234418-01KCJ-G)

Research Progress of Barium Titanate and Potassium Sodium Niobate Lead-Free Piezoelectric Ceramics

XU Minghao^1,2, HUA Kaihui^1,3, ZENG Qun², DI Bo^1,3, ZHENG Yu^1,3, WANG Hongxiang⁴, ZHANG Guoxiang⁴

1. School of Environment and Civil Engineering, Dongguan University of Technology, Dongguan 523008, China;
2. School of Information and Optoelectronic Science and Engineering, South China Normal University, Guangzhou 510006, China;
3. Guangdong Provincial Key Laboratory of Intelligent Disaster Prevention and Emergency Technologies for Urban Lifeline Engineering, Dongguan 523008, China;
4. China Harbour Engineering Company Ltd., Beijing 100027, China

Received:2023-08-31 Revised:2023-10-16 Online:2024-02-15 Published:2024-02-05

摘要/Abstract

摘要： 钛酸钡(BaTiO₃)和铌酸钾钠(K_0.5Na_0.5NbO₃)压电陶瓷因具有环境友好、电学性能良好、居里温度较好等优势而成为国际高新技术材料研究的前沿热点,有望替代部分铅基压电陶瓷应用于国防、航空航天、通信等领域的电子器件中。本文综述了BaTiO₃和K_0.5Na_0.5NbO₃压电陶瓷材料的最新研究进展,从构造相界调控压电性能、BaTiO₃基压电陶瓷的材料体系设计、K_0.5Na_0.5NbO₃基压电陶瓷的热稳定性及改善、压电陶瓷的新型成型及烧结工艺等方面进行客观分析和总结,并展望了两种材料的未来发展趋势,为开发高性能无铅压电陶瓷提供参考。

关键词: 无铅压电陶瓷, K_0.5Na_0.5NbO₃, BaTiO₃, 相界, 热稳定性

Abstract: Barium titanate (BaTiO₃) and potassium sodium niobate (K_0.5Na_0.5NbO₃) piezoelectric ceramics have become the forefront of international high-tech materials research due to their environmental friendliness, excellent electrical properties and proper curie temperature, and were expected to replace some lead-based piezoelectric ceramics in electronic devices in the fields of national defense, aerospace and communications, etc. In this paper, the latest research progress of BaTiO₃ and K_0.5Na_0.5NbO₃ piezoelectric ceramic materials was reviewed, the aspect of constructing phase boundary to regulate the piezoelectric performance, designing the material system of BaTiO₃-based piezoelectric ceramics, the thermal stability and improvement of K_0.5Na_0.5NbO₃-based piezoelectric ceramics and the new molding and sintering process of piezoelectric ceramics were analyzed and summarized objectively. Finally, future development trend of the two kinds of materials was discussed, and a reference for the development of high-performance lead-free piezoelectric ceramics was provided.

Key words: lead-free piezoelectric ceramics, K_0.5Na_0.5NbO₃, BaTiO₃, phase boundary, thermal stability

中图分类号:

TQ174.7

许明浩, 花开慧, 曾群, 邸博, 郑愚, 汪洪祥, 张国祥. 钛酸钡与铌酸钾钠无铅压电陶瓷研究进展[J]. 硅酸盐通报, 2024, 43(2): 649-658.

XU Minghao, HUA Kaihui, ZENG Qun, DI Bo, ZHENG Yu, WANG Hongxiang, ZHANG Guoxiang. Research Progress of Barium Titanate and Potassium Sodium Niobate Lead-Free Piezoelectric Ceramics[J]. BULLETIN OF THE CHINESE CERAMIC SOCIETY, 2024, 43(2): 649-658.

参考文献

[1] ZHENG T, WU J G, XIAO D Q, et al. Recent development in lead-free perovskite piezoelectric bulk materials[J]. Progress in Materials Science, 2018, 98: 552-624.
[2] SEKHAR M C, VEENA E, KUMAR N S, et al. A review on piezoelectricmaterialsand their applications[J]. Crystal Research and Technology, 2023, 58(2): 2200130.
[3] JAFFE B, ROTH R S, MARZULLO S. Piezoelectric properties of lead zirconate-lead titanate solid-solution ceramics[J]. Journal of Applied Physics, 1954, 25(6): 809-810.
[4] DAMJANOVIC D. Contributions to the piezoelectric effect in ferroelectric single crystals and ceramics[J]. Journal of the American Ceramic Society, 2005, 88(10): 2663-2676.
[5] HENNINGS D. Barium titanate based ceramic materials for dielectric use[J]. International Journal of High Technology Ceramics, 1987, 3(2): 91-111.
[6] BECHMANN R. Elastic, piezoelectric, and dielectric constants of polarized Barium titanate ceramics and some applications of the piezoelectric equations[J]. The Journal of the Acoustical Society of America, 1956, 28(3): 347-350.
[7] LIU Y C, CHANG Y F, LI F, et al. Exceptionally high piezoelectric coefficient and low strain hysteresis in grain-oriented (Ba,Ca)(Ti,Zr)O₃ through integrating crystallographic texture and domain engineering[J]. ACS Applied Materials & Interfaces, 2017, 9(35): 29863-29871.
[8] YIN H M, XU W J, ZHOU H W, et al. Effects of phase composition and grain size on the piezoelectric properties of HfO₂-doped barium titanate ceramics[J]. Journal of Materials Science, 2019, 54(19): 12392-12400.
[9] RAWAT S, AGARWAL S, SINGH K C. Lead-free (Ba_0.88Ca_0.12)(Ti_0.94Sn_0.06)O₃ piezoceramics: a comprehensive analysis of the phase evolution and enhancement of electrical properties induced by high energy ball milling[J]. Materials Chemistry and Physics, 2022, 279: 125735.
[10] ZHANG Y M, YU Y G, ZHANG N, et al. Simultaneous realization of good piezoelectric and strain temperature stability via the synergic contribution from multilayer design and rare earth doping[J]. Advanced Functional Materials, 2023, 33(11): 2211439.
[11] LIU W F, REN X B. Large piezoelectric effect in Pb-free ceramics[J]. Physical Review Letters, 2009, 103(25): 257602.
[12] ZHAO C L, WU H J, LI F, et al. Practical high piezoelectricity in Barium titanate ceramics utilizing multiphase convergence with broad structural flexibility[J]. Journal of the American Chemical Society, 2018, 140(45): 15252-15260.
[13] WU J G. Perovskite lead-free piezoelectric ceramics[J]. Journal of Applied Physics, 2020, 127(19): 190901.
[14] BIJALWAN V, HUGHES H, POOLADVAND H, et al. The effect of sintering temperature on the microstructure and functional properties of BCZT-xCeO₂ lead free ceramics[J]. Materials Research Bulletin, 2019, 114: 121-129.
[15] WANG X J, HUAN Y, ZHU Y X, et al. Defect engineering of BCZT-based piezoelectric ceramics with high piezoelectric properties[J]. Journal of Advanced Ceramics, 2022, 11(1): 184-195.
[16] KOU Q W, YANG B, SUN Y, et al. Tetragonal (Ba,Ca)(Zr,Ti)O₃ textured ceramics with enhanced piezoelectric response and superior temperature stability[J]. Journal of Materiomics, 2022, 8(2): 366-374.
[17] JAIBAN P, THEETHUAN T, KHUMTRONG S, et al. The effects of donor (Nb⁵⁺) and acceptor (Cu²⁺, Zn²⁺, Mn²⁺, Mg²⁺) doping at B-site on crystal structure, microstructure, and electrical properties of (Ba_0.85Ca_0.15)Zr_0.1Ti_0.9O₃ ceramics[J]. Journal of Alloys and Compounds, 2022, 899: 162909.
[18] ZHOU C, ZHANG Q W, CAI W, et al. Cooling rate-dependent microstructure and electrical properties of BCZT ceramics[J]. Materials Science in Semiconductor Processing, 2022, 150: 106950.
[19] HUANG Y L, ZHAO C L, WU B, et al. Grain size effects and structure origin in high-performance BaTiO₃-based piezoceramics with large grains[J]. Journal of the European Ceramic Society, 2022, 42(6): 2764-2771.
[20] BIJALWAN V, TOFEL P, SPOTZ Z, et al. Processing of 0. 55(Ba_0.9Ca_0.1)TiO₃-0. 45Ba(Sn_0.2Ti_0.8)O₃ lead-free ceramics with high piezoelectricity[J]. Journal of the American Ceramic Society, 2020, 103(8): 4611-4624.
[21] GAIED A I, DAHRI A, PERRIN V, et al. Synergistic effects of Zn B-site substitution in lead-free Ba_0.95Ca_0.05Ti_0.92Sn_0.08O₃ ferroelectric ceramics for enhancing piezoelectric properties in energy harvesting applications[J]. Journal of Alloys and Compounds, 2023, 958: 170419.
[22] LAISHRAM R, RAJPUT S, SINGH K C. Particle-size-induced high piezoelectricity in (Ba_0.88Ca_0.12)(Ti_0.94Sn_0.06)O₃ piezoceramics prepared from nanopowders[J]. Journal of Alloys and Compounds, 2020, 812: 152128.
[23] HU X H, GAO J H, WANG Y, et al. Reversible domain-wall-motion-induced low-hysteretic piezoelectric response in ferroelectrics[J]. The Journal of Physical Chemistry C, 2019, 123(25): 15434-15440.
[24] WANG S F, LIU Q B, CAI E P, et al. Relaxor behavior and superior ferroelectricity of Y₂O₃-doped (Ba_0.98Ca_0.02)(Ti_0.94Sn_0.04Zr_0.02)O₃ lead-free ceramics[J]. Journal of Rare Earths, 2022, 40(6): 942-951.
[25] ZHAO T X, QIU J H, MA M G, et al. Electrical properties of Ba_0.96Ca_0.04Ti_0.90Sn_0.10O₃ lead-free ceramics with the addition of nano-CeO₂[J]. Journal of Nanoscience and Nanotechnology, 2019, 19(9): 5661-5666.
[26] BAEK J S, KOH J H. Distortion control of (1-x)Ba(Hf, Ti)O₃-x(Ba,Ca)TiO₃ piezoelectric ceramics to improved piezoelectric properties and related Curie temperature[J]. Journal of Alloys and Compounds, 2022, 898: 162811.
[27] WANG W, MA Y B, JING R Y, et al. Concentration-driving pinning effect in lead-free Mn-substituted BCZT ferroelectric ceramics[J]. Ceramics International, 2023, 49(20): 33324-33332.
[28] LIU C, MAO R Y, WU Q Y, et al. Modification of BCZT piezoelectric ceramics by modulating oxygen vacancies in different sintering atmospheres[J]. AIP Advances, 2023, 13(6): 065217.
[29] WANG X J, HUAN Y, JI S J, et al. Ultra-high piezoelectric performance by rational tuning of heterovalent-ion doping in lead-free piezoelectric ceramics[J]. Nano Energy, 2022, 101: 107580.
[30] LI C, BAEK J S, KOH J H. Ce and Y Co-doping effects for (Ba_0.85Ca_0.15)(Zr_0.1Ti_0.9)O₃ lead-free ceramics[J]. Coatings, 2021, 11(10): 1248.
[31] TIAN Y S, MA M Y, LI S Y, et al. Piezoelectricity and thermophysical properties of Ba_0.90Ca_0.10Ti_0.96Zr_0.04O₃ ceramics modified with amphoteric Nd³⁺ and Y³⁺ dopants[J]. Materials, 2023, 16(6): 2369.
[32] FU J, XIE A W, LI T Y, et al. Ultrahigh piezoelectricity in (Ba,Ca)(Ti,Sn)O₃ lead-free compounds with enormous domain wall contribution[J]. Acta Materialia, 2022, 230: 117862.
[33] PENG S Q, ZENG F F, WANG Y Y, et al. Structure and electrical properties in Sb-doped Ba_0.93Ca_0.07Ti_0.92Sn_0.08O₃ ceramics near the phase coexistence point[J]. Journal of Materials Science: Materials in Electronics, 2020, 31(19): 16235-16246.
[34] GUO F Y, CAI W, GAO R L, et al. Microstructure, enhanced relaxor-like behavior and electric properties of (Ba_0.85Ca_0.15)(Zr_0.1-xHf_xTi_0.9)O₃ ceramics[J]. Journal of Electronic Materials, 2019, 48(5): 3239-3247.
[35] CHEN K, MA J, WU J, et al. Large piezoelectric performance in zirconium doped Ba_0.86Sr_0.14TiO₃ lead-free ceramics through utilizing multiphase coexistence[J]. Journal of Materials Science: Materials in Electronics, 2019, 30(20): 18336-18341.
[36] WANG D W, FAN Z M, RAO G H, et al. Ultrahigh piezoelectricity in lead-free piezoceramics by synergistic design[J]. Nano Energy, 2020, 76: 104944.
[37] SHI J K, LIU J Y, XIE S X, et al. Dopant tuned multi-functionality in Barium titanate based lead-free piezoceramics[J]. Journal of Alloys and Compounds, 2023, 942: 169092.
[38] ZHAO C L, WU B, THONG H C, et al. Improved temperature stability and high piezoelectricity in lead-free Barium titanate-based ceramics[J]. Journal of the European Ceramic Society, 2018, 38(16): 5411-5419.
[39] WU W J, MA J, WANG N N, et al. Electrical properties, strain stability and electrostrictive behavior in 0.5BaZr_0.2Ti_0.8O₃-(0. 5-x)Ba_0.7Ca_0.3TiO₃-xBa_0.7Sr_0.3TiO₃ lead-free ceramics[J]. Journal of Alloys and Compounds, 2020, 814: 152240.
[40] CAI E P, LIU Q B, GU H Z. Optimization of the electrical properties on lead-free Barium titanate-based piezoelectric by combining grain growth with orthorhombic-tetragonal phase boundary[J]. Journal of Alloys and Compounds, 2023, 948: 169775.
[41] LV X, ZHU J G, XIAO D Q, et al. Emerging new phase boundary in potassium sodium-niobate based ceramics[J]. Chemical Society Reviews, 2020, 49(3): 671-707.
[42] TAO H, WU H J, LIU Y, et al. Ultrahigh performance in lead-free piezoceramics utilizing a relaxor slush polar state with multiphase coexistence[J]. Journal of the American Chemical Society, 2019, 141(35): 13987-13994.
[43] WU L J, ZHENG T, WU J G. Structural origin of excellent fatigue resistance in KNN-based ceramics with multiphase coexistence[J]. Journal of the European Ceramic Society, 2024, 44(1): 205-214.
[44] SAITO Y, TAKAO H, TANI T, et al. Lead-free piezoceramics[J]. Nature, 2004, 432(7013): 84-87.
[45] ZHANG N, ZHENG T, WU J G. Lead-free (K,Na)NbO₃-based materials: preparation techniques and piezoelectricity[J]. ACS Omega, 2020, 5(7): 3099-3107.
[46] WANG X P, WU J G, XIAO D Q, et al. Giant piezoelectricity in potassium-sodium niobate lead-free ceramics[J]. Journal of the American Chemical Society, 2014, 136(7): 2905-2910.
[47] XU K, LI J, LV X, et al. Superior piezoelectric properties in potassium-sodium niobate lead-free ceramics[J]. Advanced Materials, 2016, 28(38): 8519-8523.
[48] WU J G. Advances in lead-free piezoelectric materials[M]. Singapore: Springer, 2018.
[49] QI X C, REN P R, TONG X Q. Effect of heterovalent-ion doping and oxygen-vacancy regulation on piezoelectric properties of KNN based lead-free ceramics[J]. Ceramics International, 2023, 49(22): 34795-34804.
[50] LIU Q, PAN E, DENG H, et al. Enhanced piezoelectricity and non-contact optical temperature sensing performance in Er³⁺ ion modified (K,Na)NbO₃-based multifunctional ceramics[J]. Ceramics International, 2023, 49(10): 14981-14988.
[51] LIU T, CHEN Y, ZHENG Z S, et al. The high nano-domain improves the piezoelectric properties of KNN lead-free piezo-ceramics[J]. Ceramics International, 2023, 49(15): 25035-25042.
[52] LI R C, ZENG Y S, SUN X X, et al. Multidimensional synergy-induced high piezoelectricity and reliability KNN piezoceramics for high-frequency ultrasonic transducers[J]. Science China Materials, 2023, 66(2): 686-695.
[53] CEN Z Y, CAO F Z, FENG M Y, et al. Simultaneously improving piezoelectric strain and temperature stability of KNN-based ceramics via defect design[J]. Journal of the European Ceramic Society, 2023, 43(3): 939-946.
[54] HUAN Y, WANG X J, YANG W Y, et al. Optimizing energy harvesting performance by tailoring ferroelectric/relaxor behavior in KNN-based piezoceramics[J]. Journal of Advanced Ceramics, 2022, 11(6): 935-944.
[55] JIA P W, ZHENG Z S, LI Y L, et al. The achieving enhanced piezoelectric performance of KNN-based ceramics: decisive role of multi-phase coexistence induced by lattice distortion[J]. Journal of Alloys and Compounds, 2023, 930: 167416.
[56] HE B, LIU W P, ZHOU B W, et al. Softening effect of trace Fe-substituted potassium-sodium niobate-based lead-free piezoceramics[J]. Journal of Alloys and Compounds, 2022, 909: 164718.
[57] CHEN K, MA J, SHI C Y, et al. Enhanced temperature stability in high piezoelectric performance of (K,Na)NbO₃-based lead-free ceramics trough co-doped antimony and tantalum[J]. Journal of Alloys and Compounds, 2021, 852: 156865.
[58] XIE Y N, XING J, TAN Z, et al. High mechanical quality factor and piezoelectricity in potassium sodium niobate ceramics[J]. Ceramics International, 2022, 48(5): 6565-6573.
[59] XIE L X, CHEN H, XIE Y N, et al. The roles of Sn⁴⁺ in affecting performance of Potassium Sodium Niobate ceramics[J]. Journal of Alloys and Compounds, 2022, 899: 163290.
[60] SHI C Y, MA J, WU J, et al. Coexistence of excellent piezoelectric performance and high Curie temperature in KNN-based lead-free piezoelectric ceramics[J]. Journal of Alloys and Compounds, 2020, 846: 156245.
[61] QIAO L, LI G, TAO H, et al. Full characterization for material constants of a promising KNN-based lead-free piezoelectric ceramic[J]. Ceramics International, 2020, 46(5): 5641-5644.
[62] WU B, ZHAO L, MA J, et al. Insights into the correlation between ionic characteristics and microstructure and multiferroic properties in KNN-based ceramics with BiMO₃ modification[J]. Journal of Alloys and Compounds, 2023, 966: 171568.
[63] SALMANOV S, KOBLAR M, KMET B, et al. Structure and electrical properties of cold-sintered strontium-doped potassium sodium niobate[J]. Journal of the European Ceramic Society, 2023, 43(16): 7516-7523.
[64] TRIPATHY D, CHAKROBORTY S, GADTYA A S, et al. Enhanced dielectric and electrical performance of phosphonic acid-modified tantalum (Ta)-doped potassium sodium niobate (KNaNbO₃)-P(VDF-HFP) composites[J]. The European Physical Journal E, 2023, 46(3): 21.
[65] TAN L M, WANG X C, ZHU W J, et al. Excellent piezoelectric performance of KNNS-based lead-free piezoelectric ceramics through powder pretreatment by hydrothermal method[J]. Journal of Alloys and Compounds, 2021, 874: 159770.
[66] LV X, ZHANG N, MA Y C, et al. Coupling effects of the A-site ions on high-performance potassium sodium niobate ceramics[J]. Journal of Materials Science & Technology, 2022, 130: 198-207.
[67] ZHOU J S, WANG K, YAO F Z, et al. Multi-scale thermal stability of niobate-based lead-free piezoceramics with large piezoelectricity[J]. Journal of Materials Chemistry C, 2015, 3(34): 8780-8787.
[68] ZHANG M H, ZHANG Q H, YU T T, et al. Enhanced electric-field-induced strains in (K,Na)NbO₃ piezoelectrics from heterogeneous structures[J]. Materials Today, 2021, 46: 44-53.
[69] LV X, WU J G, ZHANG X X. A new concept to enhance piezoelectricity and temperature stability in KNN ceramics[J]. Chemical Engineering Journal, 2020, 402: 126215.
[70] HUANG Y L, ZHAO C L, WU B, et al. Diffused and successive phase transitions of (K,Na)NbO₃-based ceramics with high strain and temperature insensitivity[J]. Journal of the American Ceramic Society, 2019, 102(5): 2648-2657.
[71] YAO F Z, WANG K, JO W, et al. Diffused phase transition boosts thermal stability of high-performance lead-free piezoelectrics[J]. Advanced Functional Materials, 2016, 26(8): 1217-1224.
[72] HUO X T, WANG F C, ZHANG T H, et al. A dispersed polycrystalline phase boundary constructed in CaZrO₃ modified KNN based ceramics with both excellent piezoelectric properties and thermal stability[J]. Ceramics International, 2023, 49(10): 15751-15760.
[73] ZHOU C M, ZHANG J L, YAO W Z, et al. Highly temperature-stable piezoelectric properties of 0. 96(K_0.48Na_0.52)(Nb_0.96Sb_0.04)O₃-0. 03BaZrO₃-0. 01(Bi_0.50Na_0.50)ZrO₃ ceramic in common usage temperature range[J]. Scripta Materialia, 2019, 162: 86-89.
[74] YANG W W, LI P, LI F, et al. Enhanced piezoelectric performance and thermal stability of alkali niobate-based ceramics[J]. Ceramics International, 2019, 45(2): 2275-2280.
[75] LIU Q, ZHANG Y C, ZHAO L, et al. Simultaneous enhancement of piezoelectricity and temperature stability in (K,Na)NbO₃-based lead-free piezoceramics by incorporating perovskite zirconates[J]. Journal of Materials Chemistry C, 2018, 6(39): 10618-10627.
[76] DONG Z H, ZHAO P Y, MA X, et al. Excellent strain properties in (K,Na)NbO₃-based piezoceramics induced by lamination composite strategy[J]. Chemical Engineering Journal, 2023, 472: 144763.
[77] YI S L, ZHANG W K, GAO G P, et al. Structural design and properties of fine scale 2-2-2 PZT/epoxy piezoelectric composites for high frequency application[J]. Ceramics International, 2018, 44(9): 10940-10944.
[78] CHEN Z W, LI Z Y, LI J J, et al. 3D printing of ceramics: a review[J]. Journal of the European Ceramic Society, 2019, 39(4): 661-687.
[79] HE Z X, GONG X T, LIU C L, et al. Preparation and properties of (Ba_0.85Ca_0.15)(Ti_0.9Zr_0.1)O₃ lead-free ceramics via vat photopolymerization[J]. Additive Manufacturing, 2022, 59: 103170.
[80] RENTERIA A, BALCORTA V H, MARQUEZ C, et al. Direct ink write multi-material printing of PDMS-BTO composites with MWCNT electrodes for flexible force sensors[J]. Flexible and Printed Electronics, 2022, 7(1): 015001.
[81] MARIANI M, BELTRAMI R, MIGLIORI E, et al. Additive manufacturing of lead-free KNN by binder jetting[J]. Journal of the European Ceramic Society, 2022, 42(13): 5598-5605.
[82] WEI X X, LIU Y H, ZHAO D J, et al. 3D printing of piezoelectric Barium titanate with high density from milled powders[J]. Journal of the European Ceramic Society, 2020, 40(15): 5423-5430.

钛酸钡与铌酸钾钠无铅压电陶瓷研究进展

Research Progress of Barium Titanate and Potassium Sodium Niobate Lead-Free Piezoelectric Ceramics

PDF (PC)

可视化

摘要/Abstract

引用本文

使用本文

参考文献

相关文章 15

编辑推荐

Metrics

本文评价

[1]	郭威, 庞来学, 王文超, 张佳丽, 王华, 白书霞. 粉煤灰无溶剂法合成方钠石新方法及效果验证[J]. 硅酸盐通报, 2024, 43(2): 584-592.
[2]	薛兴勇, 韩要丛, 苏俏俏, 徐梦雪, 崔学民. 铜渣基磷酸盐胶凝材料的力学性能与微观结构[J]. 硅酸盐通报, 2023, 42(5): 1750-1757.
[3]	李玮, 周昌荣, 黎清宁, 李蕊, 侯凌浩, 孟天笑. Fe₂O₃原料的预处理对0.7BiFeO₃-0.3BaTiO₃陶瓷绝缘性与电性能的影响[J]. 硅酸盐通报, 2022, 41(6): 2126-2133.
[4]	王化中, 杨宇, 夏莉红, 尹成, 朱学宏, 丰雪帆, 张福勤. BaTiO₃改性对碳/碳复合材料力学性能的影响[J]. 硅酸盐通报, 2022, 41(3): 1002-1011.
[5]	戴书云, 钟诗琪, 张欢, 朱培树, 李甜, 刘杰, 郑兴华. X8R型BaTiO₃基细晶陶瓷的制备、结构和性能[J]. 硅酸盐通报, 2022, 41(12): 4412-4418.
[6]	郭宏伟, 白赟, CHI Longxing, 赵志龙, 刘帅, 王毅, 李荣悦. La₂O₃掺杂SiO₂-B₂O₃-Nb₂O₅复相微晶玻璃相界及储能性能研究[J]. 硅酸盐通报, 2022, 41(11): 3826-3833.
[7]	徐美姿, 王兵兵, 顾少轩, 黄欣, 陶海征. ZnO·Al₂O₃·nSiO₂玻璃抗裂纹萌生能力反常演化的结构起源探索[J]. 硅酸盐通报, 2022, 41(11): 4067-4074.
[8]	包国翠, 李坤, 杨光, 崔佳宁, 施东良, 林国豪, 方必军. 镧掺杂PMN-PT陶瓷在准同型相界处的相组成调控[J]. 硅酸盐通报, 2022, 41(10): 3647-3657.
[9]	李秀英, 陶歆月, 肖卓豪, 贺一峰, 李朝圆, 夏莹, 孔令兵. 高稳定性SrF₂-Na₂O-Fe₂O₃-P₂O₅体系氟磷酸盐玻璃的制备与表征[J]. 硅酸盐通报, 2022, 41(10): 3699-3707.
[10]	商珂, 王俊胜, 赵璧, 吴颖捷, 林贵德, 赵婧, 金星, 刘丹. 高固含量聚硅酸钾基防火凝胶及其在复合防火玻璃中的应用[J]. 硅酸盐通报, 2021, 40(4): 1344-1351.
[11]	袁高峰, 崔瑞瑞, 张鑫, 邓朝勇. Li⁺掺杂浓度对Sr₃ZnNb₂O₉:Eu³⁺荧光粉发光特性的影响[J]. 硅酸盐通报, 2021, 40(12): 4128-4136.
[12]	王力, 张增平, 朱友信, 刘浩, 陈俐企, 班孝义. PAPI型聚氨酯改性沥青性能与微观机理[J]. 硅酸盐通报, 2021, 40(12): 4158-4166.
[13]	孟保健, 朱永昌, 焦云杰, 赵崇, 万伟, 韩勖, 崔竹, 杨德博. 模拟高放废液玻璃固化体析晶性能研究[J]. 硅酸盐通报, 2021, 40(10): 3516-3522.
[14]	于长清;余悠然;赵英民;巢雄宇;袁武华. 稀土氧化物RE2O3(RE=La,Ce,Gd,Yb)掺杂氧化钇稳定氧化锆气凝胶相稳定性与晶粒生长分析[J]. 硅酸盐通报, 2020, 39(5): 1620-1626.
[15]	李争光;刘向春;邓韬;白宁娜;张叶雯. 熔融氯化盐传蓄热性能的研究[J]. 硅酸盐通报, 2020, 39(3): 950-956.