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硅酸盐通报 ›› 2023, Vol. 42 ›› Issue (9): 3412-3420.

• 道路材料 • 上一篇    

大掺量煤气化炉渣稳定基层混合料的制备及路用性能研究

李晓东1, 滕逸伟2,3, 赵建宁1, 闫升2, 杨建荣1, 贾小龙2,3   

  1. 1.国家能源集团宁夏煤业有限责任公司煤制油分公司,银川 750411;
    2.宁夏交通建设股份有限公司,银川 750004;
    3.宁夏交建交通科技研究院有限公司,银川 750004
  • 收稿日期:2023-04-09 修订日期:2023-06-20 出版日期:2023-09-15 发布日期:2023-09-14
  • 通信作者: 滕逸伟。E-mail:576188257@qq.com
  • 作者简介:李晓东(1975—),男,高级工程师。主要从事煤制油煤化工方向的研究。E-mail:15012217@ceic.com
  • 基金资助:
    宁夏回族自治区重点研发计划(2022BFE02006);2022年度交通运输部重点科技项目(2022-MS5-129);煤制油分公司2022年度自立项目(MZY-2022-05)

Preparation and Pavement Performance of High Dosage Coal Gasification Slag Stabilized Base Mixture

LI Xiaodong1, TENG Yiwei2,3, ZHAO Jianning1, YAN Sheng2, YANG Jianrong1, JIA Xiaolong2,3   

  1. 1. Ningxia Coal Industry Co., Ltd., National Energy Group Coal to Oil Branch Company, Yinchuan 750411, China;
    2. Ningxia Traffic Construction Co., Ltd., Yinchuan 750004, China;
    3. Ningxia Construction Transportation Technology Research Institute Co., Ltd., Yinchuan 750004, China
  • Received:2023-04-09 Revised:2023-06-20 Online:2023-09-15 Published:2023-09-14

摘要: 为解决传统砂石骨料供应不足、工业固废煤气化炉渣大量堆存的问题,本文利用煤气化炉渣、砂砾土制备路面基层材料,探究煤气化炉渣、水泥剂量与砂砾土掺配最佳比例,从力学性能、路用性能及耐久性能方面研究了水泥稳定煤气化炉渣路面基层材料在公路工程中应用的可行性。研究结果表明:最佳配比为煤气化炉渣和砂砾土的质量比为40%∶60%、水泥剂量7%,该配比下水泥稳定煤气化炉渣路面基层材料7 d无侧限抗压强度超过3.0 MPa,劈裂强度超过0.5 MPa,弯拉强度超过1.5 MPa,具有良好的抵抗竖向变形能力;经过5次冻融循环试验后,试件抗压强度损失比B均在90%以上,质量变化率小于5%,且水稳定性良好;经过180 d干缩试验,A组(煤气化炉渣掺量35%、水泥剂量6%)和C组(煤气化炉渣掺量40%、水泥剂量7%)试件累积干缩量均小于2.5 mm,具有较好的干缩应变。采用SEM、XRD观测煤气化炉渣路面基层材料的水化产物种类及空间分布特征,提出煤气化炉渣强度形成机理,得出主要水化产物为水化硅酸钙(C-S-H)凝胶、Ca(OH)2,有利于基层混合料强度的形成。

关键词: 煤气化炉渣, 路面基层材料, 力学性能, 耐久性能, C-S-H凝胶, 微观机理

Abstract: In order to solve the problem of insufficient supply of traditional sand and gravel aggregate and large storage of industrial solid waste coal gasification slag, this paper uses coal gasification slag and gravel soil to prepare pavement base materials, and explores the best proportion of coal gasification slag, cement content and gravel soil blending. The feasibility of the application of coal gasification slag pavement base material in highway engineering was studied from the aspects of mechanical properties, road performance and durability of the mixture. The results show that the optimal ratio is that the mass ratio of coal gasification slag to gravel soil is 40% to 60% and the cement content is 7%. Under this ratio, the 7 d unconfined compressive strength, splitting strength and flexural tensile strength of cement stabilized coal gasification slag pavement base material can reach above 3.0, 0.5 and 1.5 MPa, which has good vertical deformation resistance ability. After five freeze-thaw cycles, the compressive strength loss rate B of specimens is above 90%, the mass change rate is less than 5%, and the water stability is good. After 180 d of dry shrinkage test, the cumulative dry shrinkage of a group (coal gasification slag content of 35 % and cement content of 7%) and C group (coal gasification slag content of 40% and cement content of 7%)specimens are less than 2.5 mm, showing good dry shrinkage strain. The formation mechanism of coal gasification slag strength is put forward by observing the types and spatial distribution characteristics of hydration products of cement stabilized coal gasification slag base material with SEM and XRD. It is concluded that calcium silicate hydrate (C-S-H) gel and Ca(OH)2 are the main hydration products, which is conducive to the formation of strength of base mixture.

Key words: coal gasification slag, pavement base material, mechanical property, durability, C-S-H gel, microscopic mechanism

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