羟基化石墨烯对水泥基渗透结晶型防水材料力学性能的影响

硅酸盐通报 ›› 2023, Vol. 42 ›› Issue (5): 1569-1577.

所属专题：水泥混凝土

羟基化石墨烯对水泥基渗透结晶型防水材料力学性能的影响

张惠一¹, 桂尊曜², 蒲云东², 齐孟¹, 曹蔚琦^3,4, 袁小亚^2,4,5

1.重庆交通大学土木工程学院,重庆 400074;
2.重庆交通大学材料科学与工程学院,重庆 400074;
3.重庆大学光电工程学院光电技术及系统教育部重点实验室,重庆 401331;
4.重庆诺奖二维材料研究院有限公司,重庆 400044;
5.重庆交通大学先进功能材料研究所,重庆 400074

收稿日期:2022-11-29 修订日期:2023-03-08 出版日期:2023-05-15 发布日期:2023-06-01
通信作者: 袁小亚,博士,教授。E-mail:yuanxy@cqjtu.edu.cn
作者简介:张惠一(1998—),女,硕士研究生。主要从事纳米石墨烯水泥基复合材料方面的研究。E-mail:1056546914@qq.com
基金资助:
国家自然科学基金(51402030);重庆市基础科学与前沿技术研究专项基金(cstc2017jcyjBX0028);高端外国专家引进计划(G2022035007L); 重庆市国家自然科学基金(2022NSCQ-MSX1165);国家自然科学基金(51402030);重庆市基础科学与先进技术研究专项基金(cstc2017jcyjBX0028)

Effect of Hydroxylated Graphene on Mechanical Properties of Cement-Based Permeable Crystalline Waterproof Materials

ZHANG Huiyi¹, GUI Zunyao², PU Yundong², QI Meng¹, CAO Weiqi^3,4, YUAN Xiaoya^2,4,5

1. School of Civil Engineering, Chongqing Jiaotong University, Chongqing 400074, China;
2. College of Materials Science and Engineering, Chongqing Jiaotong University, Chongqing 400074, China;
3. Key Laboratory of Optoelectronic Technology & Systems Ministry of Education, Department of Optoelectronic Engineering, Chongqing University, Chongqing 401331, China;
4. Chongqing 2D Materials Institute, Chongqing 400044, China;
5. Institute of Advanced Functional Materials, Chongqing Jiaotong University, Chongqing 400074, China

Received:2022-11-29 Revised:2023-03-08 Online:2023-05-15 Published:2023-06-01

摘要/Abstract

摘要： 使用羟基化石墨烯(HO-G)改性水泥基渗透结晶型防水材料(CCCW),不仅能够提升结构整体的力学性能,还能在一定程度上降低成本。本文研究了木质素磺酸钠(SL)对HO-G分散能力的影响和HO-G对CCCW力学性能的影响。结果表明:当m(HO-G)∶m(SL)=1∶4时,HO-G在Ca(OH)₂中的分散性最佳;当HO-G掺量为0.03%(质量分数)时,HO-G砂浆试件的3、28 d抗压强度较基准试件分别提升了37.69%、33.05%,3、28 d抗折强度分别提升了17.31%、31.52%,HO-G改性后的CCCW涂层试件较单独掺加CCCW涂层试件的抗渗压力比提高了127个百分点;SL能够促进HO-G在水泥基材料中的分散,HO-G在砂浆基质中发挥了填充作用和模板作用,增强了水化产物的密实度,进而提高了材料的力学性能。

关键词: 水泥基材料, 羟基化石墨烯, 渗透结晶型防水材料, 分散性, 力学性能, 抗渗性能

Abstract: The use of hydroxylated graphene (HO-G) modified cement-based permeable crystalline waterproof materials (CCCW) not only improves the mechanical properties of whole structure, but also reduces the cost to a certain extent. The effect of sodium lignosulfonate(SL) on the dispersion performance of HO-G was studied, and the influence of HO-G on the mechanical properties of CCCW was studied. The results show that when the mass ratio of HO-G to SL is 1∶4, HO-G has the best dispersion performance in Ca(OH)₂. When HO-G content is 0.03% (mass fraction), compared with benchmark specimen, the 3 and 28 d compressive strength of HO-G mortar specimen increases by 37.69% and 33.05%, respectively and the 3 and 28 d flexural strength increases by 17.31% and 31.52%, respectively. The impermeability pressure ratio of CCCW coating specimens modified by HO-G is 127 percentage points higher than that of CCCW coating specimens alone. SL promotes the dispersion of HO-G in cement-based materials, and HO-G plays a filling role and template role in mortar matrix, which enhances the compactness of hydration products, and then improves the mechanical properties of material.

Key words: cement-based material, hydroxylated graphene, permeable crystalline waterproof material, dispersion performance, mechanical property, impermeability

中图分类号:

TU528

张惠一, 桂尊曜, 蒲云东, 齐孟, 曹蔚琦, 袁小亚. 羟基化石墨烯对水泥基渗透结晶型防水材料力学性能的影响[J]. 硅酸盐通报, 2023, 42(5): 1569-1577.

ZHANG Huiyi, GUI Zunyao, PU Yundong, QI Meng, CAO Weiqi, YUAN Xiaoya. Effect of Hydroxylated Graphene on Mechanical Properties of Cement-Based Permeable Crystalline Waterproof Materials[J]. BULLETIN OF THE CHINESE CERAMIC SOCIETY, 2023, 42(5): 1569-1577.

参考文献

[1] 王倩, 李建成. 竹纤维水泥基材料的物理力学性能研究[J]. 建材世界, 2022, 43(5): 9-13.
WANG Q, LI J C. Study on physical and mechanical properties of bamboo fiber cement-based materials[J]. The World of Building Materials, 2022, 43(5): 9-13 (in Chinese).
[2] 苗生龙, 周样梅, 陈奎宇, 等. 纳米材料对混凝土性能影响研究进展[J]. 混凝土与水泥制品, 2019(4): 20-23.
MIAO S L, ZHOU Y M, CHEN K Y, et al. Development progress of the influence of nano-materials on performance of concrete[J]. China Concrete and Cement Products, 2019(4): 20-23 (in Chinese).
[3] PRASEEDA D, SRINIVASA RAO K. Durability performance and micro-structure analysis of nano engineered blended concrete[J]. Cleaner Materials, 2022, 6: 100155.
[4] PRASEEDA D, RAO K S. Investigation of sulphate resistance of the nano reinforced blended concrete[J]. Cleaner Materials, 2022, 3: 100047.
[5] DIVYA S, PRAVEENKUMAR S, TAYEH B A. Performance of modified nano carbon blended with supplementary materials in cement composite: an interpretive review[J]. Construction and Building Materials, 2022, 346: 128452.
[6] 袁小亚, 杨雅玲, 周超, 等. 氧化石墨烯改性水泥砂浆力学性能及微观机理研究[J]. 重庆交通大学学报(自然科学版), 2017, 36(12): 36-42.
YUAN X Y, YANG Y L, ZHOU C, et al. Mechanical properties and microcosmic mechanism of cement mortar modified by graphene oxide[J]. Journal of Chongqing Jiaotong University (Natural Science), 2017, 36(12): 36-42 (in Chinese).
[7] 王宝民, 姜瑞双, 赵汝英. 石墨烯的分散性及石墨烯水泥基复合材料的研究进展[J]. 混凝土, 2016(12): 68-72+75.
WANG B M, JIANG R S, ZHAO R Y. Research progress of the dispersibility of graphene and graphene cement-based composite materials[J]. Concrete, 2016(12): 68-72+75 (in Chinese).
[8] REDDY P V R K, PRASAD D R. Investigation on the impact of graphene oxide on microstructure and mechanical behaviour of concrete[J].Journal of Building Pathology and Rehabilitation, 2022, 7(1): 1-10.
[9] 刘文娟. 氧化石墨烯改性混凝土的制备及力学性能和抗冻性能的研究[J]. 功能材料, 2022, 53(8): 8159-8164.
LIU W J. Preparation of graphene oxide modified concrete and research on mechanical properties and freezing resistance[J]. Journal of Functional Materials, 2022, 53(8): 8159-8164 (in Chinese).
[10] 程志海, 杨森, 袁小亚. 石墨烯及其衍生物掺配水泥基材料研究进展[J]. 复合材料学报, 2021, 38(2): 339-360.
CHENG Z H, YANG S, YUAN X Y. Research progress of cement-based materials blended with graphene and its derivatives[J]. Acta Materiae Compositae Sinica, 2021, 38(2): 339-360 (in Chinese).
[11] 杨雅玲, 袁小亚, 沈旭, 等. 氧化石墨烯改性水泥砂浆耐腐蚀性能的研究[J]. 功能材料, 2017, 48(5): 5144-5148.
YANG Y L, YUAN X Y, SHEN X, et al. Research on the corrosion resistance of graphene oxide on cement mortar[J]. Journal of Functional Materials, 2017, 48(5): 5144-5148 (in Chinese).
[12] YANG S, JIA W, WANG Y G, et al. Hydroxylated graphene: a promising reinforcing nanofiller for nanoengineered cement composites[J]. ACS Omega, 2021, 6(45): 30465-30477.
[13] 袁小亚, 高军, 王远贵, 等. 氧化石墨烯分散方式及其对水泥砂浆力学性能的影响[J]. 混凝土与水泥制品, 2020, 292(8): 18-22+26.
YUAN X Y, GAO J, WANG Y G, et al. Dispersion method of graphene oxide and its effect on mechanical properties of cement-based materials[J].China Concrete and Cement Products, 2020, 292(8): 18-22+26 (in Chinese).
[14] 侯路遥, 周长阳, 陈岩, 等. 腐殖酸和木质素磺酸钠对海底沉积物微生物燃料电池性能影响的比较研究[J]. 中国海洋大学学报(自然科学版), 2022, 52(s1): 36-41.
HOU L Y, ZHOU C Y, CHEN Y, et al. Comparative study of the effects of humic acid and sodium ligninsulfonate on the performance of marine sediments microbial fuel cells[J]. Periodical of Ocean University of China, 2022, 52(s1): 36-41 (in Chinese).
[15] HADDADI S A, RAMEZANZADEH M, HAJI NAGHI TEHRANI M E, et al. Sodium lignosulfonate-loaded ZnAl-layered double hydroxide decorated graphene oxide nanolayers: toward fabrication of sustainable nanocomposite for smart corrosion prevention[J]. Journal of Cleaner Production, 2022, 374: 133980.
[16] 刘刚, 梁精龙, 李慧. 木质素基生物质胶粘剂的研究进展及应用前景[J]. 化工新型材料, 2022, 50(12): 259-263.
LIU G, LIANG J L, LI H. Research progress and application prospects of lignin-based biomass adhesives[J]. New Chemical Materials, 2022, 50(12): 259-263 (in Chinese).
[17] 王明岳, 孔祥辉, 冉晋. 木质素改良低液限粉土相关性能试验研究[J]. 路基工程, 2019(6): 51-55.
WANG M Y, KONG X H, RAN J. Experimental study on properties of lignin improved low liquid limit silt[J]. Subgrade Engineering, 2019(6): 51-55 (in Chinese).
[18] 齐孟, 蒲云东, 杨森, 等. 氧化石墨烯对水泥基渗透结晶型防水材料抗渗性能的影响[J]. 复合材料学报, 2023, 40(3): 1598-1610.
QI M, PU Y D, YANG S, et al. Effect of graphene oxide on the impermeability of cementitious capillary crystalline waterproofing[J]. Acta Materiae Compositae Sinica, 2023, 40(3): 1598-1610 (in Chinese).
[19] 张二芹, 高剑秋. 水泥基渗透结晶型防水材料的研究现状[J]. 广东建材, 2022, 38(7): 23-26.
ZHANG E Q, GAO J Q. Research status of cement-based permeable crystalline waterproof materials[J]. Guangdong Building Materials, 2022, 38(7): 23-26 (in Chinese).
[20] 延永东, 高生宇, 姚嘉诚, 等. 复掺渗透结晶材料和纳米二氧化硅混凝土抗氯离子侵蚀性能研究[J]. 混凝土, 2022(7): 48-52+66.
YAN Y D, GAO S Y, YAO J C, et al. Study on chloride transportation properties of concrete containing cementitious capillary crystalline waterproofing and nano-silica[J]. Concrete, 2022(7): 48-52+66 (in Chinese).
[21] 刘梦路, 刘鹏, 余志武, 等. 水泥基渗透结晶型防水材料的作用机理及性能评价综述[J]. 新型建筑材料, 2022, 49(4): 135-140.
LIU M L, LIU P, YU Z W, et al. Review on the action mechanism and performance evaluation of cementitious capillary crystalline waterproofing materials[J]. New Building Materials, 2022, 49(4): 135-140 (in Chinese).
[22] 张艺腾, 杨进超, 赵维霞, 等. 水泥基渗透结晶型防水材料的微观结构与机理分析[J]. 新型建筑材料, 2017, 44(7): 68-70.
ZHANG Y T, YANG J C, ZHAO W X, et al. Microstructure and mechanism analysis of cement-based capillary crystalline waterproofing material[J]. New Building Materials, 2017, 44(7): 68-70 (in Chinese).
[23] 储伯良. 对水泥基渗透结晶型防水材料的重新认识[J]. 中国建筑防水, 2005(7): 14-16.
CHU B L. Reunderstanding cementitious capillary crystalline waterproofing materials[J]. China Building Waterproofing, 2005(7): 14-16 (in Chinese).
[24] 李晓光, 徐波. 掺CCCW桥面防水混凝土抗冻与抗渗性试验研究[J]. 山西建筑, 2009, 35(30): 171-173.
LI X G, XU B. The experimental study on the frost resistance and impermeability of water proofing concrete of mixed CCCW bridge surface[J]. Shanxi Architecture, 2009, 35(30): 171-173 (in Chinese).[25] 中国建筑材料科学研究总院. 水泥胶砂流动度测定方法: GB/T 2419—2005[S]. 北京: 中国标准出版社, 2005.
China Building Materials Academy. Test method for fluidity of cement mortar: GB/T 2419—2005[S]. Beijing: Standards Press of China, 2005 (in Chinese).
[26] 中国建筑材料科学研究总院. 水泥胶砂强度检验方法(ISO法): GB/T 17671—2021[S].北京:中国标准出版社, 2022.
China Building Materials Academy. Test method of cement mortar strength(ISO method): GB/T 17671—2021[S]. Beijing: Standards Press of China, 2022 (in Chinese).
[27] 建筑材料工业技术监督研究中心. 水泥基渗透结晶型防水材料: GB 18445—2012[S]. 北京: 化学工业出版社, 2013.
Technical Supervision & Research Center for China Building Materials Industry. Cementitious capillary crystalline waterproof material: GB 18445—2012[S]. Beijing: Chemical Industry Press, 2013 (in Chinese).
[28] 中国建筑材料科学研究总院. 砂浆、混凝土防水剂: JC 474—2008[S]. 北京: 中国建材工业出版社, 2008.
China Building Materials Academy. Mortar, concrete waterproofing agent: JC 474—2008[S]. Beijing: China Architecture & Building Press, 2008 (in Chinese).

羟基化石墨烯对水泥基渗透结晶型防水材料力学性能的影响

Effect of Hydroxylated Graphene on Mechanical Properties of Cement-Based Permeable Crystalline Waterproof Materials

PDF (PC)

可视化

摘要/Abstract

引用本文

使用本文

参考文献

相关文章 15

编辑推荐

Metrics

本文评价

[1]	陈宇, 林熙杰, 李长辉, 吴堃, 黄信. 抗收缩工程水泥基复合材料力学性能研究[J]. 硅酸盐通报, 2023, 42(5): 1599-1607.
[2]	李传习, 夏雨航, 王圣杰, 邓帅, 蒋健. 初凝超30min超早强UHPC制备及其机理[J]. 硅酸盐通报, 2023, 42(5): 1630-1639.
[3]	张晓静, 王德志, 靳凯戎, 刘江, 关岩. 花岗岩石粉对水泥浆体力学性能的影响[J]. 硅酸盐通报, 2023, 42(5): 1704-1709.
[4]	杜新宇, 陈潇, 周明凯, 张浩宇, 杨寅, 王瑜德. 含硫酸盐类固废对硅酸盐水泥水化影响研究[J]. 硅酸盐通报, 2023, 42(5): 1710-1720.
[5]	薛兴勇, 韩要丛, 苏俏俏, 徐梦雪, 崔学民. 铜渣基磷酸盐胶凝材料的力学性能与微观结构[J]. 硅酸盐通报, 2023, 42(5): 1750-1757.
[6]	隋洪宇, 李林, 温婧, 李芳芳, 姜涛. 硼泥焙烧预处理制备硫氧镁水泥[J]. 硅酸盐通报, 2023, 42(5): 1758-1766.
[7]	陈尚鸿, 林佳福, 杨政险, 张勇, 熊晓立. 钢渣-矿渣透水混凝土力学性能的试验研究[J]. 硅酸盐通报, 2023, 42(5): 1767-1777.
[8]	姚凯, 李青, 王鹏淮, 陈平, 李俊潼, 明阳. 硬脂酸钠对碱激发矿渣-赤泥胶凝材料吸水速率的影响[J]. 硅酸盐通报, 2023, 42(5): 1778-1784.
[9]	周丽娜, 蔡颖, 马财龙, 罗玲. 水滑石复合水泥基材料氯离子吸附能力的研究进展[J]. 硅酸盐通报, 2023, 42(4): 1137-1147.
[10]	陈娅, 万小梅, 崔允铮, 李辉. 纤维表面改性对EGC力学性能的影响[J]. 硅酸盐通报, 2023, 42(4): 1174-1182.
[11]	梁锐, 孔森, 张琰, 刘佳龙. 梳状纳米二氧化硅分散液的制备及对水泥基材料性能的提升[J]. 硅酸盐通报, 2023, 42(4): 1183-1193.
[12]	张虹宇, 郑玉龙, 陆春华. 两种养护制度下C100高强混凝土韧性对比试验研究[J]. 硅酸盐通报, 2023, 42(4): 1252-1259.
[13]	张劲竹, 刘华新, 王家贺, 柳根金, 王学志. 混杂纤维混凝土高温后性能劣化分析与强度预测[J]. 硅酸盐通报, 2023, 42(4): 1260-1269.
[14]	姜晓丹, 孙梦琪, 刘昂, 王攀, 侯东帅. 碳化对环氧树脂与混凝土界面黏结性能影响的分子模拟研究[J]. 硅酸盐通报, 2023, 42(4): 1291-1297.
[15]	胡彪, 李先海, 晏祥政, 赵永庆. 热活化煤矸石粉对基体-骨料界面过渡区性能的影响[J]. 硅酸盐通报, 2023, 42(4): 1315-1322.