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硅酸盐通报 ›› 2023, Vol. 42 ›› Issue (4): 1315-1322.

所属专题: 资源综合利用

• 资源综合利用 • 上一篇    下一篇

热活化煤矸石粉对基体-骨料界面过渡区性能的影响

胡彪1,2,3, 李先海1,2,3, 晏祥政1,2,3, 赵永庆1,2,3   

  1. 1.贵州大学矿业学院,贵阳 550025;
    2.喀斯特地区优势矿产资源高效利用国家地方联合工程实验室,贵阳 550025;
    3.贵州省非金属矿产资源综合利用重点实验室,贵阳 550025
  • 收稿日期:2022-11-09 修订日期:2023-01-03 出版日期:2023-04-15 发布日期:2023-04-25
  • 通信作者: 李先海,博士,高级实验师。E-mail:xhli1@gzu.edu.cn
  • 作者简介:胡 彪(2001—),男。主要从事难选矿石的选矿及资源综合利用的研究。E-mail:m15985037377@163.com
  • 基金资助:
    大学生创新创业训练计划(贵大(国)创字2022(033));贵州大学大学生“SRT计划”(贵大SRT字(2022)327号);贵州大学引进人才科研项目(贵大人基合字(2021)77号)

Influence of Thermal Activated Coal Gangue Powder on Properties of Interface Transition Zone Between Matrix and Aggregate

HU Biao1,2,3, LI Xianhai1,2,3, YAN Xiangzheng1,2,3, ZHAO Yongqing1,2,3   

  1. 1. Mining College, Guizhou University, Guiyang 550025, China;
    2. National & Local Joint Laboratory of Engineering for Effective Utilization of Regional Mineral Resources from Karst Areas, Guiyang 550025, China;
    3. Guizhou Key Lab of Comprehensive Utilization of Non-Metallic Mineral Resources, Guiyang 550025, China
  • Received:2022-11-09 Revised:2023-01-03 Online:2023-04-15 Published:2023-04-25

摘要: 煤矸石是煤炭工业产生的固体废弃物,持续产生及长期堆存会对环境产生一定影响,亟需开展资源化利用研究。以贵州黔西市煤矸石为研究对象,以粗粒级煤矸石为骨料,热活化后细粒级煤矸石为矿物掺合料,采用微机控制抗压抗折试验机、显微硬度仪、扫描电子显微镜研究热活化煤矸石粉对基体-骨料界面过渡区性能的影响。结果表明:随着热活化煤矸石粉掺量的增加,胶砂试块的抗折强度和抗压强度均先升高后降低,质量分数为2.5%的热活化煤矸石粉对胶砂试块力学性能具有提升作用,能够减小界面过渡区宽度,提高界面过渡区显微硬度,同时密实界面结构;随着热活化煤矸石粉掺量进一步增加,界面过渡区宽度反而增大,微孔数量和尺寸也增加,部分胶凝物质呈团状附着在煤矸石骨料表面,进而对胶砂力学性能产生不利影响。

关键词: 煤矸石, 热活化, 界面过渡区, 力学性能, 显微硬度, 微观结构

Abstract: Coal gangue is a solid waste produced by the coal industry. The continuously produced and long-term stored coal gangue has a certain impact on the environment, so it is urgent to carry out coal gangue resource utilization. The coal gangue in Qianxi city, Guizhou province was used as the research object,coarse coal gangue was used as aggregate, thermal activated fine coal gangue was used as mineral admixture,and the influence of thermal activated coal gangue powder on the properties of matrix-aggregate interface transition zone was studied by compressive and flexural strength testing machine, microhardness meter and scanning electron microscope. The results show that with the increase of thermal activated coal gangue powder amount, both the flexural strength and compressive strength of cement sand test block increase first and then decrease. The thermal activated coal gangue powder with a mass fraction of 2.5% improves the mechanical properties of cement sand test block, reduces the width of interface transition zone, promotes the microhardness of interface transition zone, and compacts the interface structure. With the amount of thermal activated coal gangue powder further increasing, the width of interface transition zone increases, and the number and size of micropore also increase. Some cementing materials are attached to the surface of coal gangue aggregate in clumpy form, which have adverse effects on the mechanical properties of cement sand.

Key words: coal gangue, thermal activation, interface transition zone, mechanical property, microhardness, microstructure

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