黏土矿物纳米材料在锂电池隔膜和固态电解质中的应用研究进展

硅酸盐通报 ›› 2022, Vol. 41 ›› Issue (6): 2167-2180.

所属专题：新型功能材料

黏土矿物纳米材料在锂电池隔膜和固态电解质中的应用研究进展

孟贵林^1,2, 杨燕飞¹, 王万凯^1,2, 周正强³, 张俊平^1,2

1.中国科学院兰州化学物理研究所,甘肃省黏土矿物应用研究重点实验室,环境材料与生态化学发展中心,兰州 730000;
2.中国科学院大学,材料科学与光电技术学院,北京 100049;
3.甘肃省水务投资有限责任公司,兰州 730000

收稿日期:2022-02-22 修订日期:2022-03-24 出版日期:2022-06-15 发布日期:2022-07-01
通信作者: 张俊平,博士,研究员。E-mail:jpzhang@licp.cas.cn
作者简介:孟贵林(1997—),男,硕士研究生。主要从事储能材料制备及性能研究。E-mail:glmeng@licp.cas.cn
基金资助:
国家自然科学基金(51873220);兰州市人才创新创业项目(2021-RC-19)

Application of Clay Mineral Nanomaterials in Lithium Battery Separators and Solid-State Electrolytes

MENG Guilin^1,2, YANG Yanfei¹, WANG Wankai^1,2, ZHOU Zhengqiang³, ZHANG Junping^1,2

1. Key Laboratory of Clay Mineral Applied Research of Gansu Province, and Center of Eco-Material and Green Chemistry, Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences, Lanzhou 730000, China;
2. College of Materials Science and Opto-Electronic Technology, University of Chinese Academy of Sciences, Beijing 100049, China;
3. Gansu Water Investment Co., Ltd., Lanzhou 730000, China

Received:2022-02-22 Revised:2022-03-24 Online:2022-06-15 Published:2022-07-01

摘要/Abstract

摘要： 锂离子电池已被广泛应用于便携式电子设备、电动汽车和电网等领域,深刻地影响着人们的日常生活。但是受限于其低的能量密度、安全性等问题,需开发稳定、高效的电化学存储材料。黏土矿物因其独特的纳米结构、丰富的活性位点、高的比表面积、丰富的储量和低成本等优点,在锂二次电池领域有着广阔的应用前景。本文首先介绍了黏土矿物纳米材料的分类、结构和化学组成等。然后,综述了黏土矿物纳米材料在锂二次电池隔膜和固态电解质隔膜方面的应用研究进展。最后,总结了黏土矿物在电化学储能领域的优势和不足,并展望了其未来发展趋势。

关键词: 黏土矿物, 隔膜, 固态电解质, 锂离子电池, 锂金属电池, 多硫化物, 锂枝晶

Abstract: Lithium ion batteries have been widely used in portable electronic devices, electric vehicles and power grids, which have a profound impact on people's daily life. It is necessary to develop stable and efficient electrochemical energy storage materials due to their low energy density and safety. Clay minerals have great application potential in the construction of lithium battery materials because of their unique nanostructures, rich active sites, high specific surface area, rich reserves and cost-effectiveness. In this paper, the classification, structure and chemical composition of clay mineral were introduced firstly. Then, the application research progress of clay mineral in the separator and solid-state electrolytes of battery was reviewed. Finally, the advantages and disadvantages of clay mineral in the energy-storage systems were discussed, and the future development trend was also prospected.

Key words: clay mineral, separator, solid electrolyte, lithium ion battery, lithium metal battery, polysulfide, lithium dendrite

中图分类号:

O646

孟贵林, 杨燕飞, 王万凯, 周正强, 张俊平. 黏土矿物纳米材料在锂电池隔膜和固态电解质中的应用研究进展[J]. 硅酸盐通报, 2022, 41(6): 2167-2180.

MENG Guilin, YANG Yanfei, WANG Wankai, ZHOU Zhengqiang, ZHANG Junping. Application of Clay Mineral Nanomaterials in Lithium Battery Separators and Solid-State Electrolytes[J]. BULLETIN OF THE CHINESE CERAMIC SOCIETY, 2022, 41(6): 2167-2180.

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黏土矿物纳米材料在锂电池隔膜和固态电解质中的应用研究进展

Application of Clay Mineral Nanomaterials in Lithium Battery Separators and Solid-State Electrolytes

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