碳纤维长度以及添加量对碳化硅网状多孔陶瓷性能的影响

硅酸盐通报 ›› 2021, Vol. 40 ›› Issue (4): 1330-1337.

碳纤维长度以及添加量对碳化硅网状多孔陶瓷性能的影响

金新新¹, 林鹏², 刘峰², 李赛赛³, 李明辉⁴, 夏晓宇¹, 劳栋¹, 贾文宝¹, 单卿¹

1.南京航空航天大学材料科学与技术学院,南京 211106;
2.中广核研究院有限公司,深圳 518028;
3.安徽工业大学材料科学与工程学院,马鞍山 243002;
4.安徽工业大学冶金工程学院,马鞍山 243002

收稿日期:2021-01-19 修回日期:2021-02-23 出版日期:2021-04-15 发布日期:2021-05-11
通讯作者: 单卿,博士,副教授。E-mail:shanqing@nuaa.edu.cn
作者简介:金新新(1996—),男,硕士研究生。主要从事耐辐照材料的制备方面的研究。E-mail:15850633529@163.com

Effects of Carbon Fiber Length and Content on Properties of SiC Reticulated Porous Ceramics

JIN Xinxin¹, LIN Peng², LIU Feng², LI Saisai³, LI Minghui⁴, XIA Xiaoyu¹, LAO Dong¹, JIA Wenbao¹, SHAN Qing¹

1. College of Materials Science and Technology, Nanjing University of Aeronautics and Astronautics, Nanjing 211106, China;
2. China Nuclear Power Technology Research Institute, Shenzhen 518028, China;
3. School of Materials Science and Engineering,Anhui University of Technology, Maanshan 243002, China;
4. School of Metallurgical Engineering,Anhui University of Technology, Maanshan 243002, China

Received:2021-01-19 Revised:2021-02-23 Online:2021-04-15 Published:2021-05-11

摘要/Abstract

摘要： 为提高有机泡沫浸渍法制备的碳化硅网状多孔陶瓷的抗折强度,采用碳纤维对碳化硅网状多孔陶瓷进行增强。研究了添加剂和碳纤维对碳化硅陶瓷浆料流变性能和触变性能的影响以及碳纤维长度和添加量对试样微观结构、气孔率、耐压强度、抗折强度的影响。结果表明:当分散剂-FS20添加量为0.1%(质量分数),增稠剂-CMC添加量为0.1%(质量分数),粘结剂-CL添加量为0.05%(质量分数)时,碳化硅陶瓷浆料的流变性能和触变性能达到最佳,碳纤维的加入增加了浆料的粘度;另外,随着碳纤维添加量和长度的增加,试样的抗折强度呈现先增大后减小的变化趋势。当碳纤维长度为1 mm且添加量为0.75%(质量分数)时,试样抗折强度达到最大。

关键词: 碳化硅多孔陶瓷, 碳纤维, 有机泡沫浸渍法, 抗折强度, 添加剂

Abstract: In order to improve the flexural strength of SiC reticulated porous ceramics prepared by the polymer sponge replica technique, the carbon fiber was used to enhance SiC reticulated porous ceramics. The effects of additives and carbon fiber on the rheology and thixotropy of SiC ceramics slurry were studied. Furthermore, the influences of length and content of carbon fiber on the microstructure, porosity, compressive strength and flexural strength of SiC reticulated porous ceramics were also investigated. The results show that the SiC ceramics slurry with 0.1% (mass fraction) dispersant-FS20, 0.1% (mass fraction) thickness agent-CMC and 0.05% (mass fraction) binder-CL exhibits excellent rheological and thixotropic behavior. The viscosity of slurry increases by adding carbon fiber. In addition, with the increase of carbon fiber content and length, the flexural strength of SiC reticulated porous ceramics first increases and then decreases. When the length and content of carbon fiber are 1 mm and 0.75% (mass fraction) respectively, the flexural strength reaches the maximum.

Key words: SiC porous ceramics, carbon fiber, polymer sponge replica technique, flexural strength, additive

中图分类号:

TQ174

金新新, 林鹏, 刘峰, 李赛赛, 李明辉, 夏晓宇, 劳栋, 贾文宝, 单卿. 碳纤维长度以及添加量对碳化硅网状多孔陶瓷性能的影响[J]. 硅酸盐通报, 2021, 40(4): 1330-1337.

JIN Xinxin, LIN Peng, LIU Feng, LI Saisai, LI Minghui, XIA Xiaoyu, LAO Dong, JIA Wenbao, SHAN Qing. Effects of Carbon Fiber Length and Content on Properties of SiC Reticulated Porous Ceramics[J]. BULLETIN OF THE CHINESE CERAMIC SOCIETY, 2021, 40(4): 1330-1337.

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