尖晶石型无钴黑色陶瓷颜料的研究进展

摘要/Abstract

摘要： 黑色陶瓷颜料目前被广泛应用于陶瓷装饰领域,其传统制备工艺需加入氧化钴,但氧化钴的高价限制了黑色陶瓷颜料的发展,因此开发无钴黑色陶瓷颜料成为陶瓷颜料研究领域的热点之一,而尖晶石型无钴黑色陶瓷颜料因其出色的耐高温性、气氛适应性和化学稳定性受到众多研究者的青睐。本文基于尖晶石型无钴黑色陶瓷颜料的相关研究进展,围绕其呈色机理、制备原料种类和制备工艺等方面进行了详细的阐述与分析。目前,制备该类陶瓷颜料的原料主要分为化工原料、矿物原料和工业固废,制备工艺则主要包括传统高温固相法、微波焙烧法、化学沉淀法、溶胶-凝胶法、微乳液法、溶液燃烧法等,所制备颜料的呈色性能主要受原料组成中过渡金属元素之间摩尔比、焙烧温度和保温时间的影响。相较而言,采用微波焙烧工业固废制备该类陶瓷颜料具有良好的应用前景,但制备过程中尖晶石形成规律和演变机理以及工业固废所引入的杂质组分对颜料性能的影响还有待进一步研究。

关键词: 黑色陶瓷颜料, 尖晶石, 呈色机理, 过渡金属元素, 铬铁矿, 工业固废

Abstract: Black ceramic pigments are currently widely used in the field of ceramic decoration. The traditional processes to produce black ceramic pigments require the addition of cobalt oxide, but the high price of cobalt oxide limits the development of black ceramic pigments. Therefore, the development of cobalt-free black ceramic pigments has become one of the hot spots in the research field of ceramic pigments and the spinel-type cobalt-free black ceramic pigments are favored by many researchers for their excellent high-temperature resistance, atmospheric adaptability and chemical stability. Based on the research progress of spinel-type cobalt-free black ceramic pigments, coloration mechanism, raw material types and preparation technologies of the above ceramic pigments were described and analyzed detailedly in this paper. At present, the raw materials for preparing the spinel-type cobalt-free black ceramic pigments can be mainly divided into chemical raw materials, mineral raw materials and industrial solid wastes. The preparation technologies mainly include the traditional high-temperature solid-state method, the microwave roasting method, the chemical precipitation method, the sol-gel method, the microemulsion method, the solution combustion method, etc. The coloring properties of prepared pigments are mainly affected by the mole ratio among transition metal elements in raw materials, the roasting temperature and the holding time. In comparison, microwave roasting of industrial solid wastes to prepare the above ceramic pigments has a good application prospect, but the formation and evolution mechanism of spinel in the preparation process and the influence of impurity components introduced by industrial solid wastes on the properties of pigments still need to be further studied.

Key words: black ceramic pigment, spinel, coloring mechanism, transition metal element, chromite, industrial solid waste

中图分类号:

TQ174.4⁺5

张翔, 李治桥, 马国军, 王强, 刘孟珂. 尖晶石型无钴黑色陶瓷颜料的研究进展[J]. 硅酸盐通报, 2021, 40(4): 1318-1329.

ZHANG Xiang, LI Zhiqiao, MA Guojun, WANG Qiang, LIU Mengke. Research Progress of Spinel-Type Cobalt-Free Black Ceramic Pigments[J]. BULLETIN OF THE CHINESE CERAMIC SOCIETY, 2021, 40(4): 1318-1329.

参考文献

[1] 车建修.现代黑陶制作技艺初探[J].艺术品鉴,2020(21):98-99.
CHE J X. A preliminary study of modern black pottery making skills[J]. Appreciation, 2020(21): 98-99 (in Chinese).
[2] 俞康泰.陶瓷色釉料与装饰导论[M].武汉:武汉工业大学出版社,1998:16.
YU K T. Ceramic glaze and decoration introduction[M]. Wuhan: Wuhan University of Technology Press, 1998: 16 (in Chinese).
[3] 秦威,徐志成,田鸿鑫,等.陶瓷釉用黑色的研制及工艺控制[J].佛山陶瓷,2008,18(4):17-20.
QIN W, XU Z C, TIAN H X, et al. Development and process control of black for ceramic glaze[J]. Foshan Ceramics, 2008, 18(4): 17-20 (in Chinese).
[4] 张福康.中国古陶瓷的科学[J].硅酸盐通报,1983,2(3):68-69.
ZHANG F K. The science of ancient Chinese ceramics[J]. Bulletin of the Chinese Ceramic Society, 1983, 2(3): 68-69 (in Chinese).
[5] BELYI Y I, ZAICHUK A V. Ceramic pigments for producing black glazes[J]. Glass and Ceramics, 2005, 62(9/10): 290-292.
[6] COSTA G, DELLA V P, RIBEIRO M J, et al. Synthesis of black ceramic pigments from secondary raw materials[J]. Dyes and Pigments, 2008, 77(1): 137-144.
[7] YANG Y G, XU J H, CAI B, et al. Synthesis and applications of black ceramic from recycled industrial wastes[J]. Advances in Applied Ceramics, 2013, 112(3): 146-148.
[8] CALBO J, SORLÍ S, LLUSAR M, et al. Minimisation of toxicity in nickel ferrite black pigment[J]. British Ceramic Transactions, 2004, 103(1): 3-9.
[9] BLOSI M, ALBONETTI S, GATTI F, et al. Au-Ag nanoparticles as red pigment in ceramic inks for digital decoration[J]. Dyes and Pigments, 2012, 94(2): 355-362.
[10] 刘世明,曾令可,税安泽,等.论黑色陶瓷色料的制备[J].陶瓷,2007(5):32-35.
LIU S M, ZENG L K, SHUI A Z, et al. Discussion on preparation of black pigment for ceramic[J]. Ceramics, 2007(5): 32-35 (in Chinese).
[11] 张新杰.藏区与内地陶瓷艺术比较研究[D].拉萨:西藏大学,2010.
ZHANG X J. A comparative study on the ceramic art between Tibet autonomous region and mainland of China[D]. Lasa: Tibet University, 2010 (in Chinese).
[12] 朱振峰,姚建曦,陈元魁.工艺参数与铬铁矿系无钴黑颜料呈色性能关系的研究[J].中国陶瓷工业,2002,9(4):11-14.
ZHU Z F, YAO J X, CHEN Y K. Research on the relationship between technological parameters and the coloring properties of chromite system cobalt-free black pigments[J]. China Ceramic Industry, 2002, 9(4): 11-14 (in Chinese).
[13] 李春文,何代英,赵彦钊.Ni-Cr-Mn-Fe系黑颜料的合成及呈色[J].陶瓷,1998(4):25-27.
LI C W, HE D Y, ZHAO Y Z. Synthesis and color of Ni-Cr-Mn-Fe black pigment[J]. Ceramics, 1998(4): 25-27 (in Chinese).
[14] LEE J H, KWEON J W, CHO W S, et al. Formulation and characterization of black ceramic ink for a digital ink-jet printing[J]. Ceramics International, 2018, 44(12): 14151-14157.
[15] 司志胜.廉价黑色色剂的研究[J].陶瓷工程,1998,32(2):28-30.
SI Z S. Research on the cheap black colorant[J]. Ceramics Engineering, 1998, 32(2): 28-30 (in Chinese).
[16] 戴若冰.陶瓷色料及其应用技术(二)[J].佛山陶瓷,2001,11(4):30-33.
DAI R B. Ceramic colors and their application (part 2)[J]. Foshan Ceramics, 2001, 11(4): 30-33 (in Chinese).
[17] 姚建曦,朱振峰,高力明,等.无钴黑色陶瓷颜料的研究及应用现状[J].陶瓷工程,1999,33(5):41-43.
YAO J X, ZHU Z F, GAO L M, et al. Research and application status of cobalt-free black ceramic pigments[J]. Ceramics Engineering, 1999, 33(5): 41-43 (in Chinese).
[18] 梁翠玲,曹春娥,沈华荣,等.釉上彩用Fe-Cr系无钴黑色料的合成工艺与表征[J].中国陶瓷,2016,52(12):65-69.
LIANG C L, CAO C E, SHEN H R, et al. Synthesis and characterization of Fe-Cr system cobalt-free black pigment for overglaze[J]. China Ceramics, 2016, 52(12): 65-69 (in Chinese).
[19] 孙忱,殷书建,戴军,等.无钴黑色料的应用及注意问题[J].现代技术陶瓷,1998,19(2):41-44.
SUN C, YIN S J, DAI J, et al. Application of cobalt-free black stain and problems for attention[J]. Advanced Ceramics, 1998, 19(2): 41-44 (in Chinese).
[20] 闫国进.冷却方式对尖晶石型红外辐射陶瓷结晶的影响[J].陶瓷,2012(2):16-19.
YAN G J. Effects of cooling ways on the crystallization of spinel infrared ceramics[J]. Ceramics, 2012(2): 16-19 (in Chinese).
[21] NA J G, LEE T D, PARK S J. Effects of cation distribution on the magnetic and electrical properties of cobalt ferrite[J]. IEEE Transactions on Magnetics, 1992, 28(5): 2433-2435.
[22] EPPLER R A. Cobalt-free black pigments[J]. American Ceramic Society Bulletin, 1980, 60(5): 562.
[23] LEE K H, MYUNG M S, LEE B H. Development of black color spinel pigment for high temperature[J]. Journal of the Korean Ceramic Society, 2007, 44(5): 160-165.
[24] KIM J H, LEE S H, SUH M C, et al. Synthesis of cobalt oxide free black color spinel pigment[J]. Journal of the Korean Ceramic Society, 2007, 44(11): 639-644.
[25] 张登高.玻璃和陶瓷用无机颜料的现状与发展[J].硅酸盐通报,1989,8(1):30-33.
ZHANG D G. Current status and development of inorganic pigments for glass and ceramics[J]. Bulletin of the Chinese Cerrmic Society, 1989, 8(1): 30-33 (in Chinese).
[26] 张潇予,张玉军,龚红宇,等.溶胶-凝胶法制备纳米近红外高反射率黑色陶瓷颜料[J].功能材料,2013,44(3):417-420.
ZHANG X Y, ZHANG Y J, GONG H Y, et al. Nano black high near-infrared reflectance ceramic pigments synthesized by sol-gel method[J]. Journal of Functional Materials, 2013, 44(3): 417-420 (in Chinese).
[27] 吴建锋,徐晓虹.Fe-Mn-Cr-Ni系黑色料制备工艺的研究[J].陶瓷学报,1999,20(3):167-170.
WU J F, XU X H. A study on the process technology of Fe-Mn-Cr-Ni system black pigment[J]. Journal of Ceramics, 1999, 20(3): 167-170 (in Chinese).
[28] ESCARDINO A, MESTRE S, BARBA A, et al. Kinetic study of black Fe₂O₃-Cr₂O₃ pigment synthesis: i, influence of synthesis time and temperature[J]. Journal of the American Ceramic Society, 2003, 86(6): 945-950.
[29] 谢春波.纯正黑色釉的研制[J].河北陶瓷,1997(3):7-11.
XIE C B. Preparation of pure black glaze[J]. Hebei Ceramics, 1997(3): 7-11 (in Chinese).
[30] MESTRE S, PALACIOS M D, AGUT P. Solution combustion synthesis of (Co, Fe)Cr₂O₄ pigments[J]. Journal of the European Ceramic Society, 2012, 32(9): 1995-1999.
[31] YE M Q, HAN A J, CHU Z S, et al. Synthesis and characterization of Mn-doped copper chromite black pigments[J]. Advanced Materials Research, 2013, 602: 71-75.
[32] 乔艳.铬铁矿在陶瓷颜料中的应用[J].山东陶瓷,1998,21(2):34-36.
QIAO Y. Application of chromite in ceramic pigments[J]. Shandong Ceramics, 1998, 21(2): 34-36 (in Chinese).
[33] 陈宗玲,顾幸勇,胡克艳.用铬铁矿制备低成本Cr-Fe-Ni-Cu系无钴黑色色料的研究[J].陶瓷学报,2010,31(4):591-595.
CHEN Z L, GU X Y, HU K Y. Study on preparing low-cost cobalt free black ceramic pigments of cr-fe-ni-cu system with chromite[J]. Journal of Ceramics, 2010, 31(4): 591-595 (in Chinese).
[34] 张文丽.尖晶石色料的组成与结构[J].中国陶瓷,1997,33(5):12-14.
ZHANG W L. The composition and structures of spinel stains[J]. China Ceramics, 1997, 33(5): 12-14 (in Chinese).
[35] 王芬,张超武,黄剑锋.硅酸盐制品的装饰及装饰材料[M].北京:化学工业出版社,2004:109.
WANG F, ZHANG C W, HUANG J F. Decoration and decoration materials for silicate products[M]. Beijing: Chemical Industry Press, 2004: 109 (in Chinese).
[36] 张文丽.色料的呈色机理、生产及应用[J].中国陶瓷工业,1997,4(2):10-16.
ZHANG W L. Coloring mechanism, production and application of pigments[J]. China Ceramic Industry, 1997, 4(2): 10-16 (in Chinese).
[37] 陈祎.稀土氧化物对陶瓷釉的影响:以黑色色釉为例[J].江西化工,2008(4):200-201.
CHEN Y. The effect of rare earth oxides on ceramic glazes-taking black colored glaze as an example[J]. Jiangxi Chemical Industry, 2008(4): 200-201 (in Chinese).
[38] 管志斌.用稀土化合物研制无钴黑色颜料和釉料[J].中国陶瓷,1985,21(3):24-26.
GUAN Z B. Preparation of cobalt-free black pigments and glazes with rare earth compounds[J]. China Ceramics, 1985, 21(3): 24-26 (in Chinese).
[39] GARGORI C, PRIM S R, LLUSAR M, et al. Recycling of Cr/Ni/Cu plating wastes as black ceramic pigments[J]. Materials Letters, 2018, 218: 341-345.
[40] HAJJAJI W, SEABRA M P, LABRINCHA J A. Evaluation of metal-ions containing sludges in the preparation of black inorganic pigments[J]. Journal of Hazardous Materials, 2011, 185(2/3): 619-625.
[41] CHEN Z T, DU Y, LI Z F, et al. Synthesis of black pigments containing chromium from leather sludge[J]. Ceramics International, 2015, 41(8): 9455-9460.
[42] 于长凤,朱小平,李欣,等.用钒砂尾矿制备无钴黑色陶瓷颜料的研究[J].陶瓷学报,2013,34(1):76-80.
YU C F, ZHU X P, LI X, et al. Preparation of black ceramic pigment with vanadium tailings[J]. Journal of Ceramics, 2013, 34(1): 76-80 (in Chinese).
[43] ZHANG X, MA G J, JIN Y B, et al. Preparation of ceramic tiles with black pigments using stainless steel plant dust as a raw material[J]. Ceramics International, 2014, 40(7): 9693-9700.
[44] CALBO J, TENA M A, MONRÓS G, et al. Fluxing agent effect on nickel ferrite black pigment[J]. American Ceramic Society Bulletin, 2005, 84: 9201-9206.
[45] MAGALHÃES J M, SILVA J E, CASTRO F P, et al. Physical and chemical characterisation of metal finishing industrial wastes[J]. Journal of Environmental Management, 2005, 75(2): 157-166.
[46] 彭兵,彭及.不锈钢电弧炉粉尘的物理化学特性及形成机理探讨[J].北方工业大学学报,2003,15(1):34-40.
PENG B, PENG J. Physical and chemical characteristics of dust from electric arc furnace stainless steelmaking and mechanism of its formation[J]. Journal of North China University of Technology, 2003, 15(1): 34-40 (in Chinese).
[47] 马国军,倪红卫,薛正良.不锈钢厂电弧炉烟尘处理技术[J].特殊钢,2006,27(6):37-40.
MA G J, NI H W, XUE Z L. Treatment technology of EAF dust at stainless steel works[J]. Special Steel, 2006, 27(6): 37-40 (in Chinese).
[48] 魏芬绒,张延玲,魏文洁,等.不锈钢粉尘化学组成及其Cr、Ni存在形态[J].过程工程学报,2011,11(5):786-793.
WEI F R, ZHANG Y L, WEI W J, et al. Chemical composition of dust from stainless steel smelting and existing forms of Cr and Ni[J]. The Chinese Journal of Process Engineering, 2011, 11(5): 786-793 (in Chinese).
[49] 马国军,范巍,徐之浩,等.不锈钢厂烟尘中铬及其他元素的分布规律[J].过程工程学报,2010,10(s1):68-72.
MA G J, FAN W, XU Z H, et al. Distribution behavior of chromium and other elements in the stainless steel plant dust[J]. The Chinese Journal of Process Engineering, 2010, 10(s1): 68-72 (in Chinese).
[50] ZHU R, MA G, CAI Y, et al. Ceramic tiles with black pigment made from stainless steel plant dust: physical properties and long-term leaching behavior of heavy metals[J]. Journal of the Air & Waste Management Association (1995), 2016, 66(4): 402-411.
[51] 国家环境保护总局.固体废物-浸出毒性浸出方法-硫酸硝酸法:HJ/T 299—2007[S].北京:中国环境科学出版社,2007.
State Environmental Protection Administration. Solid waste-leaching toxic leaching method-sulfuric acid nitric acid method: HJ/T 299—2007[S]. Beijing: China Environmental Science Press, 2007 (in Chinese).
[52] 刘华锋,王慧,曾令可.黑色陶瓷色料的研究现状与展望[J].中国陶瓷工业,2013,20(6):32-34.
LIU H F, WANG F, ZENG L K. Current situation and future prospects of research on black ceramic pigments[J]. China Ceramic Industry, 2013, 20(6): 32-34 (in Chinese).
[53] 闫国杰,程继健.金属氧化物混相颜料研究进展[J].中国陶瓷,1999,35(5):34-36.
YAN G J, CHENG J J. Research progress of metal oxide mixed-phase pigments[J]. China Ceramics, 1999, 35(5): 34-36 (in Chinese).
[54] 孙国梁,张阔.尖晶石型红外辐射陶瓷的研究[J].陶瓷学报,2009,30(3):327-330.
SUN G L, ZHANG K. Study on the infrared radiation ceramic with spinel structure[J]. Journal of Ceramics, 2009, 30(3): 327-330 (in Chinese).
[55] NA J G, LEE T D, PARK S J. Effects of cation distribution on the magnetic and electrical properties of cobalt ferrite[J]. IEEE Transactions on Magnetics, 1992, 28(5): 2433-2435.
[56] 朱振峰,贺国瑞.Cd(S、Se)色基合成及固相反应机理的研究[J].中国陶瓷,1991,27(3):4-9.
ZHU Z F, HE G R. The investigation of the synthesis of cadmium sulphoselenide pigment and the mechanism of their solid state reaction[J]. China Ceramics, 1991, 27(3): 4-9 (in Chinese).
[57] STANDISH N, WORNER H. Microwave application in the reduction of metal oxides with carbon[J]. Journal of Microwave Power and Electromagnetic Energy, 1990, 25(3): 177-180.
[58] HUA Y, LIU C. Heating rate of minerals and compounds in microwave field[J]. Transactions of Nonferrous Metals Society of China, 1996, 6(1): 35-40.
[59] 陈津,刘浏,曾加庆,等.微波加热还原含碳铁矿粉试验研究[J].钢铁,2004,39(6):1-5.
CHEN J, LIU L, ZENG J Q, et al. Experimental research of microwave heating on iron ore concentrates containing coal and lime[J]. Iron and Steel, 2004, 39(6): 1-5 (in Chinese).
[60] KIM E, CHO S, LEE J. Kinetics of the reactions of carbon containing zinc oxide composites under microwave irradiation[J]. Metals and Materials International, 2009, 15(6): 1033-1037.
[61] CHA C Y, KIM D S. Microwave induced reactions of sulfur dioxide and nitrogen oxides in char and anthracite bed[J]. Carbon, 2001, 39(8): 1159-1166.
[62] BLOSI M, DONDI M, ALBONETTI S, et al. Microwave-assisted synthesis of Pr-ZrSiO₄, V-ZrSiO₄ and Cr-YAlO₃ ceramic pigments[J]. Journal of the European Ceramic Society, 2009, 29(14): 2951-2957.
[63] CALBO J, GARGORI C, SORLÍ S, et al. Síntesis de pigmentos cerámicos mediante radiación microondas[J]. Boletín De La Sociedad Española De Cerámica y Vidrio, 2007, 46(1): 14-20.
[64] KHATTAB R M, SADEK H E H, GABER A A. Synthesis of Co_xMg_1-xAl₂O₄ nanospinel pigments by microwave combustion method[J]. Ceramics International, 2017, 43(1): 234-243.
[65] BORIDIOLI F, CORRADI A B, FERRARI A M, et al. Microwave synthesis of Al₂O₃/CR₂O₃(SS) ceramic pigments[J]. Journal of Microwave Power and Electromagnetic Energy, 1998, 33(1): 18-23.
[66] BONDIOLI F, FERRARI A M, LUSVARGHI L, et al. Synthesis and characterization of praseodymium-doped ceria powders by a microwave-assisted hydrothermal (MH) route[J]. Journal of Materials Chemistry, 2005, 15(10): 1061.
[67] RASOULI S. Preparation of anticorrosive cobalt-doped ZnO nano pigments by a combustion method; a comparison study between microwave irradiation and a conventional heating source[J]. Journal of Ceramic Processing Research, 2011, 12(6): 668-672.
[68] 马国军,殷雪,苏伟厚,等.微波碳热还原不锈钢厂电弧炉粉尘的热力学及实验研究[J].武汉科技大学学报,2010,33(4):439-444.
MA G J, YIN X, SU W H, et al. Thermodynamics and experimental study of carbothermic reduction of electric arc furnace dust generated from stainless steel plant by microwave[J]. Journal of Wuhan University of Science and Technology, 2010, 33(4): 439-444 (in Chinese).
[69] 任强,何选盟.陶瓷颜料研究进展与发展方向[J].陶瓷学报,2006,27(1):151-154.
REN Q, HE X M. Development and direction of researching on the ceramic pigment[J]. Journal of Ceramics, 2006, 27(1): 151-154 (in Chinese).
[70] 谷科成,胡相红,陈逸,等.Sol-gel法制备纳米TiO₂凝胶过程的控制[J].后勤工程学院学报,2010,26(1):66-70.
GU K C, HU X H, CHEN Y, et al. Control on the gel process of nano-TiO₂ prepared by sol-gel method[J]. Journal of Logistical Engineering University, 2010, 26(1): 66-70 (in Chinese).
[71] 毛昉,程旭东,陈武,等.溶胶凝胶法制备Ca₃Co₄O_9+δ粉末材料[J].武汉理工大学学报,2010,32(5):39-41+66.
MAO F, CHENG X D, CHEN W, et al. Ca₃Co₄O_9+δ powder synthesized by sol-gel method[J]. Journal of Wuhan University of Technology, 2010, 32(5): 39-41+66 (in Chinese).
[72] 杜肖,曹春娥,陈云霞.溶胶-凝胶法在陶瓷色料制备中的应用[J].中国陶瓷工业,2009,16(4):30-33.
DU X, CAO C E, CHEN Y X. The application of sol-gel technique in ceramic pigment preparation[J]. China Ceramic Industry, 2009, 16(4): 30-33 (in Chinese).
[73] CHANG Q B, WANG X, WANG Y Q, et al. Encapsulated carbon black prepared by sol-gel-spraying: a new black ceramic pigment[J]. Journal of the European Ceramic Society, 2014, 34(13): 3151-3157.
[74] 林东恩,刘建雄,张逸伟.微乳液法制备超细Co-Cr-Fe-Ni钴黑陶瓷颜料[J].功能材料,2013,44(1):129-131+135.
LIN D E, LIU J X, ZHANG Y W. Preparation of ultrafine Co-Cr-Fe-Ni cobalt black pigments by microemulsion method[J]. Journal of Functional Materials, 2013, 44(1): 129-131+135 (in Chinese).
[75] 黄丽群.化学共沉淀法制备陶瓷色料研究进展[J].中国陶瓷工业,2011,18(2):27-32.
HUANG L Q. The development of research on chemical coprecipitation method for ceramic pigment preparation[J]. China Ceramic Industry, 2011, 18(2): 27-32 (in Chinese).
[76] 马光华,王迎军,李凯,等.湿化学法制备陶瓷颜料的现状与发展[J].中国陶瓷,2003,39(6):15-20.
MA G H, WANG Y J, LI K, et al. The current situation and development of ceramic pigments prepared by wet chemical method[J]. China Ceramics, 2003, 39(6): 15-20 (in Chinese).
[77] 俞康泰,解茂林.化学共沉淀结合成Pr-,Nd-Zircon色料的研究[J].中国陶瓷,2000,36(5):1-3+14.
YU K T, XIE M L. The studies of Pr-, Nd-zircon pigments for coprecipitation method[J]. China Ceramics, 2000, 36(5): 1-3+14 (in Chinese).
[78] 曹丽云,黄剑锋,杨军顺,等.超声共沉淀法制备硅铁红陶瓷颜料[J].中国陶瓷工业,2004,11(1):1-5.
CAO L Y, HUANG J F, YANG J S, et al. Syntheses of Fe₂O₃/silica red ceramic pigment using co-precipitation with the aid of ultrasonic irradiation[J]. China Ceramic Industry, 2004, 11(1): 1-5 (in Chinese).
[79] 王锦,宋淑娥.醇—水溶液共沉淀法制备铬锡红陶瓷色料超细粉[J].中国陶瓷工业,2004,11(4):8-10.
WANG J, SONG S E. Synthesis of ultra fine chrome-tin pink pigment by coprecipitation method of alohol-aqueous salt solutions[J]. China Ceramic Industry, 2004, 11(4): 8-10 (in Chinese).
[80] 俞康泰,洪小林,高升洲,等.化学共沉淀法制备铬锡红色料的研究[J].中国陶瓷,1998,34(6):14-17.
YU K T, HONG X L, GAO S Z, et al. Research on the synthesis of chrome-tin pink pigment by coprecipitation method[J]. China Ceramics, 1998, 34(6): 14-17 (in Chinese).
[81] 范恩荣.用化学沉淀法制备陶瓷颜料[J].陶瓷研究,1995,10(1):36-38.
FAN E R. Preparation of ceramic pigments by chemical precipitation method[J]. Ceramic Studies Journal, 1995, 10(1): 36-38 (in Chinese).
[82] 郭名勇,王燕民,潘志东,等.溶液燃烧法合成(Co_0.5Cu_0.5)(MnFe)O₄纳米晶陶瓷色料[J].硅酸盐学报,2015,43(4):411-417.
GUO M Y, WANG Y M, PAN Z D, et al. Synthesis of nanocrystalline (Co_0.5Cu_0.5)(MnFe)O₄ ceramic pigment via solution combustion technique[J]. Journal of the Chinese Ceramic Society, 2015, 43(4): 411-417 (in Chinese).
[83] 徐红梅,严红革,陈振华.柠檬酸—硝酸盐低温燃烧法制备Ce_0.8Y_0.2O_1.9纳米粉体的机理[J].硅酸盐学报,2006,34(4):393-397.
XU H M, YAN H G, CHEN Z H. Mechanism of citric acid-nitrates low-temperature combustion for Ce_0.8Y_0.2O_1.9 nano-scale powders[J]. Journal of the Chinese Ceramic Society, 2006, 34(4): 393-397 (in Chinese).
[84] 李家科,李艳艳,刘欣,等.溶液燃烧法合成Cu-Fe-Cr系超细无钴黑色陶瓷色料[J].中国陶瓷,2016,52(3):70-73.
LI J K, LI Y Y, LIU X, et al. Preparation of ultrafine cobalt free black ceramic pigment of Cu-Fe-Cr system by solution combustion method[J]. China Ceramics, 2016, 52(3): 70-73 (in Chinese).