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硅酸盐通报 ›› 2018, Vol. 37 ›› Issue (5): 1572-1577.

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凝灰岩制备水泥混合材的试验研究

何仕碧;陈太红;安辛友;杨辉;刘燕   

  1. 西华师范大学物理与空间科学学院,南充,637009
  • 出版日期:2018-05-15 发布日期:2021-01-18
  • 基金资助:
    四川省教育厅自然科学基金重点项目(16ZA0170)%西华师范大学英才基金(17YC501)

Experimental Study on Preparing Cement Admixture from Volcanic Tuff

HE Shi-bi;CHEN Tai-hong;AN Xin-you;YANG Hui;LIU Yan   

  • Online:2018-05-15 Published:2021-01-18

摘要: 通过X射线荧光光谱分析(XRF)、X射线衍射分析(XRD)、热分析(TG-DTA)和扫描电镜分析(SEM)等方法表征了凝灰岩的物化特性,分别采用机械活化、机械-热力复合活化研究了凝灰岩的胶砂力学性能.结果表明:试验用凝灰岩样品硅铝含量在75%以上,样品易磨性较好,试验球磨10 min比表面积可达到300 m 2/kg以上;只经机械活化的凝灰岩样品具有良好的填充效应,且主要体现在水化前期,28 d胶砂活性指数(R28)在54% ~58%之间;经机械-热力复合活化的凝灰岩样品组成结构发生了变化,对体系的胶凝活性早期与后期均有有利影响,28 d胶砂活性指数可达70%以上.

关键词: 凝灰岩;火山灰活性;热活化;水泥混合材

Abstract: Methods of XRF, XRD, TG-DTA and SEM were used to characterize the physicochemical properties of volcanic tuff, research on the mechanical and thermal -mechanical complex activation of the samples were also made respectively .Results show that: the contents of silicon and aluminum in the volcanic tuff samples are more than 75%, the samples have good grindability , whose specific surface area can reach more than 300 m 2 /kg after being grinded about 10 min in the experiment; the mechanical activated tuff sample has a good filling effect in the cementitious system , which effect mainly worked in the early hydration period, and the 28 d activity index of mortar (R28 ) is between 54% to 58%; the thermal-mechanical complex activated tuff sample 's composition and structure changed evidently , which has favorable effect on the cementitious system both in the early and further hydration period , it's 28 d activity index of mortar can reach more than 70%.

Key words: volcanic tuff;pozzolanic activity;thermal activation;cement admixture

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