钙钾摩尔比对汝窑青釉呈色与烧成温度范围的影响

doi:10.16552/j.cnki.issn1001-1625.2024.1417

硅酸盐通报 ›› 2025, Vol. 44 ›› Issue (6): 2297-2305.DOI: 10.16552/j.cnki.issn1001-1625.2024.1417

钙钾摩尔比对汝窑青釉呈色与烧成温度范围的影响

丁二宝¹, 孙稳¹, 刘楠楠¹, 杨兴化¹, 张颖², 李鑫浩³

1.平顶山学院河南省中原古陶瓷研究重点实验室,平顶山 467000;
2.景德镇陶瓷大学美术学院,景德镇 333000;
3.江西陶瓷工艺美术职业技术学院材料与机械工程学院,景德镇 333000

收稿日期:2024-11-19 修订日期:2024-12-31 发布日期:2025-06-27
通信作者: 杨兴化,博士,讲师。E-mail:3167@pdsu.edu.cn
作者简介:丁二宝(1989—),男,博士,讲师。主要从事传统陶瓷与古陶瓷结构与性能的研究。E-mail:6403@pdsu.edu.cn
基金资助:
河南省科技攻关项目(232102230123);平顶山学院高层次人才启动基金(PXY-BSQD-202111);平顶山市陶瓷产业创新发展规划项目(PXY-HX-202027);河南省社科联项目(SKL-2023-2829);河南省软科学重点项目(242400411020)

Influence of Calcium/Potassium Molar Ratio on Color and Firing Temperature Range of Ru Porcelain Celadon Glaze

DING Erbao¹, SUN Wen¹, LIU Nannan¹, YANG Xinghua¹, ZHANG Ying², LI Xinhao³

1. Henan Key Laboratory of Research for Central Plains Ancient Ceramics, Pingdingshan University, Pingdingshan 467000, China;
2. College of Art, Jingdezhen Ceramic Institute, Jingdezhen 333000, China;
3. College of Materials and Mechanical Engineering, Jiangxi Vocational College of Ceramic Arts and Technology, Jingdezhen 333000, China

Received:2024-11-19 Revised:2024-12-31 Online:2025-06-27

摘要/Abstract

摘要： 以清凉寺遗址出土的汝窑青釉的化学组成为基础制备样品,采用高温显微镜、扫描电子显微镜与色度仪等,探究了釉中钙钾摩尔比对釉烧成温度范围、显微结构与呈色的影响规律。结果表明:随钙钾摩尔比的逐渐减小(8.70~3.45),釉的色度值a^*与光泽度先减小后增大,色度值b^*与其相反;钙钾摩尔比为5.08时,釉面特征出现突变,呈现半哑光状态,呈色与遗址出土的样品接近;显微结构中主要是钙长石形貌与分相结构的变化,钙钾摩尔比在8.70~6.47时,钙长石形态为柱状、针状及片状,分相结构由孤立液滴状逐渐向棉絮状转变,平均尺寸变小;钙钾摩尔比在5.08~3.45时,熔体的表面张力开始出现较大起伏,钙长石开始出现枝晶形态,并出现次级分枝,样品的“明净感”降低。烧成温度低于1 170 ℃时,钙钾摩尔比为8.70的样品由于较低的软化温度而熔融效果较好,其余样品由于较高的软化温度而熔融效果较差;烧成温度在1 170~1 220 ℃时,钙钾摩尔比为5.08的样品具有相对较宽的烧成范围,液相量也相对较多且变化平缓,呈色较为稳定且釉面熔融效果较好,可改善汝窑青釉中因烧成范围窄而出现的呈色波动问题。

关键词: 汝窑青釉, 钙钾摩尔比, 呈色特征, 烧成温度, 显微结构

Abstract: Samples were prepared based on the chemical composition of Ru porcelain celadon glaze unearthed from Qingliangsi site. High-temperature microscopy, scanning electron microscopy, and colorimeter were employed to study the influence of calcium/potassium molar ratio in the glazes on firing temperature range, microstructure and coloration. The results show that chromatic a^* value and gloss of the glazes first decrease and then increase, while b^* value does the opposite with calcium/potassium molar ratio decreased gradually from 8.70 to 3.45. When calcium/potassium molar ratio is 5.08, the glaze characteristic shows a sudden change, showing a semi-matte surface, and the color is similar to that of unearthed samples. The microstructures are mainly the changes of morphology of anorthite and phase separation. When calcium/potassium molar ratio is in the range of 8.70~6.47, the morphology of anorthite is columnar, acicular and lamellar, and the phase separation structure gradually changes from isolated droplet to cotton wool, and the average size decreases. When calcium/potassium molar ratio is in the range of 5.08~3.45, the surface tension of the glaze melt begins to fluctuate greatly, the form of dendrite begins to appear, and the secondary branches appear, which decreases the “clarity” of the glaze. When the firing temperature is below 1 170 ℃, glaze with calcium/potassium molar ratio of 8.70 exhibits good melting effect due to its lower softening temperature, while the other samples show poor melting effect due to their higher softening temperature. When the firing temperature is between 1 170 ℃ and 1 220 ℃, glaze with calcium/potassium molar ratio of 5.08 has a relatively wide firing range, with a relatively large amount of liquid phase and changing smoothly. The color is relatively stable and glaze has a good melting effect, which can improve the color fluctuation issue in Ru porcelain celadon glaze caused by the narrow firing range.

Key words: Ru porcelain celadon glaze, calcium/potassium molar ratio, color character, firing temperature, microstructure

中图分类号:

TQ174

丁二宝, 孙稳, 刘楠楠, 杨兴化, 张颖, 李鑫浩. 钙钾摩尔比对汝窑青釉呈色与烧成温度范围的影响[J]. 硅酸盐通报, 2025, 44(6): 2297-2305.

DING Erbao, SUN Wen, LIU Nannan, YANG Xinghua, ZHANG Ying, LI Xinhao. Influence of Calcium/Potassium Molar Ratio on Color and Firing Temperature Range of Ru Porcelain Celadon Glaze[J]. BULLETIN OF THE CHINESE CERAMIC SOCIETY, 2025, 44(6): 2297-2305.

参考文献

[1] 《汝瓷志》编纂委员会. 汝瓷志[M]. 北京: 中华书局, 2018: 244-245.
Compilation Committee of “Ru ceramic chronicles”. Ru ceramic chronicles[M]. Beijing: Zhonghua Book Company, 2018: 244-245 (in Chinese).
[2] 中国硅酸盐学会. 中国陶瓷史[M]. 北京: 文物出版社, 2017: 284-285.
Chinese Ceramic Society. History of chinese ceramics[M]. Beijing: Cultural Relics Press, 2017: 284-285 (in Chinese).
[3] 赵青云, 王黎明. 河南宝丰发现窖藏汝瓷珍品[J]. 华夏考古, 1990(1): 51-55.
ZHAO Q Y, WANG L M. Henan Baofeng discovers Ru Ci treasures in a cellar[J]. Huaxia Archaeology, 1990(1): 51-55 (in Chinese).
[4] 李家治. 中国科学技术史-陶瓷卷[M]. 北京: 科学出版社, 1998: 274.
LI J Z. History of science and technology in China: ceramic volume[M]. Beijing: Science Press, 1998: 274 (in Chinese).
[5] 张福康, 陶光仪, 阮美玲, 等. 汝官窑的釉色、质感、斜开片及土蚀斑的形成原因[C]//古陶瓷科学技术5-国际讨论会论文集, 上海, 2002.
ZHANG F K, TAO G Y, RUAN M L, et al. Formation causes of the glaze color, texture, oblique cracks, and earth erosion spots of Ru oficial kiln[C]//Proceedings of the 5th International Symposium on Science and Technology of Ancient Ceramics, Shanghai, 2002 (in Chinese).
[6] 丁银忠, 侯佳钰, 李合, 等. 汝州张公巷窑和东沟窑青瓷胎釉元素组成的对比研究[J]. 中国陶瓷, 2019, 55(9): 59-63.
DING Y Z, HOU J Y, LI H, et al. Tudy on the element composition of the celadon from Zhanggongxiang kiln and Donggou kiln in Ruzhou City[J]. China Ceramics, 2019, 55(9): 59-63 (in Chinese).
[7] 宋晓岚, 黄学辉. 无机材料科学基础[M]. 北京: 化学工业出版社, 2006: 128.
SONG X L, HUANG X H. Fundamentals of inorganic materials science [M]. Beijing: Chemical Industry Press, 2006: 128 (in Chinese).
[8] 闵乃本. 探索新晶体[M]. 长沙: 湖南科学技术出版社, 1998: 226-239.
MIN N B. Exploring new crystals[M]. Changsha: Hunan Science and Technology Press, 1998: 226-239 (in Chinese).
[9] 马铁成. 陶瓷工艺学[M]. 北京: 中国轻工业出版社, 2023: 218-219.
MA T C. Ceramic technology[M]. Beijing: China Light Industry Press, 2023: 218-219 (in Chinese).
[10] 丁二宝, 曹春娥, 卢希龙, 等. 高温铜红釉的研制及主要因素对呈色影响的研究[J]. 中国陶瓷, 2015, 51(9): 56-60.
DING E B, CAO C E, LU X L, et al. Study on high-temperature copper red glaze and its influence factors[J]. China Ceramics, 2015, 51(9): 56-60 (in Chinese).
[11] 李国桢, 郭演仪. 中国名瓷工艺基础[M]. 杭州: 浙江大学出版社, 2012: 83.
LI G Z, GUO Y I. Fundamentals of famous chinese ceramic crafts[M]. Hangzhou: Zhejiang University Press, 2012: 83 (in Chinese).

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钙钾摩尔比对汝窑青釉呈色与烧成温度范围的影响

Influence of Calcium/Potassium Molar Ratio on Color and Firing Temperature Range of Ru Porcelain Celadon Glaze

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