疏水性侵蚀抑制剂对水泥水化影响及作用机理分析

硅酸盐通报 ›› 2024, Vol. 43 ›› Issue (8): 2768-2777.

疏水性侵蚀抑制剂对水泥水化影响及作用机理分析

张进飞^1,2, 马麒³, 穆松³, 郭政³, 庄志杰³, 乔宏霞^1,2, 洪锦祥^1,3

1.兰州理工大学土木工程学院,兰州 730050;
2.甘肃省先进土木工程材料工程研究中心,兰州 730050;
3.江苏苏博特新材料股份有限公司,南京 211103

收稿日期:2024-01-15 修订日期:2024-03-05 出版日期:2024-08-15 发布日期:2024-08-12
通信作者: 乔宏霞,博士,教授。E-mail:qhxlut7706@163.com;洪锦祥,博士,教授级高级工程师。E-mail:hongjinxiang@cnjsjk.cn
作者简介:张进飞(1996—),男,硕士研究生。主要从事混凝土耐久性提升技术的研究。E-mail:1146620697@qq.com
基金资助:
国家重点实验室开放课题(FH2018sk201);国家自然科学基金面上项目(52078240)

Effect and Mechanism Analysis of Carboxylic Acid Type Hydrophobic Agent on Cement Hydration

ZHANG Jinfei^1,2, MA Qi³, MU Song³, GUO Zheng³, ZHUANG Zhijie³, QIAO Hongxia^1,2, HONG Jinxiang^1,3

1. School of Civil Engineering, Lanzhou University of Technology, Lanzhou 730050, China;
2. Gansu Advanced Civil Engineering Materials Engineering Research Center, Lanzhou 730050, China;
3. Jiangsu Subote New Materials Co., Ltd., Nanjing 211103, China

Received:2024-01-15 Revised:2024-03-05 Online:2024-08-15 Published:2024-08-12

摘要/Abstract

摘要： 疏水性侵蚀抑制剂使混凝土具有优异疏水效果,抑制了侵蚀性环境中介质传输,然而其作用机制尚未明确。本文对水泥浆体在不同疏水性侵蚀抑制剂(CAHA)掺量下的水化行为进行了研究,探究了其对水泥水化放热、水化物相、表面接触角、抗压强度等性能的影响。研究结果表明,CAHA降低了水泥浆体第一水化放热峰并延缓水泥水化,在水化前期抑制了钙矾石和氢氧化钙的生成,这种抑制作用在高掺量下更为显著。CAHA一定程度上降低了砂浆早期抗压强度,对28 d抗压强度影响并不明显。CAHA显著降低砂浆吸水率并使其具有疏水性。通过比对,推荐CAHA最佳掺量为胶凝材料质量的6%,此时水泥砂浆抗压强度损失较小且抗侵蚀性能明显提升。

关键词: 硅酸盐水泥, 抗压强度, 疏水性能, 水泥水化, 水化产物, 羧酸酯

Abstract: The hydrophobic corrosion inhibitor makes the concrete have an excellent hydrophobic effect and inhibits the medium transmission in the corrosive environment. However, the mechanism of action is not clear. In this paper, the hydration behavior of cement paste with different content of carboxylic acid type hydrophobic agent (CAHA) was studied, and its effects on the hydration heat, hydrate phase, surface contact angle, and compressive strength of cement were investigated. The results show that CAHA reduces the first hydration exothermic peak of cement paste and delays the hydration of cement. In the early stage of hydration, CAHA inhibits the formation of ettringite and calcium hydroxide, which is more significant at high dosage. CAHA reduces the early compressive strength of mortar to a certain extent and has no obvious effect on 28 d compressive strength. CAHA significantly reduces the water absorption of mortar and makes it hydrophobic. Through comparison, the optimum dosage of CAHA is recommended to be 6% of the mass of cementitious material, at which time the loss of compressive strength of the cement mortar is smaller and the erosion resistance is significantly improved.

Key words: Portland cement, compressive strength, hydrophobic performance, cement hydration, hydration product, carboxylate ester

中图分类号:

TU528.042

张进飞, 马麒, 穆松, 郭政, 庄志杰, 乔宏霞, 洪锦祥. 疏水性侵蚀抑制剂对水泥水化影响及作用机理分析[J]. 硅酸盐通报, 2024, 43(8): 2768-2777.

ZHANG Jinfei, MA Qi, MU Song, GUO Zheng, ZHUANG Zhijie, QIAO Hongxia, HONG Jinxiang. Effect and Mechanism Analysis of Carboxylic Acid Type Hydrophobic Agent on Cement Hydration[J]. BULLETIN OF THE CHINESE CERAMIC SOCIETY, 2024, 43(8): 2768-2777.

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