纳米碳材料在水泥基材料中分散技术及表征方法的研究进展

硅酸盐通报 ›› 2024, Vol. 43 ›› Issue (5): 1796-1811.

所属专题：水泥混凝土

纳米碳材料在水泥基材料中分散技术及表征方法的研究进展

李雨洋^1,2, 赵立革³, 刘爽^1,2, 韩康^1,2, 刘艳军^1,2, 李润丰^1,2, 郑永超^1,2

1.北京建筑材料科学研究总院有限公司,北京 100041;
2.固废资源化利用与节能建材国家重点实验室,北京 100041;
3.金隅住宅产业化(唐山)有限公司,唐山 064108

收稿日期:2023-11-02 修订日期:2023-12-20 出版日期:2024-05-15 发布日期:2024-06-06
通信作者: 刘爽,博士,教授级高级工程师。E-mail:liushuang@bbma.com.cn
作者简介:李雨洋(1997—),女,工程师。主要从事纳米材料的合成及应用方面的研究。E-mail:15617635046@163.com
基金资助:
北京金隅集团2023年重点科研项目(B20234002)

Research Progress in Dispersion Technology and Characterization Methods of Carbon Nanomaterials in Cementitious Materials

LI Yuyang^1,2, ZHAO Lige³, LIU Shuang^1,2, HAN Kang^1,2, LIU Yanjun^1,2, LI Runfeng^1,2, ZHENG Yongchao^1,2

1. Beijing Building Materials Academy of Sciences Research, Beijing 100041, China;
2. State Key Laboratory of Solid Waste Reuse for Building Materials, Beijing 100041, China;
3. BBMG Housing Industrialization (Tangshan) Co., Ltd., Tangshan 064108, China

Received:2023-11-02 Revised:2023-12-20 Online:2024-05-15 Published:2024-06-06

摘要/Abstract

摘要： 纳米碳材料具有独特的结构和优异的性能,能够作为增强材料改善水泥基材料的性能,受到了广泛研究与关注,然而这均以纳米碳材料在水泥中能够良好分散为基础。纳米碳材料比表面积大,分子间作用力强,难以直接分散在水泥基体中,且分散效果也不易判断。本文系统梳理了常见的纳米碳材料在水泥基材料中团聚的机理,总结了近年来国内外学者采用的分散技术,详细分析了各种分散方法的机理与优缺点,同时列举了纳米碳材料在水泥基材料中分散效果的表征方法。在未来的研究中,可以重点开发更高效、更适合工业化生产的分散方法,研究纳米碳材料在水泥基体中真实分散状态的评价手段,助力纳米碳改性水泥基复合材料在实际工程项目中的规模化应用。

关键词: 纳米碳材料, 水泥基材料, 团聚, 分散, 改性, 表征方法

Abstract: Carbon nanomaterials have received extensive research and attention because of unique structure and excellent performance to be used as reinforcing materials to improve the performance of cementitious materials. However, the enhancement effect is based on the good dispersion of carbon nanomaterials in the cement. The large specific surface area and strong intermolecular forces of carbon nanomaterials make them difficult to be dispersed in the cement matrix, and the dispersion effect is difficult to judge. This paper systematically sorts out the mechanism of common carbon nanomaterials agglomeration in cementitious materials, summarizes the dispersion techniques adopted by scholars in recent years, analyses the mechanism, advantages and disadvantages of various dispersion methods in detail, and lists the characterization methods for the dipersion effect of carbon nanomaterials in cementitious material. In the future, the research should focus on the development of more efficient and suitable dispersion methods for industrialized production, and the means of evaluating the real dispersion state of carbon nanomaterials in the cement matrix, which can facilitate the scale-up of nanocarbon-modified cementitious composites for application in real engineering projects.

Key words: carbon nanomaterial, cementitious material, agglomeration, dispersion, modification, characterization method

中图分类号:

TU528.57

李雨洋, 赵立革, 刘爽, 韩康, 刘艳军, 李润丰, 郑永超. 纳米碳材料在水泥基材料中分散技术及表征方法的研究进展[J]. 硅酸盐通报, 2024, 43(5): 1796-1811.

LI Yuyang, ZHAO Lige, LIU Shuang, HAN Kang, LIU Yanjun, LI Runfeng, ZHENG Yongchao. Research Progress in Dispersion Technology and Characterization Methods of Carbon Nanomaterials in Cementitious Materials[J]. BULLETIN OF THE CHINESE CERAMIC SOCIETY, 2024, 43(5): 1796-1811.

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纳米碳材料在水泥基材料中分散技术及表征方法的研究进展

Research Progress in Dispersion Technology and Characterization Methods of Carbon Nanomaterials in Cementitious Materials

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