光固化3D打印制备高性能BaTiO3压电陶瓷

硅酸盐通报 ›› 2024, Vol. 43 ›› Issue (5): 1764-1771.

• “3D 打印无机非金属材料”专题(II) • 上一篇下一篇

光固化3D打印制备高性能BaTiO₃压电陶瓷

毕鲁南¹, 李伶¹, 宋涛¹, 王营营¹, 吕佳琪¹, 路翔¹, 韩卓群², 汪洋²

1.山东工业陶瓷研究设计院有限公司,淄博 255035;
2.济南大学材料科学与工程学院,济南 250024

收稿日期:2023-12-26 修订日期:2024-02-19 出版日期:2024-05-15 发布日期:2024-06-06
通信作者: 李伶,博士,教授级高级工程师。E-mail:sinomaliling@126.com
作者简介:毕鲁南(1994—),男,硕士研究生。主要从事先进陶瓷增材制造的研究。E-mail:biln0108@163.com
基金资助:
山东省重点研发计划(竞争性创新平台)(2022XPT003)

Preparation of High-Performance BaTiO₃ Piezoelectric Ceramics by Stereolithography 3D Printing

BI Lunan¹, LI Ling¹, SONG Tao¹, WANG Yingying¹, LYU Jiaqi¹, LU Xiang¹, HAN Zhuoqun², WANG Yang²

1. Shandong Industrial Ceramic Research and Design Institute Co., Ltd., Zibo 255035, China;
2. School of Materials Science and Engineering, University of Jinan, Jinan 250024, China

Received:2023-12-26 Revised:2024-02-19 Online:2024-05-15 Published:2024-06-06

摘要/Abstract

摘要： 光固化3D打印技术在制备异形压电陶瓷方面具有广阔的应用前景。本文采用数字光处理技术制备了钛酸钡(BaTiO₃)压电陶瓷,研究了坯体形貌、烧结温度对钛酸钡微观结构的影响。结果表明,曲拉通X-100的引入使陶瓷料浆的黏度小于3 Pa·s,同时陶瓷粉体的引入未改变树脂的性质。陶瓷坯体层间结合良好,且无明显缺陷。烧成后的BaTiO₃陶瓷内部含有四方与正交两种晶相,剩余极化强度为27.6 μC/cm²,矫顽场为4.6 kV/cm,相对介电常数为2 512,介电损耗为0.009 1,居里温度为167 ℃,介电常数为182 pC/N。

关键词: 钛酸钡, 压电陶瓷, 数字光处理技术, 增材制造, 铁电性能, 介电性能

Abstract: Stereolithography 3D printing technology has broad application prospects in the preparation of special-shaped piezoelectric ceramics. In this paper, barium titanate (BaTiO₃) piezoelectric ceramics were prepared by digital light processing technology. The effects of green body morphology and sintering temperature on the microstructure of barium titanate were studied. The results show that the introduction of Triton X-100 makes the viscosity of ceramic slurry less than 3 Pa·s, and the introduction of ceramic powder does not change the properties of resin. The bonding between the layers of ceramic green body is good, and there are no obvious defects. The BaTiO₃ ceramics after sintering contains tetragonal and orthorhombic phases. The remanent polarization is 27.6 μC/cm², the coercive field is 4.6 kV/cm, the relative dielectric constant is 2 512, the dielectric loss is 0.009 1, the Curie temperature is 167 ℃, and the dielectric constant is 182 pC/N.

Key words: barium titanate, piezoelectric ceramics, digital light processing technology, additive manufacturing, ferroelectric property, dielectric property

中图分类号:

TQ174

毕鲁南, 李伶, 宋涛, 王营营, 吕佳琪, 路翔, 韩卓群, 汪洋. 光固化3D打印制备高性能BaTiO₃压电陶瓷[J]. 硅酸盐通报, 2024, 43(5): 1764-1771.

BI Lunan, LI Ling, SONG Tao, WANG Yingying, LYU Jiaqi, LU Xiang, HAN Zhuoqun, WANG Yang. Preparation of High-Performance BaTiO₃ Piezoelectric Ceramics by Stereolithography 3D Printing[J]. BULLETIN OF THE CHINESE CERAMIC SOCIETY, 2024, 43(5): 1764-1771.

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光固化3D打印制备高性能BaTiO₃压电陶瓷

Preparation of High-Performance BaTiO₃ Piezoelectric Ceramics by Stereolithography 3D Printing

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