硅烷偶联剂对氧化铝陶瓷浆料流动性能和3D打印性能的影响

硅酸盐通报 ›› 2024, Vol. 43 ›› Issue (3): 1058-1069.

所属专题：陶瓷

硅烷偶联剂对氧化铝陶瓷浆料流动性能和3D打印性能的影响

缪新宇¹, 刘双宇¹, 陆萍², 张福隆¹, Vasilieva Tatiana Mikhailovna³, 黄传锦¹, 王立岩¹, 王斌华⁴

1.盐城工学院机械工程学院,盐城 224051;
2.盐城工学院汽车工程学院,盐城 224051;
3.莫斯科物理技术学院,多尔戈普鲁德内 141700;
4.江苏铬莱伯数字科技有限公司,盐城 224001

收稿日期:2023-11-15 修订日期:2023-12-08 出版日期:2024-03-15 发布日期:2024-03-27
通信作者: 刘双宇,博士,教授。E-mail:liushuangyu@ycit.edu.cn
作者简介:缪新宇(1997—),男,硕士研究生。主要从事光固化陶瓷性能的研究。E-mail:1304952350@qq.com
基金资助:
江苏省创新创业人才项目(JSSCRC2021545)

Effect of Silane Coupling Agent on Flow and 3D Printing Performance of Alumina Ceramic Pastes

MIAO Xinyu¹, LIU Shuangyu¹, LU Ping², ZHANG Fulong¹, Vasilieva Tatiana Mikhailovna³, HUANG Chuanjin¹, WANG Liyan¹, WANG Binhua⁴

1. College of Mechanical Engineering, Yancheng Institute of Technology, Yancheng 224051, China;
2. College of Automotive Engineering, Yancheng Institute of Technology, Yancheng 224051, China;
3. Moscow Institute of Physics and Technology, Drezna 141700, Russia;
4. Jiangsu Global Laser Box Digital Tech Co., Ltd., Yancheng 224001, China

Received:2023-11-15 Revised:2023-12-08 Online:2024-03-15 Published:2024-03-27

摘要/Abstract

摘要： 基于光固化3D打印技术需要高固相含量、低黏度的陶瓷浆料以防止烧结陶瓷部件产生裂纹、孔洞、翘曲等缺陷,通过测试流变性能与固化性能,本文优化了树脂单体的选用及配比,采用KH550、KH560、KH570三种硅烷偶联剂对Al₂O₃粉体表面改性,以改善陶瓷浆料的流变性能和稳定性,探讨了硅烷偶联剂降低Al₂O₃陶瓷浆料体系黏度的机理,获得了固相含量为75%(质量分数)(体积分数为45.5%)、黏度为4 540 mPa·s的Al₂O₃陶瓷浆料,并提出了一种光固化Al₂O₃陶瓷浆料制备的优化方法,这有望对用于制备复杂陶瓷的高固含量、低黏度的3D打印Al₂O₃陶瓷浆料提供帮助。

关键词: 光固化技术, 氧化铝陶瓷, 浆料优化, 表面改性, 硅烷偶联剂, 3D打印性能

Abstract: In order to prevent cracks, holes, warpage and other defects in sintered ceramic parts, ceramic paste with high solid content and low viscosity is needed based on light-curing 3D printing technology. By testing the flow and curing proformances, the selection and ratio of resin monomers were optimized. KH550, KH560 and KH570 were used to modify the surface of Al₂O₃ powder to improve flow performance and stability of ceramic paste. The mechanism of silane coupling agent reducing the viscosity of Al₂O₃ ceramic paste was discussed. Al₂O₃ ceramic paste with a solid content of 75% (mass fraction) (volume fraction of 45.5%) and a viscosity of 4 540 mPa·s was obtained. An optimization method for the preparation of light-curing Al₂O₃ ceramic paste was proposed, which is expected to be helpful for the preparation of 3D printing Al₂O₃ ceramic paste with high solid content and low viscosity for complex ceramics.

Key words: light-curing technology, alumina ceramics, paste optimisation, surface modification, silane coupling agent, 3D printing performance

中图分类号:

TQ174

缪新宇, 刘双宇, 陆萍, 张福隆, Vasilieva Tatiana Mikhailovna, 黄传锦, 王立岩, 王斌华. 硅烷偶联剂对氧化铝陶瓷浆料流动性能和3D打印性能的影响[J]. 硅酸盐通报, 2024, 43(3): 1058-1069.

MIAO Xinyu, LIU Shuangyu, LU Ping, ZHANG Fulong, Vasilieva Tatiana Mikhailovna, HUANG Chuanjin, WANG Liyan, WANG Binhua. Effect of Silane Coupling Agent on Flow and 3D Printing Performance of Alumina Ceramic Pastes[J]. BULLETIN OF THE CHINESE CERAMIC SOCIETY, 2024, 43(3): 1058-1069.

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硅烷偶联剂对氧化铝陶瓷浆料流动性能和3D打印性能的影响

Effect of Silane Coupling Agent on Flow and 3D Printing Performance of Alumina Ceramic Pastes

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