层状Al2O3/EP复合材料的可控制备及性能研究

硅酸盐通报 ›› 2023, Vol. 42 ›› Issue (6): 2273-2280.

所属专题：新型功能材料

• 新型功能材料 • 上一篇

层状Al₂O₃/EP复合材料的可控制备及性能研究

侯俊峰^1,2, 唐鹏程^1,2, 田少华¹, 张明哲^1,2, 吴集思³

1.北方民族大学材料科学与工程学院,银川 750021;
2.碳基先进陶瓷制备技术国家地方联合工程研究中心,银川 750021;
3.南昌航空大学航空制造工程学院,南昌 330000

收稿日期:2023-03-22 修订日期:2023-03-22 出版日期:2023-06-15 发布日期:2023-06-25
作者简介:侯俊峰(1979—),男,博士,讲师。主要从事功能陶瓷材料的研究。E-mail:hou8635@yeah.net
基金资助:
北方民族大学研究生创新项目(YCX22140);北方民族大学一般科研项目(2016KY06)

Controllable Preparation and Properties of Layered Al₂O₃/EP Composites

HOU Junfeng^1,2, TANG Pengcheng^1,2, TIAN Shaohua¹, ZHANG Mingzhe^1,2, WU Jisi³

1. School of Materials Science & Engineering, North Minzu University, Yinchuan 750021, China;
2. National and Local Joint Engineering Research Center of Advanced Carbon Based Ceramics Preparation Technology, Yinchuan 750021, China;
3. School of Aeronautical Manufacturing Engineering, Nanchang Hangkong University, Nanchang 330000, China

Received:2023-03-22 Revised:2023-03-22 Online:2023-06-15 Published:2023-06-25

摘要/Abstract

摘要： 采用冰模板法构筑具有层状结构的Al₂O₃三维网络骨架,并通过真空浸渍工艺制备出Al₂O₃/环氧树脂(EP)复合材料。研究了楔形硅橡胶角度、浆料固相含量、冷冻温度对层状Al₂O₃三维网络骨架微观结构的影响,分析了片层间距对Al₂O₃/EP复合材料导热、介电和绝缘性能的影响。结果表明:楔形硅橡胶角度为10°和15°时Al₂O₃三维网络骨架的层状有序性最佳,固相含量的增加和冷冻温度的降低均会使片层间距减小;Al₂O₃/EP复合材料的热导率和介电常数随着片层间距的减小而增大,但体积电阻率呈降低趋势;当片层间距为45 μm时,热导率达到0.52 W/(m·K),体积电阻率为10¹² Ω·cm。

关键词: Al₂O₃三维网络骨架, Al₂O₃/EP复合材料, 冰模板法, 热导率, 介电常数, 体积电阻率

Abstract: The Al₂O₃ 3D network skeletons with layered structure were constructed by ice template method. The epoxy (EP) was successfully infiltrated into the pores of porous Al₂O₃ material by vacuum impregnation process, and finally the Al₂O₃/EP composites were prepared. The influences of wedge silicone rubber angle, slurry solid content and freezing temperature on the microstructure of layered Al₂O₃ 3D network skeleton were investigated. And the influence of the lamellar spacing on the thermal, dielectric and insulation properties of Al₂O₃/EP composites was analyzed. The results show that the order of layered Al₂O₃ 3D network skeleton is the best with the wedge silicone rubber angle of 10° and 15°. Simultaneously, the lamellar spacing in the Al₂O₃ 3D network skeleton decreases with the increase of solid content and the decrease of freezing temperature. The thermal conductivity and dielectric constant of Al₂O₃/EP composites increase with the decrease of the lamellar spacing, but the volume resistivity shows a decreasing trend. When the lamellar spacing is 45 μm, the thermal conductivity reaches 0.52 W/(m·K) and the volume resistivity is 10¹² Ω·cm.

Key words: Al₂O₃ 3D network skeleton, Al₂O₃/EP composite, ice template method, thermal conductivity, dielectric constant, volume resistivity

中图分类号:

TB332

侯俊峰, 唐鹏程, 田少华, 张明哲, 吴集思. 层状Al₂O₃/EP复合材料的可控制备及性能研究[J]. 硅酸盐通报, 2023, 42(6): 2273-2280.

HOU Junfeng, TANG Pengcheng, TIAN Shaohua, ZHANG Mingzhe, WU Jisi. Controllable Preparation and Properties of Layered Al₂O₃/EP Composites[J]. BULLETIN OF THE CHINESE CERAMIC SOCIETY, 2023, 42(6): 2273-2280.

参考文献

[1] 王瑾玉, 张永海, 魏进家. 功率器件热界面材料研究进展[J]. 工程热物理学报, 2022, 43(10): 2699-2710.
WANG J Y, ZHANG Y H, WEI J J. A review of thermal interface materials for power devices[J]. Journal of Engineering Thermophysics, 2022, 43(10): 2699-2710 (in Chinese).
[2] SCIAMANNA V, NAIT-ALI B, GONON M. Mechanical properties and thermal conductivity of porous alumina ceramics obtained from particle stabilized foams[J]. Ceramics International, 2015, 41(2): 2599-2606.
[3] WU G L, WANG Y Q, WANG K K, et al. The effect of modified AlN on the thermal conductivity, mechanical and thermal properties of AlN/polystyrene composites[J]. RSC Advances, 2016, 6(104): 102542-102548.
[4] ZHAO J W, ZHAO R, HUO Y K, et al. Effects of surface roughness, temperature and pressure on interface thermal resistance of thermal interface materials[J]. International Journal of Heat and Mass Transfer, 2019, 140: 705-716.
[5] CHUNG D D L. Performance of thermal interface materials[J]. Small, 2022, 18(16): e2200693.
[6] YU S Q, HUANG M M, HAO R, et al. Recent advances in thermally conductive polymer composites[J]. High Performance Polymers, 2022, 34(10): 1081-1101.
[7] MA H Q, GAO B, WANG M Y, et al. Strategies for enhancing thermal conductivity of polymer-based thermal interface materials: a review[J]. Journal of Materials Science, 2021, 56(2): 1064-1086.
[8] XU Y F, WANG X J, HAO Q. A mini review on thermally conductive polymers and polymer-based composites[J]. Composites Communications, 2021, 24: 100617.
[9] ZHANG F, FENG Y Y, FENG W. Three-dimensional interconnected networks for thermally conductive polymer composites: design, preparation, properties, and mechanisms[J]. Materials Science and Engineering: R: Reports, 2020, 142: 100580.
[10] MEHRA N, LI Y F, YANG X T, et al. Engineering molecular interaction in polymeric hybrids: effect of thermal linker and polymer chain structure on thermal conduction[J]. Composites Part B: Engineering, 2019, 166: 509-515.
[11] HUANG Y F, WANG Z G, YU W C, et al. Achieving high thermal conductivity and mechanical reinforcement in ultrahigh molecular weight polyethylene bulk material[J]. Polymer, 2019, 180: 121760.
[12] GU J W, LV Z Y, WU Y L, et al. Enhanced thermal conductivity of SiCp/PS composites by electrospinning-hot press technique[J]. Composites Part A: Applied Science and Manufacturing, 2015, 79: 8-13.
[13] JIANG F, CUI S Q, RUNGNIM C, et al. Control of a dual-cross-linked boron nitride framework and the optimized design of the thermal conductive network for its thermoresponsive polymeric composites[J]. Chemistry of Materials, 2019, 31(18): 7686-7695.
[14] 王绪彬, 张昌海, 张天栋, 等. 三维多孔氮化铝/环氧树脂复合材料的导热与电性能[J]. 复合材料学报: 1-7 (2022-09-06) [2023-02-15]. https://doi.org/10.13801/j.cnki.fhclxb.20220905.002.
WANG X B, ZHANG C H, ZHANG T D, et al. Thermal conductivity and electrical properties of three-dimensional porous aluminum nitride/epoxy composites[J]. Acta Materiae Compositae Sinica: 1-7 (2022-09-06) [2023-02-15]. https://doi.org/10.13801/j.cnki.fhclxb.20220905.002 (in Chinese).
[15] LIANG J Z, ZHU B. Estimation of thermal conductivity of polymer multiphase composites[J]. Polymer Engineering & Science, 2017, 57(9): 965-972.
[16] QU J Y, FAN L, MUKERABIGWI J F, et al. A silicon rubber composite with enhanced thermal conductivity and mechanical properties based on nanodiamond and boron nitride fillers[J]. Polymer Composites, 2021, 42(9): 4390-4396.
[17] LEE W, WIE J, KIM J. Enhancement of thermal conductivity of alumina/epoxy composite using poly (glycidyl methacrylate) grafting and crosslinking[J]. Ceramics International, 2021, 47(13): 18662-18668.
[18] ZHAO Z B, DU X Y, WANG Y, et al. Preparation of a novel bi-layer modified alumina-based hybrid material and its effect on the thermal conductivity enhancement of polymer composites[J]. Ceramics International, 2022, 48(11): 15483-15492.
[19] HU Y, DU G P, CHEN N. A novel approach for Al₂O₃/epoxy composites with high strength and thermal conductivity[J]. Composites Science and Technology, 2016, 124: 36-43.

层状Al₂O₃/EP复合材料的可控制备及性能研究

Controllable Preparation and Properties of Layered Al₂O₃/EP Composites

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