平板玻璃行业的脱碳技术研究进展

摘要/Abstract

摘要： 平板玻璃行业是典型的高能耗、高排放行业,在实现碳中和目标过程中不容忽视。平板玻璃行业的碳排放来源于能源消耗和原料中碳酸盐的分解,其中能源消耗是最主要来源,占比80%左右。减少对化石燃料的依赖、提高玻璃熔窑热效率是平板玻璃行业脱碳的主要途径。原料中碳酸盐热分解产生的碳排放约占20%,优化配合料的配方、减少碳酸盐原料引入等方式是有效的脱碳策略。碳捕集可用于减少平板玻璃生产过程中不可避免的二氧化碳排放。本文分析了平板玻璃工业的脱碳技术研究现状及面临的挑战,并探讨了适合我国平板玻璃行业的脱碳策略。

关键词: 平板玻璃, 脱碳, 燃料替代, 余热回收, 熔化技术, 碳捕获

Abstract: The flat glass industry is a typical industry with high energy consumption and high emission, which cannot be ignored in achieving carbon neutrality goal. Carbon emission of flat glass industry comes from energy consumption and decomposition of carbonates in raw materials, where energy consumption is dominant and accounts for about 80%. Thus, reducing dependence on fossil fuels and enhancing thermal efficiency of glass furnaces are main ways for decarbonization in flat glass industry. The carbon emission from thermal decomposition of carbonate in raw material accounts for around 20%. Optimizing compound formulation and reducing the introduction of carbonate raw material are effective decarbonization strategies. Furthermore, carbon capture can be used to reduce the unavoidable emission of carbon dioxide during the production of flat glass. This paper reviewed the current research status and challenges of decarbonization technology in flat glass industry and explored decarbonization technology suitable for the situation of flat glass industry in China.

Key words: flat glass, decarbonization, fuel substitution, heat recovery, melting technology, carbon capture

中图分类号:

TQ171.9

周文彩, 周芸, 刘晓鹏, 曾红杰, 杨清荃, 王川申, 官敏. 平板玻璃行业的脱碳技术研究进展[J]. 硅酸盐通报, 2023, 42(5): 1875-1885.

ZHOU Wencai, ZHOU Yun, LIU Xiaopeng, ZENG Hongjie, YANG Qingquan, WANG Chuanshen, GUAN Min. Research Progress on Decarbonization Technology for Flat Glass Industry[J]. BULLETIN OF THE CHINESE CERAMIC SOCIETY, 2023, 42(5): 1875-1885.

参考文献

[1] ROUDIER S, SANCHO L, SCALET B, et al. Best available techniques (BAT) reference document for the manufacture of glass[M]. Spain: Joint Research Centre of European Commission, 2013: 93.
[2] ZIER M, STENZEL P, KOTZUR L, et al. A review of decarbonization options for the glass industry[J]. Energy Conversion and Management: X, 2021, 10: 100083.
[3] SCHMITZ A, KAMIİSKI J, MARIA SCALET B, et al. Energy consumption and CO₂ emissions of the European glass industry[J]. Energy Policy, 2011, 39(1): 142-155.
[4] HU P P, LI Y Z, ZHANG X Z, et al. CO₂ emission from container glass in China, and emission reduction strategy analysis[J]. Carbon Management, 2018, 9(3): 303-310.
[5] GALITSKY C, WORRELL E, GALITSKY C, et al. Energy efficiency improvement and cost saving opportunities for the glass industry[EB/OL]. 2008-03-01. https://www.osti.gov/biblio/927883.
[6] HASANBEIGI A, PRICE L, ARENS M. Emerging energy-efficiency and carbon dioxide emissions-reduction technologies for the iron and steel industry[EB/OL]. 2013-01-31. https://www.osti.gov/biblio/1172118.
[7] PAPADOGEORGOS Y. Decarbonisation of the Dutch container glass industry by 2050[D]. Delft: Delft University of Technology, 2019: 37-56.
[8] 严玉廷, 刘晶茹, 丁宁, 等. 中国平板玻璃生产碳排放研究[J]. 环境科学学报, 2017, 37(8): 3213-3219.
YAN Y T, LIU J R, DING N, et al. Investigation on CO₂ emissions from flat glass production in China[J]. Acta Scientiae Circumstantiae, 2017, 37(8): 3213-3219 (in Chinese).
[9] BEERKENS R G C, VAN LIMPT J. Energy efficiency benchmarking of glass furnaces[M]//62nd Conference on Glass Problems: Ceramic Engineering and Science Proceedings, Volume 23, Issue 1. Hoboken, NJ, USA: John Wiley & Sons, Inc., 2008: 93-105.
[10] LEICHER J, MÄRTIN M, GIESE A, et al. Investigations on the use of biogas for glass melting[C]//Proceedings of the European Combustion Meeting 2015, Budapest, Hungary, Budapest, Hungary, 2015.
[11] LEICHER J, GIESE A, GÖRNER K, et al. Utilization of biogas in glass melting applications[C]//Proceedings of ECOS 2015-The 28th Internationl Conference on Efficiency, Cost, Optimization, Simulation and Environmental Impact of Energy Systems, Pau, France, 2015.
[12] TORRIJOS M. State of development of biogas production in Europe[J]. Procedia Environmental Sciences, 2016, 35: 881-889.
[13] 陈雷, 荒木幹也, 志贺圣一, 等. 生物质燃气各组分气体燃烧与排放特性试验[J]. 农业机械学报, 2013, 44(5): 31-34.
CHEN L, ARAKI M, SHIGA S, et al. Combustion and emission characteristics of individual component of biogas in SI engine[J]. Transactions of the Chinese Society for Agricultural Machinery, 2013, 44(5): 31-34 (in Chinese).
[14] 孙康泰, 张辉, 魏珣, 等. 生物燃气产业发展现状与商业模式创新研究[J]. 林产化学与工业, 2014, 34(5): 175-180.
SUN K T, ZHANG H, WEI X, et al. Review on the current situation and business model innovation of biogas industry in China[J]. Chemistry and Industry of Forest Products, 2014, 34(5): 175-180 (in Chinese).
[15] 渠沛然. 生物天然气产业蓄势待发[N]. 中国能源报, 2022-06-13.
QU P R. Bio-natural gas is poised to take off[N]. China Energy News, 2022-06-13 (in Chinese).
[16] 马玉聪. 碳减排对平板玻璃熔化技术发展影响[J]. 玻璃, 2021, 48(4): 30-33.
MA Y C. Effect of carbon emission reduction on the development of flat glass melting technology[J]. Glass, 2021, 48(4): 30-33 (in Chinese).
[17] 李顶杰, 张丁南, 李红杰, 等. 中国生物柴油产业发展现状及建议[J]. 国际石油经济, 2021, 29(8): 91-98.
LI D J, ZHANG D N, LI H J, et al. Development status and suggestion of biodiesel industry in China[J]. International Petroleum Economics, 2021, 29(8): 91-98 (in Chinese).
[18] STEVE G, SOVACOOL BENJAMIN K, JINSOO K, et al. Industrial decarbonization via hydrogen: a critical and systematic review of developments, socio-technical systems and policy options[J]. Energy Research & Social Science, 2021, 80: 102208.
[19] IRESON R, FULLER A, WOODS J, et al. Alternative fuel switching technologies for the glass sector[EB/OL]. 2019-11. https://assets.publishing.service.gov.uk/government/uploads/system/uploads/attachment_data/file/866364/Phase_2_-_Glass_Futures_-_Fuel_Switching_Tech_for_Glass_Sector.
[20] ANDREWS G E, ALTAHER M A, LI H. Hydrogen combustion at high combustor airflow using an impinging jet flame stabiliser with no flashback and low NO_x[C]//Proceedings of ASME Turbo Expo 2012: Turbine Technical Conference and Exposition, June 11-15, 2012, Copenhagen, Denmark. 2013: 1479-1489.
[21] 贺有乐. 玻璃工业中天然气掺氢技术[J]. 玻璃, 2022, 49(7): 40-44.
HE Y L. Technology of the mixture of natural gas and hydrogen in glass industry[J]. Glass, 2022, 49(7): 40-44 (in Chinese).
[22] 刘志海. 平板玻璃行业如何从低碳走向碳中和[J]. 玻璃, 2021, 48(3): 1-5.
LIU Z H. How does the flat glass industry move from low carbon to carbon neutral[J]. Glass, 2021, 48(3): 1-5 (in Chinese).
[23] GARY C, RÉNE M. Electrifying glass production: a case study of supply chain innovation[EB/OL]. 2023-03-03. https://perspectives.se.com/blog-stream/electrifying-of-glass-production-a-case-study-of-supply-chain-innovation.
[24] CHAN Y, PETITHUGUENIN L, FLEITER T, et al. Industrial innovation: pathways to deep decarbonisation of Industry. Part 1: technology analysis[EB/OL]. 2019-01-20. https://ec.europa.eu/clima/system/files/2019-03/industrial_innovation_part_1_en.pdf.
[25] LECHTENBÖHMER S, NILSSON L J, ÅHMAN M, et al., Decarbonising the energy intensive basic materials industry through electrification: implications for future EU electricity demand[J]. Energy, 2016, 115: 1623-1631.
[26] ROUDIER S, SANCHO L, SCALET B, et al., Best available techniques (BAT) reference document for the manufacture of glass[M]. Spain: Joint Research Centre of European Commission, 2013: 74.
[27] WESSELING J H, LECHTENBÖHMER S, ÅHMAN M, et al., The transition of energy intensive processing industries towards deep decarbonization: Characteristics and implications for future research[J]. Renewable and Sustainable Energy Reviews, 2017, 79: 1303-1313.
[28] 王文峰. 玻璃电熔窑热过程数值模拟[D]. 包头: 内蒙古科技大学, 2020.
WANG W F. Numerical simulation of heating process of glass melting furnace[D]. Baotou: Inner Mongolia University of Science & Technology, 2020 (in Chinese).
[29] 王建生. 日用玻璃窑炉烟气余热回收利用技术探讨[C]. 大连: 2018年全国玻璃窑炉技术研讨交流会, 2018: 189-193.
WANG J S. Discussion on the recovery and utilization technology of flue gas waste heat in daily glass furnaces[C]. Dalian: 2018 National Glass Kiln Technology Seminar, 2018: 189-193 (in Chinese).
[30] KIM H, KANG T, KAISER K, et al. Heat oxy-combustion: an innovative energy saving solution for glass industry[M]//76th Conference on Glass Problems. Hoboken, NJ, USA: John Wiley & Sons, Inc., 2016: 149-155.
[31] GÖRÜNEY T, ARZAN N, KOÇ S, et al. Oxy-fuel tableware furnace with novel oxygen-and natural gas preheating system[M]//77th Conference on Glass Problems. Hoboken, NJ, USA: John Wiley & Sons, Inc., 2017: 73-82.
[32] 陶天训, 倪晶晶, 陈淑勇, 等. 玻璃配合料预热技术的理论与模拟分析[J]. 硅酸盐学报, 2018, 46(7): 1034-1042.
TAO T X, NI J J, CHEN S Y, et al. Theoretical and simulated study of glass batch preheating[J]. Journal of the Chinese Ceramic Society, 2018, 46(7): 1034-1042 (in Chinese).
[33] 曾小山, 玻璃窑炉全氧燃烧新技术: 普莱克斯OPTIMELT^TMTCR技术[J]. 玻璃, 2018, 45(10): 17-21.
ZENG X S. New oxy-fuel combustion technology of glass furnace-praxair OPTIMELT^TM TCR technology[J]. Glass, 2018, 45(10): 17-21 (in Chinese).
[34] LAUX S, IYOHA U, BELL R, et al. Advanced heat recovery for oxy-fuel fired glass furnaces with Optimelt^TM plus technology[C]//77th Conference on Glass Problems. Hoboken, NJ, USA: John Wiley & Sons, Inc., 2017: 83-92.
[35] 葛武军. 玻璃生产的节能减排和绿色环保[J]. 玻璃, 2017, 44(6): 41-46.
GE W J. Energy saving, emission reduction and green environmental protection in glass production[J]. Glass, 2017, 44(6): 41-46 (in Chinese).
[36] FEVE. Waste heat recovery technologies largely used in the European container glass industry to optimize energy consumption and reduce CO₂emissions[EB/OL]. 2023-03-03. https://feve.org/case_study/waste-heat-recovery-technologies-largely-used-in-the-european-container-glass-industry-to-optimize-energy-consumption-and-reduce-CO₂-emissions/.
[37] 曾雄伟, 赵恩录, 张文玲, 等. 浮法玻璃配合料粒化的研究[J]. 玻璃, 2007, 34(6): 14-16.
ZENG X W, ZHAO E L, ZHANG W L, et al. Research of float glass coordination material granulation[J]. Glass, 2007, 34(6): 14-16 (in Chinese).
[38] 赵彦林. 玻璃配合料的润湿[J]. 玻璃纤维, 1990(2): 48+46.
ZHAO Y L. Wetting of glass batch[J]. Fiber Glass, 1990(2): 48+46 (in Chinese).
[39] BEERKENS R. Energy balances of glass furnaces: parameters determining energy consumption of glass melt processes[C]. Columbu: 67th Conference on Glass Problems, 2007: 102-116.
[40] HANS VAN LIMPT R B, ANDRIES HABRAKEN. Overview of methods to recover energy from flue gases of glass furnaces-Impact on glass furnace energy consumption[EB/OL]. 2023-03-03. https://www.yumpu.com/en/document/read/11461820/overview-of-methods-to-recover-energy-from-flue-glasstrend.
[41] 叶瀚, 程亮, 王志瑞, 等. 玻璃配合料粒化的研究现状[J]. 玻璃, 2014, 41(10): 37-39.
YE H, CHENG L, WANG Z R, et al. The research status of float glass batch granulation[J]. Glass, 2014, 41(10): 37-39 (in Chinese).
[42] 张艳娟, 姚佩, 李红霞, 等. 浅谈玻璃熔制的节能降耗[J]. 玻璃, 2014, 41(4): 18-21.
ZHANG Y J, YAO P, LI H X, et al. Introduction of energy saving and consumption reducing in glass batch melted[J]. Glass, 2014, 41(4): 18-21 (in Chinese).
[43] 赵恩录. 玻璃熔窑全氧燃烧技术及发展方向[J]. 玻璃, 2021, 48(10): 68-72.
ZHAO E L. Oxy-fuel combustion technology and development direction of glass melting furnace[J]. Glass, 2021, 48(10): 68-72 (in Chinese).
[44] RUE D, BROWN J T. Submerged combustion melting of glass[J]. International Journal of Applied Glass Science, 2011, 2(4): 262-274.
[45] EERE P. Energy-efficient glass melting: Submerged combustion[EB/OL]. 2004-01-01. https://www.osti.gov/biblio/1216207.
[46] STORMONT R. Electric melting and boosting for glass quality improvement[EB/OL]. 2010-09-10. http://www.electroglass.co.uk/articles/2010-09%20Electric%20Melting%20%26%20Boosting%20for%20Glass%20Quality%20Improvement.pdf.
[47] SEO K, EDGAR T F, BALDEA M. Optimal demand response operation of electric boosting glass furnaces[J]. Applied Energy, 2020, 269: 115077.
[48] 刘志海,李超, 浮法玻璃工艺手册[M]. 北京: 化学工业出版社, 2013.
LIU Z H, LI C. Float glass process manual[M]. Beijing: Chemical Industry Press, 2013 (in Chinese).
[49] FEVE. Glass is a permanent material, endlessly recyclable[EB/OL]. 2023-03-03. https://feve.org/case_study/glass-is-a-permanent-material-endlessly-recyclable/.
[50] GRAEME DEBRINCAT E B. Re-thinking the life-cycle of architectural glass[EB/OL]. 2023-03-03. https://www.arup.com/perspectives/publications/research/section/re-thinking-the-life-cycle-of-architectural-glass.
[51] GUO P W, MENG W N, NASSIF H, et al. New perspectives on recycling waste glass in manufacturing concrete for sustainable civil infrastructure[J]. Construction and Building Materials, 2020, 257: 119579.
[52] MAIER P L, DURHAM S A. Beneficial use of recycled materials in concrete mixtures[J]. Construction and Building Materials, 2012, 29: 428-437.
[53] BEERKENS R, KERS G, VAN SANTEN E. Recycling of post-consumer glass: energy savings, CO₂ emission reduction, effects on glass quality and glass melting[M]//71st Conference on Glass Problems. Hoboken, NJ, USA: John Wiley & Sons, Inc., 2011: 167-194.
[54] 段永华. 水泥工业富氧燃烧CO₂捕集技术的理论和试验研究[D]. 西安: 西安建筑科技大学, 2015.
DUAN Y H. Theoretical and experimental study on oxygen enriched combustion technology in cement industry[D]. Xi’an: Xi’an University of Architecture and Technology, 2015 (in Chinese).
[55] BUDINIS S, KREVOR S, MAC DOWELL N, et al. An assessment of CCS costs, barriers and potential[J]. Energy Strategy Reviews, 2018, 22: 61-81.
[56] ZHAO T, LIU Z X. A novel analysis of carbon capture and storage (CCS) technology adoption: an evolutionary game model between stakeholders[J]. Energy, 2019, 189: 116352.
[57] EUROPE G F. Flat glass in climate-neutral Europe: triggering a virtuous cycle of decarbonisation[EB/OL]. 2020-02-06. https://glassforeurope.com/wp-content/uploads/2020/01/flat-glass-climate-neutral-europe.pdf.
[58] FURSZYFER DEL RIO D D, SOVACOOL B K, FOLEY A M, et al., Decarbonizing the glass industry: a critical and systematic review of developments, sociotechnical systems and policy options[J]. Renewable and Sustainable Energy Reviews, 2022, 155: 111885.
[59] 唐福恒. 玻璃熔窑蓄热室设计[J]. 玻璃, 2018, 45(12): 1-23.
TANG F H. Design of regenerator of glass melting furnace[J]. Glass, 2018, 45(12): 1-23 (in Chinese).