赤泥-石膏复合激发蒸压加气混凝土的制备与性能研究

硅酸盐通报 ›› 2023, Vol. 42 ›› Issue (4): 1393-1399.

所属专题：资源综合利用

赤泥-石膏复合激发蒸压加气混凝土的制备与性能研究

黄利祥¹, 刘泽¹, 原航¹, 王栋民¹, 危鹏², 姜宏健²

1.中国矿业大学(北京)化学与环境工程学院,北京 100083;
2.上海百奥恒新材料有限公司,上海 200042

收稿日期:2022-12-06 修订日期:2023-01-12 出版日期:2023-04-15 发布日期:2023-04-25
通信作者: 刘泽,博士,教授。E-mail:lzk1227@sina.com
作者简介:黄利祥(1995—),男,硕士研究生。主要从事固废资源化利用方面的研究。E-mail:hlx2575@163.com
基金资助:
国家自然科学基金联合基金(U20A20324);宁夏回族自治区重点研发计划(2021BEG92002)

Preparation and Properties of Autoclaved Aerated Concrete with Red Mud-Gypsum Composite Excitation

HUANG Lixiang¹, LIU Ze¹, YUAN Hang¹, WANG Dongmin¹, WEI Peng², JIANG Hongjian²

1. School of Chemical and Environmental Engineering, China University of Mining and Technology (Beijing), Beijing 100083, China;
2. Shanghai Baiaoheng New Materials Co., Ltd., Shanghai 200042, China

Received:2022-12-06 Revised:2023-01-12 Online:2023-04-15 Published:2023-04-25

摘要/Abstract

摘要： 利用赤泥-石膏复合激发矿粉、粉煤灰制备蒸压加气混凝土,对促进赤泥资源化利用,降低硅酸盐水泥消耗以及实现二氧化碳减排具有重要意义。本文以强度级别A3.5、密度级别B06的蒸压加气混凝土为设计目标,分析了赤泥、石膏、矿粉以及生石灰掺量对蒸压加气混凝土抗压强度的影响。结果表明,当m(粉煤灰)∶m(赤泥)∶m(石膏)∶m(矿粉)∶m(生石灰)质量比为60∶10∶3∶7∶20时,蒸压加气混凝土试块的干密度为623.4 kg/m³,抗压强度为3.6 MPa。水化产物分析表明,蒸压加气混凝土试块在蒸压反应前水化产物主要为钙矾石,经过蒸压反应后水化产物主要为托勃莫来石和水石榴石。

关键词: 蒸压加气混凝土, 赤泥, 二氧化碳减排, 抗压强度, 干密度, 水化产物

Abstract: The autoclaved aerated concrete is prepared by using red mud-gypsum to excite blast furnace slag (BFS) and fly ash, which is of great significance to promote the resource utilization of red mud, reduce the consumption of Portland cement, and achieve CO₂ reduction. The autoclaved aerated concrete with strength grade A3.5 and density grade B06 was taken as the design goal, and the influences of red mud, gypsum, BFS, and quicklime on the compressive strength of autoclaved aerated concrete were analyzed. The results show that when the mass ratio of fly ash, red mud, gypsum, BFS and quicklime is 60∶10∶3∶7∶20, the dry density and compressive strength of autoclaved aerated concrete are 623.4 kg/m³ and 3.6 MPa, respectively. The analysis of hydration products shows that the hydration product before autoclave reaction is mainly ettringite, and the hydration products after autoclaved reaction are tobermorite and katoite.

Key words: autoclaved aerated concrete, red mud, CO₂ reduction, compressive strength, dry density, hydration product

中图分类号:

TU528

黄利祥, 刘泽, 原航, 王栋民, 危鹏, 姜宏健. 赤泥-石膏复合激发蒸压加气混凝土的制备与性能研究[J]. 硅酸盐通报, 2023, 42(4): 1393-1399.

HUANG Lixiang, LIU Ze, YUAN Hang, WANG Dongmin, WEI Peng, JIANG Hongjian. Preparation and Properties of Autoclaved Aerated Concrete with Red Mud-Gypsum Composite Excitation[J]. BULLETIN OF THE CHINESE CERAMIC SOCIETY, 2023, 42(4): 1393-1399.

参考文献

[1] 耿超, 郭士会, 刘志国, 等. 赤泥资源化综合利用现状及展望[J]. 中国有色冶金, 2022, 51(5): 37-45.
GENG C, GUO S H, LIU Z G, et al. Current situation and prospect of red mud resource comprehensive utilization[J]. China Nonferrous Metallurgy, 2022, 51(5): 37-45 (in Chinese).
[2] 侯双明, 高嵩, 李秋义, 等. 赤泥基碱激发胶凝材料的制备及机理研究[J]. 混凝土, 2020(1): 27-31.
HOU S M, GAO S, LI Q Y, et al. Preparation technology and mechanism of alkali-activated red mud based cementitious materials[J]. Concrete, 2020(1): 27-31 (in Chinese).
[3] YU P, KIRKPATRICK R J, POE B, et al. Structure of calcium silicate hydrate (C-S-H): near-, mid-, and far-infrared spectroscopy[J]. Journal of the American Ceramic Society, 2004, 82(3): 742-748.
[4] 展光美. 赤泥地聚合物制备技术及耐久性试验研究[D]. 徐州: 中国矿业大学, 2016: 13-18.
ZHAN G M. Preparation technology and durability of red mud geopolymer[D]. Xuzhou: China University of Mining and Technology, 2016: 13-18. (in Chinese)
[5] 刘次啟, 张强, 杨佳成. 蒸压加气混凝土砌块的研究现状[J]. 砖瓦, 2022(3): 34-36+39.
LIU C Q, ZHANG Q, YANG J C. Research status of autoclaved aerated concrete blocks[J]. Brick-Tile, 2022(3): 34-36+39 (in Chinese).
[6] 刘军, 郑先凤, 谢小莉, 等. 加气混凝土砌块全生命周期碳排放量的理论与实际分析[J]. 建筑砌块与砌块建筑, 2012(5): 43-45.
LIU J, ZHENG X F, XIE X L, et al. Theoretical and practical analysis of carbon emission of aerated concrete block in its whole life cycle[J]. Building Block & Block Construction, 2012(5): 43-45 (in Chinese).
[7] 王瑞燕, 岳涛. 赤泥-粉煤灰加气混凝土制备研究[J]. 新型建筑材料, 2011, 38(6): 31-34.
WANG R Y, YUE T. Study on preparation of red mud & fly ash aerated concrete[J]. New Building Materials, 2011, 38(6): 31-34 (in Chinese).
[8] 张泓泓, 詹树林, 徐强, 等. 赤泥对蒸压加气混凝土流动性和力学性能影响研究[J]. 新型建筑材料, 2020, 47(10): 119-122.
ZHANG H H, ZHAN S L, XU Q, et al. Study of the influence of red mud content on the fluidity and mechanical properties of aerated concrete[J]. New Building Materials, 2020, 47(10): 119-122 (in Chinese).
[9] DONG M H, RUAN S Q, ZHAN S L, et al. Utilization of red mud with high radiation for preparation of autoclaved aerated concrete (AAC): performances and microstructural analysis[J]. Journal of Cleaner Production, 2022, 347: 131293.
[10] 郭晖, 马小娥, 邢宝林. 利用赤泥和粉煤灰生产加气混凝土试块的试验研究[J]. 河南建材, 2006(5): 41-42+46.
GUO H, MA X E, XING B L. Experimental study on production of aerated concrete test block from red mud and fly ash[J]. Henan Building Materials, 2006(5): 41-42+46 (in Chinese).
[11] 饶益杰, 汪丽娟, 尹祥国, 等. 单一钙质材料生产砂加气混凝土砌块的试验研究与应用[J]. 新型建筑材料, 2019, 46(2): 138-141.
RAO Y J, WANG L J, YIN X G, et al. Research and application of production of aerated concrete block with single calcium material[J]. New Building Materials, 2019, 46(2): 138-141 (in Chinese).
[12] 何博晗, 孙科杰. 蒸压加气混凝土砌块的研究现状[J]. 四川建材, 2018, 44(11): 18-19.
HE B H, SUN K J. Development trend of autoclaved aerated concrete block[J]. Sichuan Building Materials, 2018, 44(11): 18-19 (in Chinese).
[13] 檀星, 韩福强, 赵风清. 一种全固废蒸压轻质砌块的研制[J]. 新型建筑材料, 2018, 45(11): 112-115+142.
TAN X, HAN F Q, ZHAO F Q. Development of a solid waste based autoclaved lightweight block[J]. New Building Materials, 2018, 45(11): 112-115+142 (in Chinese).
[14] QU X L, ZHAO X G. Previous and present investigations on the components, microstructure and main properties of autoclaved aerated concrete-A review[J]. Construction and Building Materials, 2017, 135: 505-516.[15] 王长龙, 乔春雨, 王爽, 等. 煤矸石与铁尾矿制备加气混凝土的试验研究[J]. 煤炭学报, 2014, 39(4): 764-770.
WANG C L, QIAO C Y, WANG S, et al. Experimental study on autoclaved aerated concrete from coal gangue and iron ore tailings[J]. Journal of China Coal Society, 2014, 39(4): 764-770 (in Chinese).
[16] 毛奎, 蔡亮, 吴小文, 等. 几种典型铁尾矿制备加气混凝土性能及水化机理研究[J]. 硅酸盐通报, 2019, 38(12): 3719-3725.
MAO K, CAI L, WU X W, et al. Hydration mechanism and properties of aerated concrete prepared by several typical iron tailings[J]. Bulletin of the Chinese Ceramic Society, 2019, 38(12): 3719-3725 (in Chinese).
[17] MOLLAH M Y A. A Fourier transform infrared spectroscopic investigation of the early hydration of Portland cement and the influence of sodium lignosulfonate[J]. Cement and Concrete Research, 2000, 30(2): 267-273.
[18] FANG YONG HAO, LU ZHENG LONG, WANG ZHONG LI. FT-IR study on early-age hydration of alkali-activated slag cement[J]. Key Engineering Materials, 2011, 492: 429-432.

赤泥-石膏复合激发蒸压加气混凝土的制备与性能研究

Preparation and Properties of Autoclaved Aerated Concrete with Red Mud-Gypsum Composite Excitation

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