亚硝酸钙与富铝矿相协同调控碱矿渣氯离子固化能力研究

硅酸盐通报 ›› 2023, Vol. 42 ›› Issue (4): 1148-1155.

所属专题：水泥混凝土

亚硝酸钙与富铝矿相协同调控碱矿渣氯离子固化能力研究

范小春¹, 汪阳^1,2, 高旭¹, 张宇¹, 袁波³

1.武汉理工大学土木工程与建筑学院,武汉 430070;
2.武汉理工大学三亚科教创新园,三亚 572000;
3.武汉理工大学材料科学与工程学院,武汉 430070

收稿日期:2022-11-24 修订日期:2022-12-26 出版日期:2023-04-15 发布日期:2023-04-25
通信作者: 汪阳,硕士研究生。E-mail:1559248971@qq.com
作者简介:范小春(1975—),男,博士,教授。主要从事新型混凝土材料与结构方面的研究。E-mail:fxcfree@126.com
基金资助:
国家自然科学基金(52108244,51902235);武汉市知识创新专项-曙光计划(2022010801020192);武汉理工大学三亚科创园开放基金(2021KF0001)

Coordinated Control of Chloride Binding Capacity of Alkali Activated Slag by Calcium Nitrite and Aluminum-Rich Mineral Phases

FAN Xiaochun¹, WANG Yang^1,2, GAO Xu¹, ZHANG Yu¹, YUAN Bo³

1. School of Civil Engineering and Architecture, Wuhan University of Technology, Wuhan 430070, China;
2. Sanya Science and Education Innovation Park, Wuhan University of Technology, Sanya 572000, China;
3. School of Materials Science and Engineering, Wuhan University of Technology, Wuhan 430070, China

Received:2022-11-24 Revised:2022-12-26 Online:2023-04-15 Published:2023-04-25

摘要/Abstract

摘要： 胶凝材料的氯离子固化能力是影响海工混凝土结构服役寿命的关键影响因素。选用亚硝酸钙作为额外钙相,偏高岭土或纳米氧化铝作为额外铝相,探究了钙相和铝相对碱矿渣胶凝材料水化产物、氯离子固化能力和宏观性能的影响。结果表明:亚硝酸钙和铝相的掺入有效促进了胶凝材料的化学反应和氯离子固化能力,胶凝材料的固氯量相较对照组提高了11.5%~34.8%;体系中的m(Ca)/m(Al)值对氯离子固化能力有重要影响,m(Ca)/m(Al)值的降低导致AFm相、C-(A)-S-H凝胶等产物生成量增加;亚硝酸钙的掺量存在极值,若掺量过高会对材料强度造成不利影响,但纳米氧化铝的加入可在一定程度上弥补这一缺陷。

关键词: 碱矿渣, 亚硝酸钙, 偏高岭土, 纳米氧化铝, AFm相, 氯离子固化

Abstract: The chloride binding capacity of cementitious materials is a key factor affecting the service life of marine concrete structures. Calcium nitrite was selected as additional calcium phases, and metakaolin or nano alumina was selected as additional aluminum phases. The effects of Ca-Al phases on hydration products, chloride binding capacity and macro performance of alkali activated slag cementitious materials were investigated. The results show that the addition of Ca-Al phases effectively promotes chemical reaction, and improves the chloride binding capacity of alkali activated slag cementitious materials. Compared with control group, the amount of binding chloride increases by 11.5%~34.8%. m(Ca)/m(Al) value in system has an important influence on chloride binding capacity. The decrease of m(Ca)/m(Al) value results in the increase of the content of AFm phases, C-(A)-S-H gels and other products. The content of calcium nitrite has an optimum value. Excessively high content of calcium nitrite negatively affects the strength, but nano alumina compensates for the strength loss. In general, the relative content of Ca-Al phases is important for phase composition and chloride binding capacity of alkali activated slag.

Key words: alkali activated slag, calcium nitrite, metakaolin, nano alumina, AFm phase, chloride binding

中图分类号:

TU528

范小春, 汪阳, 高旭, 张宇, 袁波. 亚硝酸钙与富铝矿相协同调控碱矿渣氯离子固化能力研究[J]. 硅酸盐通报, 2023, 42(4): 1148-1155.

FAN Xiaochun, WANG Yang, GAO Xu, ZHANG Yu, YUAN Bo. Coordinated Control of Chloride Binding Capacity of Alkali Activated Slag by Calcium Nitrite and Aluminum-Rich Mineral Phases[J]. BULLETIN OF THE CHINESE CERAMIC SOCIETY, 2023, 42(4): 1148-1155.

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亚硝酸钙与富铝矿相协同调控碱矿渣氯离子固化能力研究

Coordinated Control of Chloride Binding Capacity of Alkali Activated Slag by Calcium Nitrite and Aluminum-Rich Mineral Phases

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