花岗岩锯泥和大理石废石粉制备发泡陶瓷

硅酸盐通报 ›› 2023, Vol. 42 ›› Issue (3): 939-947.

所属专题：资源综合利用

花岗岩锯泥和大理石废石粉制备发泡陶瓷

董祎然¹, 赵成琳¹, 郭伟², 姜葱葱¹, 黄世峰¹, 程新¹

1.济南大学山东省建筑材料制备与测试技术重点实验室,济南 250022;
2.咸阳陶瓷研究设计院有限公司,咸阳 712000

收稿日期:2022-10-17 修订日期:2022-12-08 出版日期:2023-03-15 发布日期:2023-03-31
通信作者: 姜葱葱,博士,讲师。E-mail:mse_jiangcc@163.com;程新,博士,教授。E-mail:chengxin@ujn.edu.cn
作者简介:董祎然(1997—),女,硕士研究生。主要从事固体废弃物资源化利用、发泡陶瓷材料的研究。E-mail:2247646444@qq.com
基金资助:
山东省泰山学者攀登计划;济南市支持顶尖人才(团队)创新创业“一事一议”项目;济南市新高校20 条院所科研带头人工作室(2021GXRC087)

Preparation of Foamed Ceramics from Granite Scrap and Marble Scrap

DONG Yiran¹, ZHAO Chenglin¹, GUO Wei², JIANG Congcong¹, HUANG Shifeng¹, CHENG Xin¹

1. Shandong Provincial Key Laboratory of Preparation and Measurement of Building Materials, University of Jinan, Jinan 250022, China;
2. Xianyang Research & Design Institute of Ceramics Co., Ltd., Xianyang, 712000, China

Received:2022-10-17 Revised:2022-12-08 Online:2023-03-15 Published:2023-03-31

摘要/Abstract

摘要： 为实现“双碳”目标,推动大宗固废的资源化利用,开发探究多种固废协同制备发泡陶瓷材料的方法理论,以花岗岩锯泥和大理石废石粉为主要原料,SiC为发泡剂,通过高温烧结制备高闭气孔率的发泡陶瓷,研究原材料配比、烧结温度以及发泡剂掺量对发泡陶瓷的孔结构及性能的影响。结果表明,大理石废石粉中的CaCO₃在高温下分解出的CaO是有效的助熔剂,能够破坏Si—O键,降低液相的黏度,促进发泡。同时CaO能够与SiO₂反应生成硅灰石,提高材料的机械强度。在烧结温度为1 130 ℃、大理石废石粉质量掺量为10%、SiC质量掺量为1.0%时,制备的发泡陶瓷孔结构均匀,综合性能最佳,闭口气孔率为79.16%,体积密度为583.42 kg/m³,抗压强度为3.86 MPa,吸水率为0.40%。本研究为花岗岩锯泥和大理石废石粉回收利用制备发泡陶瓷提供了理论基础。

关键词: 发泡陶瓷, 花岗岩锯泥, 大理石废石粉, 碳化硅, 高温烧结, 固废利用

Abstract: To achieve the goal of “double carbon”and promote the resource utilization of bulk solid waste,the method and theory of coordinated preparation of foamed ceramics materials by various solid wastes were developed and explored. Foamed ceramics with high closed porosity were prepared by sintering at high temperature with granite scrap and marble scrap as main raw materials and SiC as foaming agent. The effects of raw material ratio, sintering temperature and foaming agent content on the pore structure and properties of foamed ceramics were investigated. The results show that at high temperature, CaO decomposed from the CaCO₃ component in marble scrap is an effective flux that destroys the Si—O bond, reduces viscosity of liquid phase and promotes smooth foaming. Meanwhile, CaO can react with SiO₂ to form wollastonite, which improves compressive strength of material. The foamed ceramics have the most favorable uniform pore structure and overall performance when the sintering temperature is 1 130 ℃, the marble scrap mass content is 10% and the SiC mass content is 1.0%, with the closed porosity of 79.16%, the bulk density of 583.42 kg/m³, the compressive strength of 3.86 MPa and the water absorption rate of 0.40%. This study provides a theoretical foundation for the preparation of foamed ceramics by recycling granite scrap and marble scrap.

Key words: foamed ceramics, granite scrap, marble scrap, silicon carbide, high-temperature sintering, solid waste utilization

中图分类号:

TQ174

董祎然, 赵成琳, 郭伟, 姜葱葱, 黄世峰, 程新. 花岗岩锯泥和大理石废石粉制备发泡陶瓷[J]. 硅酸盐通报, 2023, 42(3): 939-947.

DONG Yiran, ZHAO Chenglin, GUO Wei, JIANG Congcong, HUANG Shifeng, CHENG Xin. Preparation of Foamed Ceramics from Granite Scrap and Marble Scrap[J]. BULLETIN OF THE CHINESE CERAMIC SOCIETY, 2023, 42(3): 939-947.

参考文献

[1] VIJAYALAKSHMI M, SEKAR A S S, GANESH P G. Strength and durability properties of concrete made with granite industry waste[J]. Construction and Building Materials, 2013, 46: 1-7.
[2] SADEK H E H, ZAWRAH M F, GABER A A, et al. Utilization of granite sludge for production of cordierite ceramics by direct coagulation casting[J]. Ceramics International, 2021, 47(14): 20187-20195.
[3] HOJAMBERDIEV M, EMINOV A, XU Y. Utilization of muscovite granite waste in the manufacture of ceramic tiles[J]. Ceramics International, 2011, 37(3): 871-876.
[4] ZHANG J J, LIU B, ZHANG S. A review of glass ceramic foams prepared from solid wastes: processing, heavy-metal solidification and volatilization, applications[J]. Science of the Total Environment, 2021, 781: 146727.
[5] SILVA R V, DE BRITO J, LYE C Q, et al. The role of glass waste in the production of ceramic-based products and other applications: a review[J]. Journal of Cleaner Production, 2017, 167: 346-364.
[6] MA L, LI G Z. The preparation of red mud foam lightweight thermal insulation material[J]. Applied Mechanics and Materials, 2014, 541/542: 104-107.
[7] 周明凯, 柳剑锋, 葛雪祥, 等. 粉煤灰发泡陶瓷的制备及性能研究[J]. 硅酸盐通报, 2021, 40(2): 605-609+621.
ZHOU M K, LIU J F, GE X X, et al. Preparation and properties of foamed ceramics from fly ash[J]. Bulletin of the Chinese Ceramic Society, 2021, 40(2): 605-609+621 (in Chinese).
[8] 朱建平, 乐红志, 白荣, 等. 利用黄金尾矿制备发泡陶瓷的研究[J]. 硅酸盐通报, 2021, 40(9): 2989-2997.
ZHU J P, YUE H Z, BAI R, et al. Research on preparation of foamed ceramics from gold tailings[J]. Bulletin of the Chinese Ceramic Society, 2021, 40(9): 2989-2997 (in Chinese).
[9] 梁宗宇, 张华, 马明龙, 等. 烧成工艺制度对含钛高炉渣制备发泡陶瓷性能的影响[J]. 硅酸盐通报, 2020, 39(5): 1627-1632.
LIANG Z Y, ZHANG H, MA M L, et al. Effect of firing process system on performance of foamed ceramic prepared by titanium-bearing blast furnace slag[J]. Bulletin of the Chinese Ceramic Society, 2020, 39(5): 1627-1632 (in Chinese).
[10] ZHOU M K, GE X X, WANG H, et al. Effect of the CaO content and decomposition of calcium-containing minerals on properties and microstructure of ceramic foams from fly ash[J]. Ceramics International, 2017, 43(12): 9451-9457.
[11] XI X A, XU L F, SHUI A Z, et al. Effect of silicon carbide particle size and CaO content on foaming properties during firing and microstructure of porcelain ceramics[J]. Ceramics International, 2014, 40(8): 12931-12938.
[12] 姜葱葱, 董祎然, 黄世峰, 等. 基于原位发泡工艺的固废基发泡陶瓷研究进展[J]. 硅酸盐学报, 2022, 50(9): 2510-2526.
JIANG C C, DONG Y R, HUANG S F, et al. Research progress on solid waste-based foamed ceramics based on in situ foaming process[J]. Journal of the Chinese Ceramic Society, 2022, 50(9): 2510-2526 (in Chinese).
[13] GE X X, ZHOU M K, WANG H, et al. Effects of flux components on the properties and pore structure of ceramic foams produced from coal bottom ash[J]. Ceramics International, 2019, 45(9): 12528-12534.
[14] CHEN Z W, WANG H, JI R, et al. Reuse of mineral wool waste and recycled glass in ceramic foams[J]. Ceramics International, 2019, 45(12): 15057-15064.
[15] LI X M, SUN D, YANG Q, et al. Foaming performance of the closed-pore foamed ceramics using silicon nitride as a foaming agent and sodium tetraborate as a modifier of foaming[J]. Journal of the European Ceramic Society, 2021, 41(13): 6330-6337.
[16] WANG H B, FENG K Q, SUN Q Z. Effect of calcium carbonate on the preparation of glass ceramic foams from water-quenched titanium-bearing blast furnace slag and waste glass[J]. Advances in Applied Ceramics, 2018, 117(5): 312-318.
[17] DONG Y R, JIANG C C, ZHANG L N, et al. Waste-bearing foamed ceramic from granite scrap and red mud[J]. International Journal of Applied Ceramic Technology, 2022, 19(5): 2686-2700.
[18] NIU Y H, FAN X Y, REN D, et al. Effect of Na₂CO₃ content on thermal properties of foam-glass ceramics prepared from smelting slag[J]. Materials Chemistry and Physics, 2020, 256: 123610.
[19] 谭洪波, 吕周岭, 马保国, 等. 黄姜废渣发泡陶瓷的制备及其性能研究[J]. 硅酸盐通报, 2021, 40(2): 597-604.
TAN H B, LYU Z L, MA B G, et al. Preparation and properties of foamed ceramics from turmeric residue[J]. Bulletin of the Chinese Ceramic Society, 2021, 40(2): 597-604 (in Chinese).
[20] FANG W Q, HOU L J, LI Y. Foaming mechanism of SiC in steel slag foamed ceramics[J]. ISIJ International, 2021, 61(3): 1043-1052.

花岗岩锯泥和大理石废石粉制备发泡陶瓷

Preparation of Foamed Ceramics from Granite Scrap and Marble Scrap

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