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硅酸盐通报 ›› 2023, Vol. 42 ›› Issue (12): 4524-4531.

• 新型功能材料 • 上一篇    下一篇

C包覆Cu纳米颗粒对Na2SO4·10H2O相变纳米流体性能的影响

柳馨1, 陈凤兰1, 于鹏程1, 汪长安1,2, 铁生年1   

  1. 1.青海大学,新能源光伏产业研究中心,西宁 810016;
    2.清华大学,材料科学与工程学院,北京 100084
  • 收稿日期:2023-08-27 修订日期:2023-10-14 出版日期:2023-12-15 发布日期:2023-12-12
  • 通信作者: 铁生年,教授。E-mail:tieshengnian@163.com
  • 作者简介:柳 馨(1993—),女,讲师。主要从事相变储能材料的研究。E-mail:qhuliuxin@163.com
  • 基金资助:
    青海省自然科学基金(2021-ZJ-906)

Effects of C-Coated Cu Nanoparticles on Properties of Na2SO4·10H2O Phase Change Nanofluids

LIU Xin1, CHEN Fenglan1, YU Pengcheng1, WANG Chang’an1,2, TIE Shengnian1   

  1. 1. New Energy (Photovoltaic) Industry Research Center, Qinghai University, Xining 810016, China;
    2. School of Materials Science and Engineering, Tsinghua University, Beijing 100084, China
  • Received:2023-08-27 Revised:2023-10-14 Online:2023-12-15 Published:2023-12-12

摘要: 本文探讨了不同温度条件下不同质量分数(1.0%、1.5%、2.0%、3.5%和5.0%)C包覆Cu纳米颗粒对芒硝基相变纳米流体流变行为的影响,以及在不同剪切速率(39.91~140 s-1)及不同温度(35~50 ℃)下测量C包覆Cu纳米颗粒相变纳米流体的黏度。结果表明,通过水热法成功制备出C包覆Cu纳米颗粒。在35 ℃下C包覆Cu纳米颗粒质量分数为1.0%的纳米流体样品和35、40 ℃下质量分数为1.5%的样品表现出牛顿流体行为,而在其他温度下则表现出非牛顿流体行为。当C包覆Cu纳米颗粒质量分数增加至2.0%、3.5%和5.0%时,样品表现出非牛顿流体行为,符合幂律模型。同时研究芒硝复合相变储能材料的热性能,复合相变纳米流体具有较高的导热系数和较低的过冷度,且具有较好的循环稳定性。

关键词: 相变储能材料, C包覆Cu纳米颗粒, 芒硝基相变纳米流体, 黏度, 潜热

Abstract: The effects of C-coated Cu nanoparticles on the rheological behavior of mirabilite phase change nanofluids with different mass fraction (1.0%, 1.5%, 2.0%, 3.5%, and 5.0%) at different temperatures were investigated. The viscosity of C-coated Cu nanoparticles phase change nanofluids was investigated at different shear rates (39.91~140 s-1) and different temperatures (35~50 ℃). The results show that the hydrothermal method successfully prepares C-coated Cu nanoparticles. Nanofluid samples with mass fraction of 1.0% C-coated Cu nanoparticles at 35 ℃ and 1.5% C-coated Cu nanoparticles at 35, 40 ℃ exhibit Newtonian fluid behavior, but nanofluid samples exhibit non-Newtonian fluid behavior at other temperatures. When the mass fraction of C-coated Cu nanoparticles increases to 2.0%, 3.5% and 5.0%, the samples exhibit non-Newtonian fluid behavior, which conforms to the power law model. At the same time, the thermal properties of mirabilite composite phase change energy storage materials were studied. The composite phase change nanofluid has higher thermal conductivity, lower undercooling, and better cycle stability.

Key words: phase change energy storage material, C-coated Cu nanoparticle, mirabilite phase change nanofluid, viscosity, latent heat

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