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硅酸盐通报 ›› 2022, Vol. 41 ›› Issue (2): 545-552.

• 胶凝材料 • 上一篇    下一篇

热处理时间对磷石膏基复合胶凝材料劈裂抗拉性能的影响

安红芳1, 付汝松1, 陆跃贤1, 孔德文1, 罗双2, 王琳1, 吕方涛1   

  1. 1.贵州大学土木工程学院,贵阳 550025;
    2.湖南大学土木工程学院,长沙 410082
  • 收稿日期:2021-11-01 修回日期:2021-12-19 出版日期:2022-02-15 发布日期:2022-03-01
  • 通讯作者: 孔德文,博士,教授。E-mail:kongdewen0608@126.com
  • 作者简介:安红芳(1996—),女,硕士研究生。主要从事土木工程材料的研究。E-mail:3222423473@qq.com
  • 基金资助:
    国家自然科学基金(51968009,52168027);贵州省科技计划项目(黔科合[2018]2816,[2020]1Y244)

Effect of Heat Treatment Time on Splitting Tensile Properties of Phosphogypsum-Based Composite Cementitious Material

AN Hongfang1, FU Rusong1, LU Yuexian1, KONG Dewen1, LUO Shuang2, WANG Lin1, LYU Fangtao1   

  1. 1. School of Civil Engineering, Guizhou University, Guiyang 550025, China;
    2. School of Civil Engineering, Hunan University, Changsha 410082, China
  • Received:2021-11-01 Revised:2021-12-19 Online:2022-02-15 Published:2022-03-01

摘要: 通过恒温烘箱对磷石膏(PG)进行热处理,复掺灰钙粉、普通硅酸盐水泥、缓凝剂及减水剂制备磷石膏基复合胶凝材料(PGCM),研究热处理时间对PGCM的劈裂抗拉强度、轴心抗压强度与劈裂抗拉强度折减系数、破坏形态、劈裂抗拉应力-应变曲线的影响规律。结果表明:PGCM的劈裂抗拉强度随热处理时间的延长先增加后减小,当热处理时间为90 min时,PGCM的劈裂抗拉强度最大达到1.68 MPa;轴心抗压强度与劈裂抗拉强度折减系数随热处理时间的延长几乎都减小,PGCM的劈裂抗拉强度为轴心抗压强度的4.2%~9.2%;PGCM的破坏形态主要有中心开裂破坏、局部破坏和次要裂缝破坏;PGCM的劈裂抗拉应力-应变曲线先逐渐上升后呈直线下降。结合试验数据,得到PGCM的轴心抗压强度与劈裂抗拉强度的换算关系以及劈裂抗拉应力-应变上升段曲线方程,拟合结果与试验数据较吻合。

关键词: 热处理时间, 磷石膏, 复合胶凝材料, 劈裂抗拉强度, 破坏形态, 应力-应变曲线, 资源利用

Abstract: The phosphogypsum (PG) was heat-treated in an oven with a constant temperature, and the phosphogypsum-based composite cementitious material (PGCM) was prepared by adding lime calcium powder, normal Portland cement, retarder and water reducing agent. The effects of heat treatment time on the splitting tensile strength of PGCM, the reduction coefficient of axial compressive strength and splitting tensile strength, the failure morphology, and the splitting tensile stress-strain curves were studied. The results show that the splitting tensile strength increases first and then decreases with the extension of heat treatment time. When the heat treatment time is 90 min, the splitting tensile strength reaches the maximum 1.68 MPa. The reduction coefficients of axial compressive strength and splitting tensile strength almost reduce with the extension of heat treatment time. The splitting tensile strength is 4.2% to 9.2% of axial compressive strength. The failure morphology of PGCM mainly including central cracking failure, local failure and minor crack failure. The splitting tensile stress-strain curves of PGCM gradually rise first and then decrease linearly. Combined with the test data, the conversion relationship between the axial compressive strength and splitting tensile strength of PGCM, and the equation of splitting tensile stress-strain rising section curves are obtained. The fitting results are in good agreement with test data.

Key words: heat treatment time, phosphogypsum, composite cementitious material, splitting tensile strength, failure morphology, stress-strain curve, resource utilization

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