水化热调控剂与氧化镁复掺对混凝土抗裂行为的影响

硅酸盐通报 ›› 2022, Vol. 41 ›› Issue (12): 4273-4281.

所属专题：水泥混凝土

水化热调控剂与氧化镁复掺对混凝土抗裂行为的影响

程福星¹, 张珍杰¹, 周月霞¹, 辜振睿², 向飞², 王海龙², 纪宪坤²

1.武汉源锦建材科技有限公司,武汉 430083;
2.武汉三源特种建材有限责任公司,武汉 430083

收稿日期:2022-06-14 修订日期:2022-08-23 出版日期:2022-12-15 发布日期:2023-01-11
作者简介:程福星(1988—),男,工程师。主要从事新型建筑材料的研究。E-mail:yycfx0714@163.com
基金资助:
2021年度湖北省建设科技计划(2021-55)

Effect of Hydration Heat Regulator and Magnesium Oxide Compounding on Crack Resistance Behavior of Concrete

CHENG Fuxing¹, ZHANG Zhenjie¹, ZHOU Yuexia¹, GU Zhenrui², XIANG Fei², WANG Hailong², JI Xiankun²

1. Wuhan Ujoin Building Material Technology Co. Ltd., Wuhan 430083, China;
2. Wuhan Sanyuan Special Building Material Co. Ltd., Wuhan 430083, China

Received:2022-06-14 Revised:2022-08-23 Online:2022-12-15 Published:2023-01-11

摘要/Abstract

摘要： 为了研究氧化镁膨胀剂与水化热调控剂复掺对混凝土抗裂性能的影响,探讨水化热调控剂的作用机理,开展了单掺氧化镁及水化热调控剂与氧化镁复掺对混凝土水化热、绝热温升、限制膨胀率、体积变形、自收缩、弹性模量及微观结构的影响研究。结果表明:水化热调控剂可显著改变水泥水化放热历程,净浆抑温率可达31.2%,随入模温度升高,抑温效果增强;水化热调控剂可激发氧化镁的水化,促进膨胀能的释放,随养护温度提升,作用效果更显著;水化热调控剂可改变混凝土温升历程,特别是降低混凝土早期水化热释放速率;水化热调控剂与氧化镁复掺可降低混凝土自收缩,当水化热调控剂掺量为0.2%和0.4%(质量分数)时,混凝土收缩值分别减少了84 με和54 με;水化热调控剂会导致混凝土早龄期弹性模量降低,但对长龄期弹性模量影响不大;水化热调控剂对水泥水化历程、水化产物生成及微观结构密实程度的改变是提高混凝土抗裂性能的根本原因。

关键词: 水化热调控剂, 氧化镁, 抗裂, 绝热温升, 弹性模量, 自收缩

Abstract: In order to study the effect of magnesium oxide expansion agent and hydration heat regulator compounding on the crack resistance of concrete and explore the mechanism of hydration heat regulator, diabetic temperature rise, limited expansion rate, volume deformation, self-shrinkage, elastic modulus of the concrete mixed with magnesium oxide and the concrete mixed with magnesium oxide and hydration heat regulator were tested, and the microstructure was investigated. The results show that the hydration heat regulator can significantly change the cement hydration exothermic process, the temperature suppression rate of the slurry reaches 31.2%, and the temperature suppression effect is enhanced with the increase of the mold temperature. The hydration heat regulator can stimulate the hydration of magnesium oxide and promote the release of expansion energy, and the effect is more obvious with the increase of curing temperature. The hydration heat regulator can change the temperature rise history of concrete, especially reduce the early hydration heat release rate. The combination of hydration heat regulator and magnesium oxide can reduce the self-shrinkage of concrete. When the content of hydration heat regulator is 0.2% and 0.4% (mass fraction), the shrinkage value is reduced by 84 με and 54 με, respectively. The hydration heat regulator will reduce the elastic modulus of concrete in the early age, but it has little effect on the elastic modulus in the long age. The change of cement hydration process, hydration product generation and microstructure compactness caused by hydration heat regulator is the fundamental reason for improving the crack resistance of concrete.

Key words: hydration heat regulator, magnesium oxide, crack resistance, adiabatic temperature rise, elastic modulus, self-shrinkage

中图分类号:

TQ172.46

程福星, 张珍杰, 周月霞, 辜振睿, 向飞, 王海龙, 纪宪坤. 水化热调控剂与氧化镁复掺对混凝土抗裂行为的影响[J]. 硅酸盐通报, 2022, 41(12): 4273-4281.

CHENG Fuxing, ZHANG Zhenjie, ZHOU Yuexia, GU Zhenrui, XIANG Fei, WANG Hailong, JI Xiankun. Effect of Hydration Heat Regulator and Magnesium Oxide Compounding on Crack Resistance Behavior of Concrete[J]. BULLETIN OF THE CHINESE CERAMIC SOCIETY, 2022, 41(12): 4273-4281.

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水化热调控剂与氧化镁复掺对混凝土抗裂行为的影响

Effect of Hydration Heat Regulator and Magnesium Oxide Compounding on Crack Resistance Behavior of Concrete

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