粉煤灰基沸石处理氮磷废水的研究进展

摘要/Abstract

摘要： 近年来,粉煤灰因其价格低廉、产量高,且与沸石结构相似,常被用来作为合成沸石的原材料。在水处理方面,粉煤灰基沸石处理氮磷废水的研究颇受广大学者青睐。本文简介了粉煤灰的理化性质及利用现状,概述了粉煤灰基沸石因其独特的内部结构所具有的三个特性:离子交换性、吸附性、催化性。介绍了粉煤灰基沸石除氮、磷的机理,重点论述了粉煤灰基沸石对低、中、高不同浓度的氨氮废水、含磷废水、氮磷共存废水处理的进展情况。最后分析了该领域目前存在的问题及未来发展趋势。

关键词: 粉煤灰, 沸石, 氨氮废水, 含磷废水, 特性

Abstract: In recent years, fly ash is often used as a raw material for synthetic zeolite due to its low price, high output and similar structure to zeolite. In terms of water treatment, the research on the treatment of nitrogen and phosphorus wastewater with fly ash-based zeolite is quite popular among scholars. The physical and chemical properties and utilization status of fly ash are introduced. Ion exchange, adsorption and catalysis are the main characteristics of fly ash-based zeolite, due to its unique internal structure. The mechanism of nitrogen and phosphorus removal by fly ash-based zeolite is introduced. The focus is on the progress of the treatment of low, medium and high concentrations of ammonia nitrogen wastewater, phosphorus wastewater and nitrogen-phosphorus coexisting wastewater with fly ash-based zeolite. Finally, the current problems in this field and future development trends are analyzed.

Key words: fly ash, zeolite, ammonia nitrogen wastewater, phosphorus wastewater, characteristic

中图分类号:

X773

崔家新, 王连勇, 张坤, 孙延文, 韩建丽. 粉煤灰基沸石处理氮磷废水的研究进展[J]. 硅酸盐通报, 2021, 40(8): 2622-2630.

CUI Jiaxin, WANG Lianyong, ZHANG Kun, SUN Yanwen, HAN Jianli. Research Progress on Treatment of Nitrogen and Phosphorus Wastewater with Fly Ash-Based Zeolite[J]. BULLETIN OF THE CHINESE CERAMIC SOCIETY, 2021, 40(8): 2622-2630.

参考文献

[1] 张祥成,孟永彪.浅析中国粉煤灰的综合利用现状[J].无机盐工业,2020,52(2):1-5.
ZHANG X C, MENG Y B. Brief analysis on present situation of comprehensive utilization of fly ash in China[J]. Inorganic Chemicals Industry, 2020, 52(2): 1-5 (in Chinese).
[2] 王建新,李晶,赵仕宝,等.中国粉煤灰的资源化利用研究进展与前景[J].硅酸盐通报,2018,37(12):3833-3841.
WANG J X, LI J, ZHAO S B, et al. Research progress and prospect of resource utilization of fly ash in China[J]. Bulletin of the Chinese Ceramic Society, 2018, 37(12): 3833-3841 (in Chinese).
[3] 曾青云,薛丽燕,曾繁钢,等.氨氮废水处理技术的研究现状[J].有色金属科学与工程,2018,9(4):83-88.
ZENG Q Y, XUE L Y, ZENG F G, et al. Research progress of treatment technology for ammonia nitrogen wastewater[J]. Nonferrous Metals Science and Engineering, 2018, 9(4): 83-88 (in Chinese).
[4] 鲁秀国,杨凌焱,黄林长,等.非粮生物质吸附剂吸附水中氨氮的研究进展[J].华东交通大学学报,2018,35(1):90-96.
LU X G, YANG L Y, HUANG L C, et al. Research progress of ammonia-nitrogen adsorption by use of non-food biomass[J]. Journal of East China Jiaotong University, 2018, 35(1): 90-96 (in Chinese).
[5] DENG X, QI L Q, ZHANG Y J. Experimental study on adsorption of hexavalent chromium with microwave-assisted alkali modified fly ash[J]. Water, Air & Soil Pollution, 2018, 229(1): 1-6.
[6] 阙耀华,郭俊温,张雪峰,等.粉煤灰沸石阳离子交换容量的测量研究[J].内蒙古科技大学学报,2010,29(4):374-376.
QUE Y H, GUO J W, ZHANG X F, et al. Study on the determination of fly ash zeolite cation exchange capacity[J]. Journal of Inner Mongolia University of Science and Technology, 2010, 29(4): 374-376 (in Chinese).
[7] PARAMITHA T, WULANDARI W, RIZKIANA J, et al. Performance evaluation of coal fly ash based zeolite A for heavy metal ions adsorption of wastewater[J]. IOP Conference Series: Materials Science and Engineering, 2019, 543: 012095.
[8] BOYCHEVA S V, ZGUREVA D M. Surface studies of fly ash zeolites via adsorption/desorption isotherms[J]. Bulgarian Chemical Communications, 2016, Special Issue A: 101-107.
[9] PÉDROLO D R S, DE MENEZES Q L K, DE SOUZA G, et al. Synthesis of zeolites from Brazilian coal ash and its application in SO₂ adsorption[J]. Journal of Environmental Chemical Engineering, 2017, 5(5): 4788-4794.
[10] 马子然,王宝冬,路光杰,等.粉煤灰基SAPO-34分子筛脱硝催化剂的合成及其脱硝性能[J].化工进展,2020,39(10):4051-4060.
MA Z R, WANG B D, LU G J, et al. Preparation and performance of SAPO-34 based SCR catalyst derived from fly ash[J]. Chemical Industry and Engineering Progress, 2020, 39(10): 4051-4060 (in Chinese).
[11] 李建,石应杰,付晓恒,等.粉煤灰基介孔ZSM-5的孔径调控以及催化油烟中戊醛[J].中南大学学报(自然科学版),2020,51(5):1174-1188.
LI J, SHI Y J, FU X H, et al. Aperture adjustment of mesoporous ZSM-5 based on fly ash for catalysis of pentanal in cooking fumes[J]. Journal of Central South University (Science and Technology), 2020, 51(5): 1174-1188 (in Chinese).
[12] WEI D, ZHANG K Y, NGO H H, et al. Nitrogen removal via nitrite in a partial nitrification sequencing batch biofilm reactor treating high strength ammonia wastewater and its greenhouse gas emission[J]. Bioresource Technology, 2017, 230: 49-55.
[13] XIAO J, TANG J H. Nitrogen removal with nitrification and denitrification via nitrite[J]. Advanced Materials Research, 2014, 908: 175-178.
[14] CHEN W, DAI X, CAO D, et al. Performance and microbial ecology of a nitritation sequencing batch reactor treating high-strength ammonia wastewater[J]. Scientific Reports, 2016, 6: 35693.
[15] 王爱民,白妮,王金玺,等.粉煤灰合成单一SOD型沸石及其氨氮吸附性能研究[J].硅酸盐通报,2015,34(4):1111-1115.
WANG A M, BAI N, WANG J X, et al. Study on adsorption of ammonia nitrogen wastewater using single-phase SOD zeolite synthesized from fly ash[J]. Bulletin of the Chinese Ceramic Society, 2015, 34(4): 1111-1115 (in Chinese).
[16] 李晓,刘碧武,郭军.折点加氯法去除生活污水氨氮的试验研究[J].能源环境保护,2019,33(5):32-35.
LI X, LIU B W, GUO J. Experimental study on ammonia removal from domestic sewage by breakpoint chlorination[J]. Energy Environmental Protection, 2019, 33(5): 32-35 (in Chinese).
[17] TANG J W, LI M, ZHANG Y F. Performance of two-stage A/O process on high-strength ammonia nitrogen wastewater[J]. IOP Conference Series: Materials Science and Engineering, 2018, 452: 022106.
[18] SAN-MARTÍN M I, MATEOS R, ESCAPA A, et al. Understanding nitrogen recovery from wastewater with a high nitrogen concentration using microbial electrolysis cells[J]. Journal of Environmental Science and Health, Part A, 2019, 54(5): 472-477.
[19] GUEST R K, SMITH D W. Isolation and screening of fungi to determine potential for ammonia nitrogen treatment in wastewater[J]. Journal of Environmental Engineering and Science, 2007, 6(2): 209-217.
[20] LIU W D, HE L C, WANG M Y, et al. Effective removal of ammonia from wastewater using hollow fiber renewal liquid membrane[J]. Asia-Pacific Journal of Chemical Engineering, 2018, 13(5): e2245.
[21] 张健,万东锦,朱云云,等.两种ZSM-5沸石分子筛吸附水中氨氮的研究[J].环境科学与技术,2011,34(8):104-108.
ZHANG J, WAN D J, ZHU Y Y, et al. Adsorption of NH⁺₄-N from aqueous solution by two kinds of ZSM-5 molecular sieve[J]. Environmental Science & Technology, 2011, 34(8): 104-108 (in Chinese).
[22] 韩杨.粉煤灰副产物合成4A分子筛及对氨氮废水的吸附研究[D].长春:吉林建筑大学,2018.
HAN Y. Synthesis of 4A zeolite from fly ash byproducts and its adsorption of ammonia-nitrogen wastewater[D]. Changchun: Jilin Jianzhu University, 2018 (in Chinese).
[23] 何宏福,李亚光.粉煤灰合成Na-P1型沸石对氨氮的吸附[J].净水技术,2018,37(s2):79-85+117.
HE H F, LI Y G. Adsorption of ammonia nitrogen by Na-P1 zeolite synthesized from fly ash[J]. Water Purification Technology, 2018, 37(s2): 79-85+117 (in Chinese).
[24] CARDOSO A M, HORN M B, FERRET L S, et al. Integrated synthesis of zeolites 4A and Na-P1 using coal fly ash for application in the formulation of detergents and swine wastewater treatment[J]. Journal of Hazardous Materials, 2015, 287: 69-77.
[25] TEMEREV V L, VEDYAGIN A A, IOST K N, et al. Effect of silver addition on the adsorption properties of Y zeolite[J]. Materials Science Forum, 2020, 998: 108-113.
[26] 王璐,王国栋,李现龙,等.粉煤灰水热合成Y型沸石及其表征[J].环境工程学报,2018,12(2):618-624.
WANG L, WANG G D, LI X L, et al. Synthesis and characterization of Y-type zeolite from coal fly ash by hydrothermal method[J]. Chinese Journal of Environmental Engineering, 2018, 12(2): 618-624 (in Chinese).
[27] 滕庭庭,卢新卫.以煤矸石为原料合成Y型沸石及其吸附性能的探究[J].合成化学,2017,25(9):763-768.
TENG T T, LU X W. Synthesis and adsorption performance of mesoporous zeolite-Y[J]. Chinese Journal of Synthetic Chemistry, 2017, 25(9): 763-768 (in Chinese).
[28] 邱素芬,王源,蔡觅,等.粉煤灰及其制备沸石对高浓度氨氮的去除比较[J].化工环保,2015,35(6):583-587.
QIU S F, WANG Y, CAI M, et al. Comparison of high-concentration ammonia nitrogen removal effects between fly ash and zeolite from fly ash[J]. Environmental Protection of Chemical Industry, 2015, 35(6): 583-587 (in Chinese).
[29] 李晓光,赵颖,康得军,等.粉煤灰基X型沸石分子筛的合成制备及其去除氨性能研究[J].硅酸盐通报,2018,37(11):3663-3668.
LI X G, ZHAO Y, KANG D J, et al. Synthesis of pure X zeolite sieve from coal fly ash for ammonium removal[J]. Bulletin of the Chinese Ceramic Society, 2018, 37(11): 3663-3668 (in Chinese).
[30] 闫玉兵.改性粉煤灰对含磷废水的处理研究[J].矿产综合利用,2020(5):34-44.
YAN Y B. Research on modified fly ash treats for phosphorus wastewater[J]. Multipurpose Utilization of Mineral Resources, 2020(5): 34-44 (in Chinese).
[31] ZALETOVA N. Elimination of polluting nutrients from wastewater[J]. MATEC Web of Conferences, 2018, 251: 03053.
[32] HUANG L, FANG H W, HE G J, et al. Phosphorus adsorption on natural sediments with different pH incorporating surface morphology characterization[J]. Environmental Science and Pollution Research, 2016, 23(18): 18883-18891.
[33] YANG M G, SHI J, XU Z W, et al. Phosphorus removal and recovery from fosfomycin pharmaceutical wastewater by the induced crystallization process[J]. Journal of Environmental Management, 2019, 231: 207-212.
[34] BENGTSSON S, DE BLOIS M, WILÉN B M, et al. A comparison of aerobic granular sludge with conventional and compact biological treatment technologies[J]. Environmental Technology, 2019, 40(21): 2769-2778.
[35] 柯瑶瑶,冀晓东,李亚伟,等.合成条件对粉煤灰合成沸石除磷特性的影响[J].环境工程学报,2016,10(3):1492-1499.
KE Y Y, JI X D, LI Y W, et al. Effect of synthetic conditions on characters of phosphorus removal using synthetic zeolite from fly ash[J]. Chinese Journal of Environmental Engineering, 2016, 10(3): 1492-1499 (in Chinese).
[36] XIE J, LAI L, LIN L D, et al. Phosphate removal from water by a novel zeolite/lanthanum hydroxide hybrid material prepared from coal fly ash[J]. Journal of Environmental Science and Health, Part A, 2015, 50(12): 1298-1305.
[37] WANG Z, FAN Y, LI Y W, et al. Synthesis of zeolite/hydrous lanthanum oxide composite from coal fly ash for efficient phosphate removal from lake water[J]. Microporous and Mesoporous Materials, 2016, 222: 226-234.
[38] GOSCIANSKA J, PTASZKOWSKA-KONIARZ M, FRANKOWSKI M, et al. Removal of phosphate from water by lanthanum-modified zeolites obtained from fly ash[J]. Journal of Colloid and Interface Science, 2018, 513: 72-81.
[39] 王宇,谌建宇,李小明,等.粉煤灰沸石在水处理中的应用及研究进展[J].工业水处理,2011,31(12):18-21+30.
WANG Y, CHEN J Y, LI X M, et al. Application of zeolitized fly ash to wastewater treatment and its research progress[J]. Industrial Water Treatment, 2011, 31(12): 18-21+30 (in Chinese).
[40] 戴昊,彭想,张天志,等.粉煤灰合成沸石在水处理中的应用进展[J].广州化工,2020,48(15):1-3+6.
DAI H, PENG X, ZHANG T Z, et al. Research and application progress of zeolite from fly ash in water treatment[J]. Guangzhou Chemical Industry, 2020, 48(15): 1-3+6 (in Chinese).
[41] GONG W J, LI Y, LUO L N, et al. Application of struvite-MAP crystallization reactor for treating cattle manure anaerobic digested slurry: nitrogen and phosphorus recovery and crystal fertilizer efficiency in plant trials[J]. International Journal of Environmental Research and Public Health, 2018, 15(7): E1397.
[42] WANG J, XIA L, CHEN J Y, et al. Synergistic simultaneous nitrification-endogenous denitrification and EBPR for advanced nitrogen and phosphorus removal in constructed wetlands[J]. Chemical Engineering Journal, 2020: 127605.
[43] HE Y H, LIN H, DONG Y B, et al. Simultaneous removal of phosphate and ammonium using salt-thermal-activated and lanthanum-doped zeolite: fixed-bed column and mechanism study[J]. Desalination and Water Treatment, 2016, 57(56): 27279-27293.
[44] GUAYA D, VALDERRAMA C, FARRAN A, et al. Simultaneous nutrients (N, P) removal by using a hybrid inorganic sorbent impregnated with hydrated manganese oxide[J]. Journal of Environmental Chemical Engineering, 2017, 5(2): 1516-1525.
[45] MURAYAMA N, YOSHIDA S, TAKAMI Y, et al. Simultaneous removal of NH⁺₄ and PO^3-₄ in aqueous solution and its mechanism by using zeolite synthesized from coal fly ash[J]. Separation Science and Technology, 2003, 38(1): 113-130.
[46] WU D Y, HU Z B, WANG X Z, et al. Use of zeolitized coal fly ash in the simultaneous removal of ammonium and phosphate from aqueous solution[J]. Frontiers of Environmental Science & Engineering in China, 2007, 1(2): 213-220.
[47] 陈晓燕.粉煤灰纳米沸石复合颗粒功能化设计及其污水氮磷去除初步研究[D].杭州:浙江大学,2011.
CHEN X Y. Synthesis of fly ash-derived nano-zeolite material and its application in the simultaneous removal of ammonium and phosphate in wastewater[D]. Hangzhou: Zhejiang University, 2011 (in Chinese).
[48] HE H F, XU S Y, HAN R Q, et al. Nutrient sequestration from wastewater by using zeolite Na-P1 synthesized from coal fly ash[J]. Environmental Technology, 2017, 38(8): 1022-1029.
[49] LI Z, GU G Z, JI S H. Performance of nitrogen and phosphorus removal in petrochemical wastewater by zeolited fly ash[J]. IOP Conference Series: Earth and Environmental Science, 2018, 153: 022020.