氧化铁红颜料对白水泥基3D打印材料流变及可打印性能的影响

硅酸盐通报 ›› 2021, Vol. 40 ›› Issue (6): 1863-1869.

• 3D 打印水泥基材料 • 上一篇下一篇

氧化铁红颜料对白水泥基3D打印材料流变及可打印性能的影响

徐嘉宾, 金源, 赵智慧, 陈明旭, 芦令超, 程新

济南大学,山东省建筑材料制备与测试技术重点实验室,济南 250022

收稿日期:2020-03-31 修回日期:2021-05-19 出版日期:2021-06-15 发布日期:2021-07-08
通讯作者: 芦令超,博士,教授。E-mail:lingchao_lu@163.com
作者简介:徐嘉宾(1996—),男,硕士研究生。主要从事建筑材料3D打印的研究。E-mail:xujiabin0307@163.com
基金资助:
国家自然科学基金(52072147)

Effect of Iron Oxide Red Pigment on Rheological Property and Printability of 3D Printed White Portland Cement-Based Materials

XU Jiabin, JIN Yuan, ZHAO Zhihui, CHEN Mingxu, LU Lingchao, CHENG Xin

Shandong Provincial Key Laboratory of Preparation and Measurement of Building Materials, University of Jinan, Jinan 250022, China

Received:2020-03-31 Revised:2021-05-19 Online:2021-06-15 Published:2021-07-08

摘要/Abstract

摘要： 目前3D打印技术在建筑材料领域的研究主要集中在大型结构的建立和力学性能上,而对异形装饰及景观构件的研究还很少。本文采用白色硅酸盐水泥作为胶凝材料,并引入亚微米级粒度氧化铁红颜料来制备彩色水泥基3D打印材料,并研究氧化铁红颜料对白水泥基3D打印材料流变性能、可打印性能及力学性能的影响。结果表明,低掺量的颜料可以降低白水泥基3D打印浆体的动态流变性能,改善浆体的挤出性能。此外,颜料的掺入能够明显提高浆体的静态屈服应力,使得结构变形率从11.38%降低至4.03%。同时,颜料的掺入能够改善浆体的早期力学性能,其3 d抗压和抗折强度最高可达到48.56 MPa和5.07 MPa。总的来说,氧化铁红颜料可调控白水泥基3D打印材料流变性能和优化材料微观结构。

关键词: 3D打印, 白水泥, 颜料, 流变性能, 可打印性能, 力学性能

Abstract: Recently, most of the research on 3D printing technology in the field of architectural decoration focuses on the rheological property of materials and the mechanical properties of materials, while the study of its decorative effect is still few. In this paper, iron oxide red pigment was introduced into 3D printed white Portland cement-based materials for dyeing. The effects of iron oxide red pigment on the rheological property, printability, and mechanical property on 3D printed white Portland cement-based materials were studied. The experimental results show that the low pigment content can reduce the dynamic rheological property of the 3D printed white Portland cement-based materials and improve the extrusion performance of the paste, while the high pigment content is not conducive to the extrusion of the paste. Besides, the addition of iron oxide red pigment can significantly increase the static yield stress of the paste and reduce the structural deformation rate from 11.38% to 4.03%. At the same time, the addition of iron oxide red pigment can improve the early mechanical properties of the paste, and the 3 d maximum compressive strength and flexural strength of the paste can reach 48.56 MPa and 5.07 MPa, respectively. In general, the introduction of iron oxide red pigment can improve the deformation rate of paste through the regulation of rheological properties.

Key words: 3D printing, white Portland cement, pigment, rheological property, printability, mechanical property

中图分类号:

TQ172

徐嘉宾, 金源, 赵智慧, 陈明旭, 芦令超, 程新. 氧化铁红颜料对白水泥基3D打印材料流变及可打印性能的影响[J]. 硅酸盐通报, 2021, 40(6): 1863-1869.

XU Jiabin, JIN Yuan, ZHAO Zhihui, CHEN Mingxu, LU Lingchao, CHENG Xin. Effect of Iron Oxide Red Pigment on Rheological Property and Printability of 3D Printed White Portland Cement-Based Materials[J]. BULLETIN OF THE CHINESE CERAMIC SOCIETY, 2021, 40(6): 1863-1869.

参考文献

[1] BROWNE M P, REDONDO E, PUMERA M. 3D printing for electrochemical energy applications[J]. Chemical Reviews, 2020, 120(5): 2783-2810.
[2] HE F, CHENG J S, DENG D W, et al. Structure of Bi₂O₃-ZnO-B₂O₃ system low-melting sealing glass[J]. Journal of Central South University of Technology, 2010, 17(2): 257-262.
[3] KHAN M A. Mix suitable for concrete 3D printing: a review[J]. Materials Today: Proceedings, 2020, 32: 831-837.
[4] PANDA B, UNLUER C, TAN M J. Extrusion and rheology characterization of geopolymer nanocomposites used in 3D printing[J]. Composites Part B: Engineering, 2019, 176: 107290.
[5] INGAGLIO J, FOX J, NAITO C J, et al. Material characteristics of binder jet 3D printed hydrated CSA cement with the addition of fine aggregates[J]. Construction and Building Materials, 2019, 206: 494-503.
[6] ZHANG Y, ZHANG Y S, SHE W, et al. Rheological and harden properties of the high-thixotropy 3D printing concrete[J]. Construction and Building Materials, 2019, 201: 278-285.
[7] CHEN M X, YANG L, ZHENG Y, et al. Yield stress and thixotropy control of 3D-printed calcium sulfoaluminate cement composites with metakaolin related to structural build-up[J]. Construction and Building Materials, 2020, 252: 119090.
[8] KETEL S, FALZONE G, WANG B, et al. A printability index for linking slurry rheology to the geometrical attributes of 3D-printed components[J]. Cement and Concrete Composites, 2019, 101: 32-43.
[9] TAY Y W D, QIAN Y, TAN M J. Printability region for 3D concrete printing using slump and slump flow test[J]. Composites Part B: Engineering, 2019, 174: 106968.
[10] CHRIST S, SCHNABEL M, VORNDRAN E, et al. Fiber reinforcement during 3D printing[J]. Materials Letters, 2015, 139: 165-168.
[11] ARUNOTHAYAN A R, NEMATOLLAHI B, RANADE R, et al. Fiber orientation effects on ultra-high performance concrete formed by 3D printing[J]. Cement and Concrete Research, 2021, 143: 106384.
[12] 郅真真.高强石膏3D打印材料流变特性与结构成型调控研究[D].武汉:武汉理工大学,2018.
ZHI Z Z. Research of rheology characteristic and structure formation of 3D priting high-strength gypsum materials[D]. Wuhan: Wuhan University of Technology, 2018 (in Chinese).
[13] XIAO J Z, ZOU S, YU Y, et al. 3D recycled mortar printing: system development, process design, material properties and on-site printing[J]. Journal of Building Engineering, 2020, 32: 101779.
[14] 杨林,焦媛,况栋梁,等.颜料对聚合物水泥砂浆性能影响的实验研究[J].科学技术与工程,2018,18(6):321-325.
YANG L, JIAO Y, KUANG D L, et al. Experimental investigation on the effect of pigments on properties of polymer cement mortar[J]. Science Technology and Engineering, 2018, 18(6): 321-325 (in Chinese).
[15] 郭文星.彩色清水自密实混凝土性能与工程应用研究[D].北京:北京建筑大学,2020.
GUO W X. Research on performance and engineering application of colored architectural self-compacting concrete[D]. Beijing: Beijing University of Civil Engineering and Architecture, 2020 (in Chinese).
[16] 孙培钊,邢振贤,耿世博.颜料品种与掺量对彩色砂浆性能的影响[J].四川建材,2020,46(4):14-15+21.
SUN P Z, XING Z X, GENG S B. Influence of pigment variety and content on performance of colored mortar[J]. Sichuan Building Materials, 2020, 46(4): 14-15+21 (in Chinese).

氧化铁红颜料对白水泥基3D打印材料流变及可打印性能的影响

Effect of Iron Oxide Red Pigment on Rheological Property and Printability of 3D Printed White Portland Cement-Based Materials

PDF (PC)

可视化

摘要/Abstract

引用本文

使用本文

参考文献

相关文章 15

编辑推荐

Metrics

本文评价

[1]	焦敏. 氧化石墨烯对新拌水泥浆体流变性的影响[J]. 硅酸盐通报, 2021, 40(7): 2159-2164.
[2]	姚苏琴, 查文华, 刘新权, 季圣星, 何昌春, 余跃. 萍乡废弃煤矸石理化特性及热活化性能研究[J]. 硅酸盐通报, 2021, 40(7): 2280-2287.
[3]	范小春, 张雯静, 梁天福, 陈凯风. 回收轮胎钢纤维再生骨料混凝土基本力学性能试验研究[J]. 硅酸盐通报, 2021, 40(7): 2331-2340.
[4]	黄开林, 李书进, 臧旭航. 不同类型再生细骨料对保温混凝土力学性能的影响[J]. 硅酸盐通报, 2021, 40(7): 2341-2347.
[5]	阿拉腾沙嘎, 陈冠宏, 陈星. 磁场作用下冷冻铸造法制备仿生材料研究进展[J]. 硅酸盐通报, 2021, 40(7): 2348-2359.
[6]	李宝玉. 石墨烯/聚乙烯复合改性沥青胶结料的流变性能研究[J]. 硅酸盐通报, 2021, 40(7): 2461-2468.
[7]	张超, 邓智聪, 马蕾, 刘超, 陈宇宁, 汪智斌, 贾子健, 王香港, 贾鲁涛, 陈春, 孙正明, 张亚梅. 3D打印混凝土研究进展及其应用[J]. 硅酸盐通报, 2021, 40(6): 1769-1795.
[8]	张翼, 朱艳梅, 任强, 蒋正武. 3D打印建筑技术及其水泥基材料研究进展评述[J]. 硅酸盐通报, 2021, 40(6): 1796-1807.
[9]	刘俊力, 任杰, Jonathan Phuong Tran. 3D打印混凝土技术在澳大利亚的最近研究进展[J]. 硅酸盐通报, 2021, 40(6): 1808-1813.
[10]	王里, 李丹利, 叶珂含, 关景元, 冯舵. 水泥基复合材料3D可打印性的量化、优化及标准化[J]. 硅酸盐通报, 2021, 40(6): 1814-1820.
[11]	焦泽坤, 王栋民, 王启宝, 黄天勇, 王吉祥, 李林坤. 3D打印混凝土材料可打印性的影响因素与测试方法[J]. 硅酸盐通报, 2021, 40(6): 1821-1831.
[12]	孙凯利, 吴翔强, 蔺喜强, 李国友, 李新健, 孙志鹏. 混凝土3D打印材料及3D打印模板技术应用进展[J]. 硅酸盐通报, 2021, 40(6): 1832-1843.
[13]	王瑜玲, 王春福, 张飞燕. 3D打印混凝土性能要求及相关外加剂研究进展[J]. 硅酸盐通报, 2021, 40(6): 1844-1854.
[14]	金源, 徐嘉宾, 孙登田, 陈明旭, 黄永波, 芦令超, 程新. 纳米二氧化硅对白水泥基3D打印材料结构变形、流变及力学性能的影响[J]. 硅酸盐通报, 2021, 40(6): 1855-1862.
[15]	张超, 邓智聪, 汪智斌, 侯泽宇, 贾子健, 王香港, 贾鲁涛, 陈春, 孙正明, 张亚梅, 潘金龙. 纤维对3D打印混凝土打印性能与力学性能的影响[J]. 硅酸盐通报, 2021, 40(6): 1870-1878.