微波辐照煤系高岭土及其吸油性能

硅酸盐通报 ›› 2021, Vol. 40 ›› Issue (2): 527-533.

所属专题：资源综合利用

微波辐照煤系高岭土及其吸油性能

闫雷, 张涛, 黎佳全, 巩柯语, 苗洋, 高峰

太原理工大学材料科学与工程学院,太原 030024

收稿日期:2020-09-15 修回日期:2020-11-06 出版日期:2021-02-15 发布日期:2021-03-10
通讯作者: 高峰,博士,教授。E-mail:sxgaof@163.com;苗洋,博士,副教授。E-mail:miaoyang198781@163.com
作者简介:闫雷(1995—),男,硕士研究生。主要从事无机粉体制备的研究。E-mail:1161039120@qq.com
基金资助:
山西省科技重大专项(20181101004);山西省重点研发计划(201903D321064)

Microwave Irradiated Coal Series Kaolin and Its Oil Absorption Performance

YAN Lei, ZHANG Tao, LI Jiaquan, GONG Keyu, MIAO Yang, GAO Feng

College of Materials Science and Engineering, Taiyuan University of Technology, Taiyuan 030024, China

Received:2020-09-15 Revised:2020-11-06 Online:2021-02-15 Published:2021-03-10

摘要/Abstract

摘要： 以山西煤系高岭土为原料,在1 800 W的功率下对3 g煤系高岭土进行微波辐照,以此提高煤系高岭土的吸油值。利用扫描电镜、X射线衍射仪、红外光谱分析仪、比表面积分析仪等对处理前后样品的形貌和结构进行表征。结果表明,随微波辐照时间的增加,煤系高岭土的吸油值呈先增加后降低的趋势,且在处理时间为17.5 min(最高温度达到1 100 ℃)时吸油值最高,达到74.4 g/100 g,较高岭土原土吸油值提升了61%,此时煅烧高岭土的吸附平均孔径最大且生成了少量的莫来石。随着处理时间的延长,煅烧高岭土出现烧结,导致内部孔隙闭合,吸油值降低。煅烧高岭土的吸油值与其吸附平均孔径以及孔径分布有关,生成少量莫来石对吸油值的提高有促进作用。

关键词: 煤系高岭土, 微波, 吸油值, 吸附孔径

Abstract: As a raw material, Shanxi coal series kaolin (3 g) was processed under the microwave of 1800 W to increase the oil absorption value of coal series kaolin. The morphology and structure of kaolin before and after treatment were analyzed by means of scanning electron microscopy, X-ray diffractometer, infrared spectrum analyzer, and specific surface area analyzer. The results show that the oil absorption value of coal series kaolin increases first and then decreases with the increase of microwave treatment time. The oil absorption value reaches the highest (74.4 g/100 g) when the treatment time is 17.5 min (the highest temperature is 1 100 ℃), which is higher than the original kaolin by 61%. At this time, the adsorption average pore diameter of calcined kaolin is the largest and a small amount of mullite is produced. As the microwave process time increasing, the calcined kaolin sinters, which causes the closure of internal pores and the decrease of the oil absorption value. The oil absorption value of calcined kaolin is related to its adsorption average pore diameter and pore size distribution, and the production of a small amount of mullite can promote the increase of the oil absorption value.

Key words: coal series kaolin, microwave, oil absorption value, adsorption pore diameter

中图分类号:

TQ174.9

闫雷, 张涛, 黎佳全, 巩柯语, 苗洋, 高峰. 微波辐照煤系高岭土及其吸油性能[J]. 硅酸盐通报, 2021, 40(2): 527-533.

YAN Lei, ZHANG Tao, LI Jiaquan, GONG Keyu, MIAO Yang, GAO Feng. Microwave Irradiated Coal Series Kaolin and Its Oil Absorption Performance[J]. BULLETIN OF THE CHINESE CERAMIC SOCIETY, 2021, 40(2): 527-533.

参考文献

[1] MURRAY H H. Applied clay mineralogy today and tomorrow[J]. Clay Minerals, 1999, 34(1): 39-49.
[2] 陈阳,郭萍,管俊芳,等.高岭土生产消费与国际贸易[J].中国非金属矿工业导刊,2011(3):55-56.
CHEN Y, GUO P, GUAN J F, et al. Kaolin production and consumption and international trade[J]. China Non-Metallic Minerals Industry, 2011(3): 55-56 (in Chinese).
[3] 韦宝玺,孙晓玲.我国煤矸石综合利用现状及对策研究[J].中国国土资源经济,2016,29(4):51-53+72.
WEI B X, SUN X L. The situation China faces in comprehensive utilization of coal gangue and tactful research[J]. Natural Resource Economics of China, 2016, 29(4): 51-53+72 (in Chinese).
[4] 唐靖炎,张韬.中国煤系高岭土加工利用现状与发展[J].新材料产业,2009(3):60-63.
TANG J Y, ZHANG T. Current status and development of processing and utilization of kaolin from coal measures in China[J]. Advanced Materials Industry, 2009(3): 60-63 (in Chinese).
[5] 毕仲平,罗训樵.我国煅烧高岭土行业现状及发展前景[J].非金属矿,2001,24(5):5-6+44.
BI Z P, LUO X Q. Present situation of calcined kaolin industry of China and its development prospect[J]. Non-Metallic Mines, 2001, 24(5): 5-6+44 (in Chinese).
[6] 董圣镯,徐星佩,骆剑军,等.超微细煤系煅烧高岭土改性工艺及其应用[J].中国非金属矿工业导刊,2003(4):12-13+17.
DONG S Z, XU X P, LUO J J, et al. Modification process and application of ultrafine coal-series calcined kaolinite[J]. China Non-Metallic Mining Industry Herald, 2003(4): 12-13+17 (in Chinese).
[7] SIDDIQUI M A, AHMED Z, SALEEMI A A. Evaluation of Swat kaolin deposits of Pakistan for industrial uses[J]. Applied Clay Science, 2005, 29(1): 55-72.
[8] 王玉飞.碱改性高岭土的吸油性能研究[J].榆林学院学报,2011,21(4):82-86.
WANG Y F. Study on oil absorptive properties of alkali-modified kaolin[J]. Journal of Yulin University, 2011, 21(4): 82-86 (in Chinese).
[9] 孙涛,陈洁渝,周春宇,等.煅烧高岭土的比表面积与吸油性能[J].硅酸盐学报,2013,41(5):685-690.
SUN T, CHEN J Y, ZHOU C Y, et al. Specific surface area and oil adsorption of calcinated kaolin clay[J]. Journal of the Chinese Ceramic Society, 2013, 41(5): 685-690 (in Chinese).
[10] REINOSA J J, GARCÍA-BAÑOS B, CATALÁ-CIVERA J M, et al. A step ahead on efficient microwave heating for kaolinite[J]. Applied Clay Science, 2019, 168: 237-243.
[11] MISHRA R R, SHARMA A K. Microwave-material interaction phenomena: heating mechanisms, challenges and opportunities in material processing[J]. Composites Part A: Applied Science and Manufacturing, 2016, 81: 78-97.
[12] CHEN J P, JIA H, LIU Z, et al. Construction of C-Si heterojunction interface in SiC whisker/reduced graphene oxide aerogels for improving microwave absorption[J]. Carbon, 2020, 164: 59-68.
[13] ZHANG A J, MU B, WANG X W, et al. Microwave hydrothermal assisted preparation of CoAl₂O₄/kaolin hybrid pigments for reinforcement coloring and mechanical property of acrylonitrile butadiene styrene[J]. Applied Clay Science, 2019, 175: 67-75.
[14] FAGURY-NETO E, KIMINAMI R H G A. Al₂O₃/mullite/SiC powders synthesized by microwave-assisted carbothermal reduction of kaolin[J]. Ceramics International, 2001, 27(7): 815-819.
[15] 王雪静,张甲敏,李晓波,等.高岭土和煅烧高岭土的微观结构研究[J].中国非金属矿工业导刊,2007(5):18-20.
WANG X J, ZHANG J M, LI X B, et al. Study on the microstucture of kaolin and kaolin fired[J]. China Non-Metallic Mining Industry Herald, 2007(5): 18-20 (in Chinese).
[16] 王时晨,胡永莉,王展志,等.烧结温度对煤系高岭土制备堇青石陶瓷的影响[J].人工晶体学报,2018,47(12):2648-2654.
WANG S C, HU Y L, WANG Z Z, et al. Effect of sintering temperature on cordierite ceramics prepared from coal series kaolin[J]. Journal of Synthetic Crystals, 2018, 47(12): 2648-2654 (in Chinese).
[17] GABRIEL C, GABRIEL S, GRANT E H, et al. Dielectric parameters relevant to microwave dielectric heating[J]. Chemical Society Reviews, 1998, 27(3): 213.
[18] 郑水林,李杨,许霞.温度对煤系煅烧高岭土物化性能影响的研究[J].硅酸盐学报,2003,31(4):417-420.
ZHENG S L, LI Y, XU X. Study of effects of temperature on the physical and chemical properties of calcined kaolinite[J]. Journal of the Chinese Ceramic Society, 2003, 31(4): 417-420 (in Chinese).
[19] 唐武飞,谷晓昱,张胜,等.磷酸二氢钾插层改性高岭土复合物的制备与表征[J].光谱学与光谱分析,2015,35(2):462-465.
TANG W F, GU X Y, ZHANG S, et al. Preparation and characterization of kaolinite-potassium dihydrogen phosphate intercalation composite[J]. Spectroscopy and Spectral Analysis, 2015, 35(2): 462-465 (in Chinese).
[20] NIU S, XIE X, WANG Z, et al. Enhanced removal performance for Congo red by coal-series kaolin with acid treatment[J]. Environmental Technology, 2019: 1-10.
[21] 高琼英,张智强.高岭石矿物高温相变过程及其火山灰活性[J].硅酸盐学报,1989,17(6):541-548.
GAO Q Y, ZHANG Z Q. Study on the structural change in the calcination process of kaolinite and its pozzolanic activity[J]. Journal of the Chinese Ceramic Society, 1989, 17(6): 541-548 (in Chinese).
[22] 魏存弟,马鸿文,杨殿范,等.煅烧煤系高岭石的相转变[J].硅酸盐学报,2005,33(1):77-81.
WEI C D, MA H W, YANG D F, et al. Phase transformation for calcined coal measures kaolinite[J]. Journal of the Chinese Ceramic Society, 2005, 33(1): 77-81 (in Chinese).
[23] 马雪,姚晓,华苏东.原位反应合成多孔莫来石质支撑体及其显微结构(英文)[J].硅酸盐学报,2009,37(10):1777-1781.
MA X, YAO X, HUA S D. Microstructure and synthesis of porous mullite-based support for light-weight proppant by in situ reaction sintering[J]. Journal of the Chinese Ceramic Society, 2009, 37(10): 1777-1781.
[24] 近藤精一,石川达雄,安部郁夫.吸附科学[M].北京:化学工业出版社,2005:30-110.
JINTENG J, SHICHUAN D, ANBU Y. Adsorption science[M]. Beijing: Chemical Industry Press, 2005: 30-110 (in Chinese).

微波辐照煤系高岭土及其吸油性能

Microwave Irradiated Coal Series Kaolin and Its Oil Absorption Performance

PDF (PC)

可视化

摘要/Abstract

引用本文

使用本文

参考文献

相关文章 15

编辑推荐

Metrics

本文评价

[1]	黎佳全, 屈湃, 王倩, 张丰年, 马怡曼, 苗洋, 高峰. 煅烧煤系高岭土吸油性能与颗粒形貌关系研究[J]. 硅酸盐通报, 2022, 41(6): 2031-2038.
[2]	万洋, 余剑英, 何鹏, 曾尚恒. 基于微波加热的热膨胀微球/石蜡/石墨自修复功能材料的制备及其在砂浆中的应用[J]. 硅酸盐通报, 2022, 41(3): 757-765.
[3]	向阳开, 刘威震, 赵毅, 张庆宇, 张艳娟. 钢渣沥青混合料微波加热自愈合性能研究[J]. 硅酸盐通报, 2022, 41(2): 667-677.
[4]	张於亮, 汪振华, 姜志嵩, 张铁. 微波烧结陶瓷结合剂金刚石砂轮研究[J]. 硅酸盐通报, 2022, 41(10): 3675-3679.
[5]	力国民, 苏宁静, 朱保顺, 梁丽萍, 田玉明. 利用煤矸石制备Fe₃O₄和Fe负载的微波吸收材料[J]. 硅酸盐通报, 2021, 40(9): 2998-3004.
[6]	何逸宁, 戴高尚, 吴甲民, 张洁, 潘明珠, 陈敬炎, 陈颖, 王永均, 张红星. 环氧树脂含量对激光选区烧结制备多孔煤系高岭土陶瓷性能的影响[J]. 硅酸盐通报, 2021, 40(6): 1950-1956.
[7]	刘玉召, 蔡宗英, 曹卫刚, 刘洋. 钛酸锌锂微波介质陶瓷研究进展[J]. 硅酸盐通报, 2021, 40(3): 964-969.
[8]	舒国劲, 袁世逢, 庞锦标, 窦占明, 杨俊, 刘凯, 韩光学. ZnO-B₂O₃玻璃对Li₂Zn₃Ti₄O₁₂-CaTiO₃复合陶瓷低温烧结及性能的影响[J]. 硅酸盐通报, 2021, 40(10): 3305-3310.
[9]	闫爽;刘世峰;王冬旭. 煤系高岭土煅烧与微生物提质试验研究[J]. 硅酸盐通报, 2020, 39(4): 1219-1223.
[10]	张涛, 闫雷, 巩柯语, 黎佳全, 何宏伟, 苗洋, 高峰. 超声波辅助插层-剥离法制备煤系高岭土微粉的研究[J]. 硅酸盐通报, 2020, 39(12): 3932-3938.
[11]	冯焱;张绍奇;林志伟;郭荣鑫;郭宁林;陈星宇. 微波辐照下丁二酸对磷石膏制备半水石膏的影响[J]. 硅酸盐通报, 2020, 39(11): 3535-3541.
[12]	严欣堪;丁士华;黄龙;张晓云;李超;朱惠. CaO-B2O3-SiO2玻璃相对BaAl2Si2O8陶瓷结构与介电性能的影响[J]. 硅酸盐通报, 2019, 38(8): 2341-234.
[13]	蒙柳方;袁昌来;覃令灿. CeO2/Ca0.7Bi0.15Na0.15TiO3复合陶瓷微波介电性研究[J]. 硅酸盐通报, 2019, 38(6): 1727-173.
[14]	林聪毅;袁璐;李蔚. MgO/MgF2掺杂对Al2O3陶瓷烧结、显微结构及微波介电性能的影响[J]. 硅酸盐通报, 2019, 38(12): 3845-384.
[15]	赵海鑫;孙莹. 微波加热改性再生骨料试验研究[J]. 硅酸盐通报, 2019, 38(11): 3518-352.