砂岩石质文物灌浆材料的成分设计及多场景应用研究

硅酸盐通报 ›› 2021, Vol. 40 ›› Issue (2): 513-520.

所属专题：资源综合利用

砂岩石质文物灌浆材料的成分设计及多场景应用研究

王晓飞¹, 魏小红¹, 朱建锋¹, 罗宏杰^1,2, 王芬¹, 施佩¹, 张彪¹

1.陕西科技大学材料科学与工程学院,陕西省无机材料绿色制备与功能化重点实验室,西安 710021;
2.上海大学文化遗产保护基础科学研究院,上海 200444

收稿日期:2020-10-20 修回日期:2020-12-15 出版日期:2021-02-15 发布日期:2021-03-10
通讯作者: 朱建锋,博士,教授。E-mail:zhujf@sust.edu.cn
作者简介:王晓飞(1992—),男,硕士研究生。主要从事文物保护研究。E-mail:wangxiaofeihb@163.com
基金资助:
国家重点研发计划(2019YFC1520100)

Composition Design and Multi-Scene Application of Grouting Material for Sandstone Stone Cultural Relics

WANG Xiaofei¹, WEI Xiaohong¹, ZHU Jianfeng¹, LUO Hongjie^1,2, WANG Fen¹, SHI Pei¹, ZHANG Biao¹

1. Shaanxi Key Laboratory of Green Preparation and Functionalization for Inorganic Materials, School of Materials Science and Engineering, Shaanxi University of Science and Technology, Xi'an 710021, China;
2. Institute for the Conservation of Cultural Heritage, Shanghai University, Shanghai 200444, China

Received:2020-10-20 Revised:2020-12-15 Online:2021-02-15 Published:2021-03-10

摘要/Abstract

摘要： 为了制备出性能可调且满足多场景应用的砂岩石质文物灌浆材料,采用四角配料法,以水硬性石灰(NHL2)、硫铝酸盐水泥(SAC)、偏高岭土(MK)和水性环氧树脂(WER)为原料,制备出不同配方的灌浆材料,并对其力学性能、凝结时间、流动性、粘接强度等进行测试分析。结果表明,NHL2和MK含量较高的灌浆材料,抗压强度和粘接强度较低,适用于修复壁画或镶嵌图案。SAC和WER含量较高的灌浆材料,抗压强度和粘接强度较高,适用于修复断崖、悬岩型砂岩石质文物。WER和MK含量较高的灌浆材料,韧性和变形能力良好,适用于修复易受外界应力的砂岩石质文物。

关键词: 砂岩石质文物, 灌浆材料, 四角配料法, 性能调控, 多场景应用

Abstract: In order to prepare a sandstone stone cultural relic grouting material with adjustable properties and meet the requirements of multi-scene application, the four-angle experiment method was adopted. The hydraulic lime (NHL2), sulphoaluminate cement (SAC), metakaolin (MK) and water-based epoxy resin (WER) were used as raw materials to prepared grouting materials with different formulations. Furthermore, the mechanical properties, setting time, fluidity and abonding strength of the grouting material were tested and analyzed. The results indicate that the grouting material with higher content of NHL2 and MK is suitable for repairing murals or mosaic patterns because of its low compressive strength and bonding strength. The grouting material with higher content of SAC and WER has higher compressive strength and bonding strength, which is suitable for repairing cliff and overhanging sandstone stone relics. Besides, the grouting material with higher content of WER and MK has good toughness and deformation ability, and it is suitable for repairing sandstone cultural relics susceptible to external stress.

Key words: sandstone stone cultural relic, grouting material, four-angle experiment method, performance adjustment, multi-scene application

中图分类号:

TB332

王晓飞, 魏小红, 朱建锋, 罗宏杰, 王芬, 施佩, 张彪. 砂岩石质文物灌浆材料的成分设计及多场景应用研究[J]. 硅酸盐通报, 2021, 40(2): 513-520.

WANG Xiaofei, WEI Xiaohong, ZHU Jianfeng, LUO Hongjie, WANG Fen, SHI Pei, ZHANG Biao. Composition Design and Multi-Scene Application of Grouting Material for Sandstone Stone Cultural Relics[J]. BULLETIN OF THE CHINESE CERAMIC SOCIETY, 2021, 40(2): 513-520.

参考文献

[1] KALAGRI A, MILTIADOU-FEZANS A, VINTZILEOU E. Design and evaluation of hydraulic lime grouts for the strengthening of stone masonry historic structures[J]. Materials and Structures, 2010, 43(8): 1135-1146.
[2] 魏涛,汪在芹,韩炜,等.环氧树脂灌浆材料的种类及其在工程中的应用[J].长江科学院院报,2009,26(7):69-72.
WEI T, WANG Z Q, HAN W, et al. Category of epoxy resin grouting materials and its application[J]. Journal of Yangtze River Scientific Research Institute, 2009, 26(7): 69-72 (in Chinese).
[3] 孙鹏,严绍军,窦彦,等.大足石刻砂岩模拟裂隙灌浆试验[J].长江科学院院报,2016,33(6):134-139.
SUN P, YAN S J, DOU Y, et al. Simulation of fracture grouting test for sandstones of Dazu rock carvings[J]. Journal of Yangtze River Scientific Research Institute, 2016, 33(6): 134-139 (in Chinese).
[4] 彭反三.天然水硬性石灰[C]//冶金石灰技术交流会议,武汉:中国石灰协会,2009(3):44-48.
PENG F S. Natural hydraulic limes[C]//Metallurgical Lime Technology Exchange Conference, Wuhan: China Lime Association, 2009(3): 44-48 (in Chinese).
[5] HUGHES J J, CUTHBERT S J. The petrography and microstructure of medieval lime mortars from the west of Scotland: implications for the formulation of repair and replacement mortars[J]. Materials and Structures, 2000, 33(9): 594-600.
[6] ADEL E, BALL R J, CARTER M A, et al. Effect of dewatering on the strength of lime and cement grouting materials[J]. J Am Ceram Soc, 2010, 93(7): 2074-2081.
[7] PAVÍA S, TOOMEY B. Influence of the aggregate quality on the physical properties of natural feebly-hydraulic lime mortars[J]. Materials and Structures, 2008, 41(3): 559-569.
[8] SABBIONI C, ZAPPIA G, RIONTINO C, et al. Atmospheric deterioration of ancient and modern hydraulic mortars[J]. Atmospheric Environment, 2001, 35(3): 539-548.
[9] 沈燕,李雪飘.贝利特活化的研究进展[J].硅酸盐通报,2018,37(2):519-523.
SHEN Y, LI X P. Research progress of belite activation[J]. Bulletin of the Chinese Ceramic Society, 2018, 37(2): 519-523 (in Chinese).
[10] 罗旌旺,卢都友,许涛,等.偏高岭土对硅酸盐水泥浆体干燥收缩行为的影响及机理[J].硅酸盐学报,2011,39(10):1687-1693.
LUO J W, LU D Y, XU T, et al. Effect of metakaolin on drying shrinkage behaviour of Portland cement pastes and its mechanism[J]. Journal of the Chinese Ceramic Society, 2011, 39(10): 1687-1693 (in Chinese).
[11] 王燕谋.硫铝酸盐水泥[M].北京:北京工业大学出版社,1999:174-178.
WANG Y M. Sulphoaluminate cement[M]. Beijing: Beijing University of Technology Press, 1999: 174-178 (in Chinese).
[12] 沈燕,张伟,陈玺,等.硫铝酸盐水泥改性的研究进展[J].硅酸盐通报,2019,38(3):683-687.
SHEN Y, ZHANG W, CHEN X, et al. Research progress of sulfoaluminate cement modification[J]. Bulletin of the Chinese Ceramic Society, 2019, 38(3): 683-687 (in Chinese).
[13] PAVLÍK V, UŽÁKOVÁ M. Effect of curing conditions on the properties of lime, lime-metakaolin and lime-zeolite mortars[J]. Construction and Building Materials, 2016, 102: 14-25.
[14] SONG F, YU Z, YANG F, et al. Strätlingite and calcium hemicarboaluminate hydrate in belite-calcium sulphoaluminate cement[J]. Ceram Silik, 2014, 58(4): 269-274.
[15] 宋彦军.石灰-偏高岭土胶凝材料的制备及其天然矿物纤维改性研究[D].西安:长安大学,2017.
SONG Y J. Study on the preparation of lime-metakaolin cementations material and the modification of them with natural mineral fibers[D]. Xi'an: Chang'an University, 2017 (in Chinese).
[16] SIDDIQUE R, KLAUS J. Influence of metakaolin on the properties of mortar and concrete: a review[J]. Applied Clay Science, 2009, 43(3/4): 392-400.
[17] ZHANG Y R, KONG X M. Correlations of the dispersing capability of NSF and PCE types of superplasticizer and their impacts on cement hydration with the adsorption in fresh cement pastes[J]. Cement and Concrete Research, 2015, 69: 1-9.
[18] TIAN H W, KONG X M, CUI Y, et al. Effects of polycarboxylate superplasticizers on fluidity and early hydration in sulfoaluminate cement system[J]. Construction and Building Materials, 2019, 228: 116711.
[19] MA B, MA M, SHEN X D, et al. Compatibility between a polycarboxylate superplasticizer and the belite-rich sulfoaluminate cement: setting time and the hydration properties[J]. Construction and Building Materials, 2014, 51: 47-54.
[20] VINTZILEOU E. Three-leaf masonry in compression, before and after grouting: a review of literature[J]. International Journal of Architectural Heritage, 2011, 5(4/5): 513-538.
[21] FANG S Q, ZHANG K, ZHANG B J, et al. Evaluation of cement-based grout for reinforcing unsafe rocks of stone carvings at Hangzhou klippe in China[J]. Journal of Materials in Civil Engineering, 2019, 31(2): 05018005.

砂岩石质文物灌浆材料的成分设计及多场景应用研究

Composition Design and Multi-Scene Application of Grouting Material for Sandstone Stone Cultural Relics

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