层状硅酸盐黏土/硅橡胶纳米复合材料的研究进展

硅酸盐通报 ›› 2021, Vol. 40 ›› Issue (2): 493-504.

所属专题：资源综合利用

层状硅酸盐黏土/硅橡胶纳米复合材料的研究进展

赵华华¹, 宋焕玲¹, 陶新姚², 陈革新³, 王爱勤⁴, 丑凌军¹

1.中国科学院兰州化学物理研究所,羰基合成与选择氧化国家重点实验室,兰州 730000;
2.浙江新光饰品有限公司,义乌 322013;
3.义乌市中科院兰州化物所功能材料中心,义乌 322000;
4.中国科学院兰州化学物理研究所,环境材料与生态化学发展中心,甘肃省黏土矿物应用研究重点实验室,兰州 730000

收稿日期:2020-09-10 修回日期:2020-11-30 出版日期:2021-02-15 发布日期:2021-03-10
通讯作者: 陶新姚,教授级高工。E-mail:txy53@163.com;丑凌军,博士,研究员。E-mail:ljchou@licp.cas.cn
作者简介:赵华华(1984—),女,博士研究生。主要从事纳米材料的研究。E-mail:hhzhao@licp.cas.cn
基金资助:
中国科学院青年创新促进会(2017460)

Research Progress on Layered Silicate Clay/Silicone Rubber Nanocomposites

ZHAO Huahua¹, SONG Huanling¹, TAO Xinyao², CHEN Gexin³, WANG Aiqin⁴, CHOU Lingjun¹

1. State Key Laboratory for Oxo Synthesis and Selective Oxidation, Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences, Lanzhou 730000, China;
2. Zhejiang Neoglory Jewelry Co., Ltd., Yiwu 322013, China;
3. Yiwu R&D Center for Functional Materials of LICP, Chinese Academy of Sciences, Yiwu 322000, China;
4. Key Laboratory of Clay Mineral Applied Research of Gansu Province, Center of Eco-materials and Green Chemistry, Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences, Lanzhou 730000, China

Received:2020-09-10 Revised:2020-11-30 Online:2021-02-15 Published:2021-03-10

摘要/Abstract

摘要： 层状硅酸盐黏土因其独特的纳米层状结构在改性硅橡胶高分子材料性能上具有明显的理论优势,其资源丰富、成本低和绿色无污染等特点在实际应用中受到广泛关注。本文综述了近年来层状硅酸盐黏土包括2∶1型结构如蒙脱石、凹凸棒石和1∶1型结构如高岭石、埃洛石等在改性硅橡胶高分子材料机理和性能方面的国内外最新研究进展,指出目前研究的重点主要集中在硅橡胶性能提高方面,如何使层状硅酸盐黏土粒子在硅橡胶基体中达到最佳纳米分散状态,从而获得性能优异的纳米复合材料是研究的难点。同时,展望了层状硅酸盐黏土/硅橡胶纳米复合材料的发展前景,旨在为层状硅酸盐黏土改性和高性能硅橡胶纳米复合材料的研究提供借鉴。

关键词: 层状硅酸盐, 硅橡胶, 纳米复合材料, 分散, 蒙脱石, 凹凸棒石, 高岭石, 埃洛石

Abstract: Layered silicate clay has attracted great attention in improving the properties of silicone rubber due to its unique nano-layered structure, resourceful, low-cost and pollution-free characteristics. Recent advances in the mechanism and properties of silicone rubber nanocomposite materials modified with layered silicate clay including 2∶1 structure such as montmorillonite, attapulgite and 1∶1 structure such as kaolinite and halloysite are reviewed. In this article, the emphasis of the recent studies is pointed out to be the improvement of the performance of silicone rubber. And uniform dispersion of the layered silicate clay particles into silicone rubber matrix is crucial and challenging due to the disparity in hydrophilic and hydrophobic character of the layered silicate clay and the rubber matrix. The development of layered silicate clay/silicone rubber nanocomposites is prospected in order to provide reference for the deep-digging of the modified layered silicate clay and silicone rubber nanocomposites with high performance.

Key words: layered silicate clay, silicone rubber, nanocomposite, dispersion, montmorillonite, attapulgite, kaolinite, halloysite

中图分类号:

O631

赵华华, 宋焕玲, 陶新姚, 陈革新, 王爱勤, 丑凌军. 层状硅酸盐黏土/硅橡胶纳米复合材料的研究进展[J]. 硅酸盐通报, 2021, 40(2): 493-504.

ZHAO Huahua, SONG Huanling, TAO Xinyao, CHEN Gexin, WANG Aiqin, CHOU Lingjun. Research Progress on Layered Silicate Clay/Silicone Rubber Nanocomposites[J]. BULLETIN OF THE CHINESE CERAMIC SOCIETY, 2021, 40(2): 493-504.

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层状硅酸盐黏土/硅橡胶纳米复合材料的研究进展

Research Progress on Layered Silicate Clay/Silicone Rubber Nanocomposites

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