多孔竹炭负载SnO2的制备及其电化学性能研究

摘要/Abstract

摘要： 多孔竹炭为无定形碳,具有丰富的孔结构,孔径分布在1~6 nm之间,且具有较大的孔体积(1.21 cm³/g)。本文以多孔竹炭为载体,采用溶胶-凝胶法制得B₂O₃-SnO₂/C复合材料。SEM和TEM结果显示SnO₂和B₂O₃均匀分布在多孔竹炭表面。多孔竹炭和B₂O₃有效缓冲SnO₂可逆反应的体积变化,提高SnO₂的循环稳定性。将B₂O₃-SnO₂/C复合材料作为负极组装成锂离子半电池,进行电化学性能测试,在1 C(1 C=372 mA/g)倍率下充放电循环200次结束后仍然保留649.9 mAh/g的放电比容量,放电比容量保留率为58.6%。B₂O₃-SnO₂/C复合材料充放电过程受扩散和电容两种行为控制,电容控制的贡献率随着扫描速率的增大而增大。

关键词: B₂O₃-SnO₂/C复合材料, 循环稳定性, 锂离子电池, 负极材料, 多孔竹炭, 溶胶-凝胶法

Abstract: Porous bamboo charcoal is amorphous carbon with abundant pore structure, and the pore size ranges from 1 nm to 6 nm, with a large pore volume (1.21 cm³/g). Using porous bamboo charcoal as the carrier, the B₂O₃-SnO₂/C composite material was prepared by the sol-gel method. SEM and TEM results show that SnO₂ and B₂O₃ are uniformly distributed on the surface of the porous bamboo charcoal. The porous bamboo charcoal and B₂O₃ effectively accommodate the volume change of the reversible reaction of SnO₂ and improve the cycling stability of SnO₂. The lithium-ion batteries were assembled by B₂O₃-SnO₂/C composite materials as anode, and the electrochemical performance was tested. After 200 cycles, the discharge specific capacity still reaches 649.9 mAh/g at 1 C (1 C=372 mA/g) rate, and the discharge specific capacity retention rate is as high as 58.6%. The charge-discharge process of B₂O₃-SnO₂/C porous composites is controlled by diffusion and capacitance behavior, and the contribution rate of capacitance control increases with the increase of scan rate.

Key words: B₂O₃-SnO₂/C composite, cycling stability, lithium-ion battery, anode material, porous bamboo charcoal, sol-gel method

中图分类号:

TQ152

吴洪, 陈前林, 李翠芹. 多孔竹炭负载SnO₂的制备及其电化学性能研究[J]. 硅酸盐通报, 2021, 40(11): 3740-3749.

WU Hong, CHEN Qianlin, LI Cuiqin. Preparation and Electrochemical Performance of SnO₂ Supported on Porous Bamboo Charcoal[J]. BULLETIN OF THE CHINESE CERAMIC SOCIETY, 2021, 40(11): 3740-3749.

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多孔竹炭负载SnO₂的制备及其电化学性能研究

Preparation and Electrochemical Performance of SnO₂ Supported on Porous Bamboo Charcoal

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