MgO含量对微晶玻璃结构及性能的影响

硅酸盐通报 ›› 2021, Vol. 40 ›› Issue (10): 3497-3503.

MgO含量对微晶玻璃结构及性能的影响

彭瑞欣^1,2, 韩韩^1,2, 林鸿剑^3,4, 李筱凡^1,2, 姜宏^1,2,3,4

1.海南大学,海南省特种玻璃重点实验室,海口 570228;
2.海南大学,南海海洋资源利用国家重点实验室,海口 570228;
3.海南海控特玻科技有限公司,澄迈 571924;
4.特种玻璃国家重点实验室,澄迈 571924

收稿日期:2021-04-20 修回日期:2021-05-24 出版日期:2021-10-15 发布日期:2021-11-11
通讯作者: 姜宏,博士,教授。E-mail:jhong63908889@sina.com
作者简介:彭瑞欣(1996—),男,硕士研究生。主要从事盖板玻璃的研究。E-mail:378051139@qq.com
基金资助:
海南省重点研发计划(ZDYF2020015);国家自然科学基金(51761010);海南大学科研平台建设(ZY2019HN09)

Effect of MgO Content on Structure and Properties of Glass-Ceramics

PENG Ruixin^1,2, HAN Han^1,2, LIN Hongjian^3,4, LI Xiaofan^1,2, JIANG Hong^1,2,3,4

1. Special Glass Key Lab of Hainan Province, Hainan University, Haikou 570228;
2. State Key Laboratory of Marine Resource Utilizationin South China Sea, Hainan University, Haikou 570228;
3. HNHT Special Glass Technology Co., Ltd., Chengmai, 571924, China;
4. State Key Laboratory of Special Glass, Chengmai 571924, China

Received:2021-04-20 Revised:2021-05-24 Online:2021-10-15 Published:2021-11-11

摘要/Abstract

摘要： 锂铝硅系微晶玻璃是一种具有优异的光学、力学性能的微晶玻璃材料。本文制备了以透锂长石和二硅酸锂为主晶相的锂铝硅系透明微晶玻璃,并通过DSC、XRD与SEM研究了MgO含量对该微晶玻璃析晶行为及结构的影响,利用维氏硬度、抗弯强度等测试方法研究了MgO含量对该微晶玻璃力学性能的影响。结果表明,当MgO含量(质量分数)从0%增加至3%,基础玻璃的析晶温度从771 ℃降低至729 ℃,析晶能力增强,微晶玻璃的结晶度从62%增加至72%,晶粒尺寸从29 nm增大至33 nm。随着MgO含量的增加,微晶玻璃中会析出β-石英固溶体,抗弯强度增大。

关键词: 锂铝硅系微晶玻璃, 氧化镁, 析晶性能, 透锂长石, 二硅酸锂, β-石英固溶体

Abstract: Li₂O-Al₂O₃-SiO₂ glass-ceramics have excellent optical and mechanical properties. In this paper, the Li₂O-Al₂O₃-SiO₂ transparent glass-ceramics with diorthite and lithium disilicate as the main crystal phase were prepared. The influence of MgO content on the crystallization behavior and structure of glass-ceramics was studied by DSC, XRD and SEM, and the influence of MgO content on the mechanical properties of glass-ceramics was studied by Vickers hardness, bending strength and other test methods. The results show that when the MgO content (mass fraction) increases from 0% to 3%, the crystallization temperature of the basic glass decreases from 771 ℃ to 729 ℃, and the crystallization ability is enhanced, basides, the crystallinity increases from 62% to 72%, and the grain size increases from 29 nm to 33 nm. With the increase of MgO content, β-quartz solid solution precipitates out of the glass-ceramics and the bending strength increases.

Key words: Li₂O-Al₂O₃-SiO₂ glass-ceramics, MgO, crystallizabitity, petalite, lithium disilicate, β-quartz solid solution

中图分类号:

TQ171

彭瑞欣, 韩韩, 林鸿剑, 李筱凡, 姜宏. MgO含量对微晶玻璃结构及性能的影响[J]. 硅酸盐通报, 2021, 40(10): 3497-3503.

PENG Ruixin, HAN Han, LIN Hongjian, LI Xiaofan, JIANG Hong. Effect of MgO Content on Structure and Properties of Glass-Ceramics[J]. BULLETIN OF THE CHINESE CERAMIC SOCIETY, 2021, 40(10): 3497-3503.

参考文献

[1] 刘秀状,黄小凤,马丽萍,等.MgO对黄磷炉渣微晶玻璃析晶影响[J].硅酸盐通报,2018,37(8):2606-2609+2615.
LIU X Z, HUANG X F, MA L P, et al. Effect of MgO on crystallization of yellow phosphorus slag glass-ceramics[J]. Bulletin of the Chinese Ceramic Society, 2018, 37(8): 2606-2609+2615 (in Chinese).
[2] 包镇红,江伟辉,苗立锋,等.MgO/Al₂O₃比对MgO-Al₂O₃-SiO₂系统玻璃分相与析晶的影响[J].材料导报,2018,32(24):4253-4257.
BAO Z H, JIANG W H, MIAO L F, et al. Effect of MgO/Al₂O₃ ratio on phase-separation and crystallization of MgO-Al₂O₃-SiO₂ glass[J]. Materials Review, 2018, 32(24): 4253-4257 (in Chinese).
[3] 程金树,郑伟宏,楼贤春,等.MgO/ZnO对锂铝硅系微晶玻璃性能的影响[J].武汉理工大学学报,2006,28(2):4-6+13.
CHENG J S, ZHENG W H, LOU X C, et al. Influence of MgO/ZnO on the properties of LAS glass-ceramic[J]. Journal of Wuhan University of Technology, 2006, 28(2): 4-6+13 (in Chinese).
[4] 张翠玲,陆雷,王永志,等.不同MgO/Al₂O₃的LMAS系微晶玻璃的显微结构和性能的研究[J].中国陶瓷,2010,46(2):26-29.
ZHANG C L, LU L, WANG Y Z, et al. Effect of different MgO/Al₂O₃ on the microstrcture and properties of lmas glass-ceramics[J]. China Ceramics, 2010, 46(2): 26-29 (in Chinese).
[5] MA J, CHEN C Z, WANG D G, et al. Effect of MgO addition on the crystallization and in vitro bioactivity of glass ceramics in the CaO-MgO-SiO₂-P₂O₅ system[J]. Ceramics International, 2012, 38(8): 6677-6684.
[6] HSIANG H I, YUNG S W, WANG C C. Effects of the addition of alumina on the crystallization, densification and dielectric properties of CaO-MgO-Al₂O₃-SiO₂ glass in the presence of ZrO₂[J]. Ceramics International, 2014, 40(10): 15807-15813.
[7] ZDANIEWSKI W. Crystallization and structure of a MgO-Al₂O₃-SiO₂-TiO₂ glass-ceramic[J]. Journal of Materials Science, 1973, 8(2): 192-202.
[8] LARSEN P H, POULSEN F W, BERG R W. The influence of SiO₂ addition to 2MgO-Al₂O₃-3.3P₂O₅ glass[J]. Journal of Non-Crystalline Solids, 1999, 244(1): 16-24.
[9] 江亿,李元哲,狄洪发.关于透过体系透过率计算方法的探讨[J].太阳能学报,1980,1(2):166-175.
JIANG Y, LI Y Z, DI H F. A research of the method for calculation of the transmittance of partially transparent mediums[J]. Acta Energiae Solaris Sinica, 1980, 1(2): 166-175 (in Chinese).
[10] GUO X Z, CAI X B, SONG J, et al. Crystallization and microstructure of CaO-MgO-Al₂O₃-SiO₂ glass-ceramics containing complex nucleation agents[J]. Journal of Non-Crystalline Solids, 2014, 405: 63-67.
[11] 文潮,吕宝桐.脆性材料抗弯强度分布规律的研究[J].机械科学与技术,1998,17(4):121-123
WEN C, LÜ B T. Research on distribution law of flexural strength of brittle materials[J]. Mechanical Science and Technology, 1998, 17(4): 121-123 (in Chinese)
[12] 刘梦蝶,高婧,王富,等.氧化锆对二硅酸锂玻璃陶瓷力学性能的影响[J].临床口腔医学杂志,2012,28(3):138-141.
LIU M D, GAO J, WANG F, et al. Effect of zirconia content on flexural strength and fracture toughness of dental experimental lithium disilicate glass-ceramic[J]. Journal of Clinical Stomatology, 2012, 28(3): 138-141 (in Chinese).
[13] 钱冬冬,张蕾,骆小平,等.反复烧结对牙科二硅酸锂玻璃陶瓷颜色和透光性的影响[J].华西口腔医学杂志,2015,33(1):50-53.
QIAN D D, ZHANG L, LUO X P, et al. Effect of repeated sintering on the color and translucency of dental lithium disilicate-based glass ceramic[J]. West China Journal of Stomatology, 2015, 33(1): 50-53 (in Chinese).
[14] 林燕喃,林城,陈含德,等.硅锂比对二硅酸锂玻璃陶瓷的结构与性能的影响[J].硅酸盐学报,2019,47(2):255-259.
LIN Y N, LIN C, CHEN H D, et al. Effect of SiO₂/Li₂O ratio on structure and property of lithium disilicate glass-ceramics[J]. Journal of the Chinese Ceramic Society, 2019, 47(2): 255-259 (in Chinese).
[15] 郑欣.二硅酸锂微晶玻璃的制备及力学性能研究[D].哈尔滨:哈尔滨工业大学,2007.
ZHENG X. Preparation and mechanical properties of lithium disilicate glass-ceramics[D]. Harbin: Harbin Institute of Technology, 2007 (in Chinese).
[16] ELLISON A, KICZENSKI T. Alkali-free glass compositions having high thermal and chemical stability: US8598056 B2[P]. 2013-10-03.
[17] CLARK D E. Chemical stability of glass and glass-ceramics[J]. Trans Am Nucl Soc (United States), 1980, 35.
[18] ZHANG Y Q, WANG M T, LI M, et al. The effect of Sm₂O₃ on the chemical stability of borosilicate glass and glass ceramics[J]. Journal of Wuhan University of Technology-Mater Sci Ed, 2014, 29(4): 692-697.
[19] HARTMANN P, REICH M L, LEICHTWEISS T, et al. Transport properties and chemical stability of lisicon-based glass ceramics in contact with lithium[J]. Electrochemical Society, 2012.