燃烧法制备铝酸铜色料的研究

硅酸盐通报 ›› 2021, Vol. 40 ›› Issue (10): 3490-3496.

燃烧法制备铝酸铜色料的研究

程智鹏¹, 刘昆², 徐轶男¹, 方圆¹, 江财水¹, 李豪¹, 于欢³, 包启富², 周健儿²

1.景德镇陶瓷大学艺术文博学院,景德镇 333403;
2.景德镇陶瓷大学材料科学与工程学院,景德镇 333403;
3.景德镇学院人文学院,景德镇 333032

收稿日期:2021-04-25 修回日期:2021-06-20 出版日期:2021-10-15 发布日期:2021-11-11
通讯作者: 刘昆,博士,讲师。E-mail:nishiwodejia@126.com
作者简介:程智鹏(1995—),男,硕士研究生。主要从事陶瓷色釉料、陶瓷科学技术史方面的研究。E-mail:1269272459@qq.com
基金资助:
江西省陶瓷文物遗存保护暨御窑研究协同创新中心项目(JXYY2013);江西省教育厅科学技术研究项目(GJJ209702);景德镇市科技局项目(20201GYZD013-12);中国科学院特种无机涂层重点实验室开放基金项目(ICM-202004)

Preparation of Copper Aluminate Pigment by Combustion Method

CHENG Zhipeng¹, LIU Kun², XU Yinan¹, FANG Yuan¹, JIANG Caishui¹, LI Hao¹, YU Huan³, BAO Qifu², ZHOU Jian’er²

1. School of Art, Culture and Museum, Jingdezhen Ceramic Institute, Jingdezhen 333403, China;
2. School of Materials Science and Engineering,Jingdezhen Ceramic Institute, Jingdezhen 333403, China;
3. School of Humanities, Jingdezhen University, Jingdezhen 333032, China

Received:2021-04-25 Revised:2021-06-20 Online:2021-10-15 Published:2021-11-11

摘要/Abstract

摘要： 以三水合硝酸铜、九水合硝酸铝和甘氨酸为原料,采用燃烧法制备了铝酸铜(CuAl₂O₄)棕色色料。采用SEM、XRD、FT-IR、TG-DTA和UV-Vis等测试手段,研究了煅烧制度和铜铝摩尔比(Cu/Al)对色料物相组成、微观结构、呈色性能的影响。结果表明,当Cu/Al摩尔比为1∶2.4,煅烧温度为1 100 ℃(不进行保温)时,可以得到呈色性能最佳的CuAl₂O₄色料,其色度值为L^*=46.22、a^*=24.43、b^*=27.09。

关键词: CuAl₂O₄, 棕色色料, 燃烧法, 煅烧制度, 呈色性能, 微观结构

Abstract: In this paper, copper nitrate trihydrate, aluminum nitrate nonahydrate and glycine were used as raw materials to prepare CuAl₂O₄ brown pigment by combustion method. The effects of calcination system and Cu/Al molar ratio on phase composition, microstructure, and color performance of the pigment were investigated by means of XRD, FT-IR, TG-DTA and UV-Vis. The results show that when the the calcination temperature is 1 100 ℃ (without heat preservation) and the Cu/Al molar ratio is 1∶2.4, the CuAl₂O₄ pigment with the best color performance is obtained and its chromatic value is L^*=46.22, a^*=24.43, b^*=27.09.

Key words: CuAl₂O₄, brown pigment, combustion method, calcination system, color performance, microstructure

中图分类号:

TQ174.4

程智鹏, 刘昆, 徐轶男, 方圆, 江财水, 李豪, 于欢, 包启富, 周健儿. 燃烧法制备铝酸铜色料的研究[J]. 硅酸盐通报, 2021, 40(10): 3490-3496.

CHENG Zhipeng, LIU Kun, XU Yinan, FANG Yuan, JIANG Caishui, LI Hao, YU Huan, BAO Qifu, ZHOU Jian’er. Preparation of Copper Aluminate Pigment by Combustion Method[J]. BULLETIN OF THE CHINESE CERAMIC SOCIETY, 2021, 40(10): 3490-3496.

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