SnO对SnF2-P2O5-WO3系统玻璃结构和性能的影响

硅酸盐通报 ›› 2021, Vol. 40 ›› Issue (1): 266-270.

所属专题：玻璃

SnO对SnF₂-P₂O₅-WO₃系统玻璃结构和性能的影响

刁金龙^1,2, 于天来³, 莫大洪³, 郑涛^1,2, 郭艳艳¹, 吕景文¹

1.长春理工大学,光电功能材料教育部工程研究中心,长春 130022;
2.长春理工大学,吉林省光学材料与化学科技创新中心,长春 130022;
3.成都光明光电股份有限公司,成都 610100

收稿日期:2020-08-09 修回日期:2020-10-20 出版日期:2021-01-15 发布日期:2021-02-07
通讯作者: 郑涛,博士,副教授。E-mail:zhengtao@cust.edu.cn
作者简介:刁金龙(1995—),男,硕士研究生。主要从事功能玻璃方面的研究。E-mail:1948976541@qq.com
基金资助:
国家重点研发计划(2016YFB0303805);吉林省科技发展计划(20190302006GX)

Effect of SnO on Structure and Performance ofSnF₂-P₂O₅-WO₃ Glass System

DIAO Jinlong^1,2, YU Tianlai³, MO Dahong³, ZHENG Tao^1,2, GUO Yanyan¹, LYU Jingwen¹

1. Engineering Research Center of Optoelectronic Functional Materials,Ministry of Education,Changchun University of Science andTechnology,Changchun 130022,China;
2. Jilin Provincial Science and Technology Innovation Center of Optical Materials andChemistry,Changchun University of Science and Technology,Changchun 130022,China;
3. Chengdu Guangming GlassCompany Limited,Chengdu 610100,China

Received:2020-08-09 Revised:2020-10-20 Online:2021-01-15 Published:2021-02-07

摘要/Abstract

摘要： 封接玻璃具有耐热好、化学稳定性和机械强度高的优点,被大量运用在真空微电子技术及航天和汽车等众多行业领域。磷酸盐玻璃具有低成本、低特征温度、低稳定性等特点,常被用于封接玻璃的制备。本文采用高温熔融法制备了(60-x)SnF₂-xSnO-35P₂O₅-5WO₃(x=0%,5%,10%,15%,20%,质量分数)组成的玻璃,研究了SnO含量对玻璃结构和性能的影响。通过红外光谱表征了玻璃的微观结构,并测定了玻璃的热膨胀系数和特征温度数值。结果表明,组分中添加SnO可以引入非桥氧来改变O/P原子个数比,从而影响玻璃的结构和性能。随着SnO含量的增加,玻璃的特征温度、封接温度和耐水性能提高,热膨胀系数降低。

关键词: 低温封接玻璃, 磷酸盐, 结构, 特征温度, 热膨胀系数, 耐水性

Abstract: Sealing glass is widely used in vacuum microelectronics,aerospace,automobile and other industrial fields due to its good heat resistance,high chemical stability and mechanical strength.Phosphate glass has the characteristics of low cost,low characteristic temperature and low stability,which is often used to prepare sealing glass.The glass with composition of (60-x)SnF₂-xSnO-35P₂O₅-5WO₃ (x=0%,5%,10%,15%,20%,mass fraction) was prepared by high temperature melting method.The effect of SnO content on the structure and performance of the glass was studied.The internal structure of the glass was characterized by IR,and the thermal expansion coefficient and characteristic temperatures of the glass were measured.The results show that the addition of SnO to the composition introduces non-bridging oxygen to change the O/P atomic ratio,thereby affecting the glass structure and performance.With the increase of SnO content,the characteristic temperature,sealing temperature and water resistance of the glass are improved,and the coefficient of thermal expansion decreases.

Key words: low temperature sealing glass, phosphate, structure, characteristic temperature, coefficient of thermal expansion, water resistance

中图分类号:

TQ171.1

刁金龙, 于天来, 莫大洪, 郑涛, 郭艳艳, 吕景文. SnO对SnF₂-P₂O₅-WO₃系统玻璃结构和性能的影响[J]. 硅酸盐通报, 2021, 40(1): 266-270.

DIAO Jinlong, YU Tianlai, MO Dahong, ZHENG Tao, GUO Yanyan, LYU Jingwen. Effect of SnO on Structure and Performance ofSnF₂-P₂O₅-WO₃ Glass System[J]. BULLETIN OF THE CHINESE CERAMIC SOCIETY, 2021, 40(1): 266-270.

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SnO对SnF₂-P₂O₅-WO₃系统玻璃结构和性能的影响

Effect of SnO on Structure and Performance ofSnF₂-P₂O₅-WO₃ Glass System

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