欢迎访问《硅酸盐通报》官方网站,今天是
分享到:

硅酸盐通报 ›› 2018, Vol. 37 ›› Issue (4): 1462-1466.

• • 上一篇    下一篇

鄂尔多斯煤矸石合成A型沸石吸附剂试验研究

夏彬;王晓丽;张艳   

  1. 内蒙古师范大学化学与环境科学学院,呼和浩特,010020
  • 出版日期:2018-04-15 发布日期:2021-01-18
  • 基金资助:
    国家自然科学基金(21567020)%内蒙古自然科学基金(2012MS0619)

Synthesis of Zeolite A Adsorbents by Coal Gangue in Erdos

XIA Bin;WANG Xiao-li;ZHANG Yan   

  • Online:2018-04-15 Published:2021-01-18

摘要: 试验以内蒙古鄂尔多斯煤矸石为原料,采用水热法合成A型沸石吸附剂.以氨氮去除率为指标,通过正交试验考察了焙烧温度、焙烧时间、晶化温度、晶化时间对合成A型沸石的影响并确定了最佳合成条件.结果表明:对A型沸石氨氮去除率的影响顺序为晶化温度>晶化时间>焙烧时间>焙烧温度,最佳合成条件为焙烧温度750℃,焙烧时间2.5 h,晶化温度95 ℃,晶化时间8 h.样品经XRD、SEM、BET表征,得到了形态较佳且结晶度较好的A型沸石,且该产品为良好的吸附剂.

关键词: 煤矸石;水热法;A型沸石;氨氮去除率

Abstract: The zeolite-based adsorbents were synthesized from coal gangue in Erdos by hydrothermal synthesis.The ammonia-nitrogen removal efficiency was regarded as an indicator, the effect of calcinations temperature, calcinations time, crystallization temperature, and crystallization time on the zeolite A was studied by orthogonal test method and the optimum synthesis conditions were determined. The results show that crystallization temperature is the maximal influence factor on the ammonia-nitrogen removal efficiency of zeolite A,followed by the crystallization time and calcinations time,the minimum is calcinations temperature,and the optimum synthesis conditions are as follows,calcinations temperature is 750 ℃,calcinations time is 2.5 h,crystallization temperature is 95 ℃,and crystallization time is 8 h. The XRD,SEM and BET show that the zeolite A with better morphology, higher crystallinity, and it is still a good adsorbent.

Key words: coal gangue;hydrothermal synthesis;zeolite A;ammonia-nitrogen removal efficiency

中图分类号: