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硅酸盐通报 ›› 2017, Vol. 36 ›› Issue (9): 3024-3029.

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MCM-41介孔分子筛合成与改性的研究进展

陈平;王晨;王瑶;阚连宝;林红岩   

  1. 东北石油大学,大庆,163318
  • 出版日期:2017-09-15 发布日期:2021-01-18

Advances in Synthesis and Modification of MCM-41 Mesoporous Molecular Sieve

CHEN Ping;WANG Chen;WANG Yao;KAN Lian-bao;LIN Hong-yan   

  • Online:2017-09-15 Published:2021-01-18

摘要: 简要介绍了MCM-41介孔分子筛的特点,应用和改性原因.综述了MCM-41介孔分子筛的合成方法,主要包括水热合成法,室温合成法,微波合成法等,列出了每种合成方法的优缺点和合成过程中的影响因素,pH值、晶化时间、晶化温度、模板剂的种类及用量等都会对MCM-41介孔分子筛的结构和孔径产生很大影响.阐述了MCM-41介孔分子筛的改性方法,包括金属杂原子取代法,如主族金属、过渡金属、稀土金属等,有机修饰或功能化法,负载型改性法,如负载金属氧化物、无机酸、杂多酸、有机碱、金属的配合物等.最后就MCM-41介孔分子筛的应用前景做了展望.

关键词: MCM-41介孔分子筛;合成方法;影响因素;改性

Abstract: The characteristics , application and modification reasons of MCM-41 mesoporous molecular sieves were introduced .The synthesis of MCM-41 mesoporous molecular sieves , including hydrothermal method, room temperature synthesis method , microwave synthesis method , lists the advantages and disadvantages and influencing factors of synthesis process of each method , pH value , crystallization time , crystallization temperature , and the amount of template will have greatly influence on the structure and pore size of mesoporous molecular sieve MCM-41.Describes the modification methods of MCM-41 mesoporous molecular sieve , including metal heteroatom substitution , such as metal , transition metal and rare earth metals, organic modification or functionalization method , the modified method of load type , load such as metal oxides , inorganic acid, heteropoly acid, alkali and organic metal complexes .Finally, the application prospect of MCM-41 mesoporous molecular sieves is prospected .

Key words: MCM-41 mesoporous molecular sieve;synthesis method;influencing factor;modification

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