欢迎访问《硅酸盐通报》官方网站,今天是

硅酸盐通报 ›› 2017, Vol. 36 ›› Issue (9): 2981-2986.

• • 上一篇    下一篇

前驱物裂解法低温制备碳化硅陶瓷膜

徐慢;王昭;王树林;沈凡;代小元;司马晨欣   

  1. 武汉工程大学材料科学与工程学院,武汉 430074;武汉工程大学节能材料与膜技术研究所,武汉 430074;武汉工程大学材料科学与工程学院,武汉,430074
  • 出版日期:2017-09-15 发布日期:2021-01-18
  • 基金资助:
    湖北省科技支撑计划项目(2014BAA102)%湖北省技术创新专项(2016ACA160)%研究生创新基金(CX2016013)

Preparation of Silicon Carbide Ceramic Membrane in Low Temperature by Precursor Pyrolysis

XU Man;WANG Zhao;WANG Shu-lin;SHEN Fan;DAI Xiao-yuan;SIMA Chen-xin   

  • Online:2017-09-15 Published:2021-01-18

摘要: 将碳化硅(SiC)粉体和一定量聚碳硅烷(polycarbosilane,PCS)、蒸馏水、聚丙烯酰胺(polyacrylamide,PAM)、聚丙烯酸(polypropylene acid,PAA)混合球磨以制备水性SiC浆料并测定了SiC粒子的动电位及粘度;将浆料均匀涂在SiC支撑体上,在1100℃真空条件下烧成,制备了SiC陶瓷膜并测定陶瓷膜的孔径分布及纯水通量及观察其形貌.研究结果表明:涂膜所用的浆料在pH值为11左右时,SiC粒子动电位最大达到-40 mV,浆料表观粘度最小为20 mPa·s,制备的陶瓷膜孔径大小集中在1μm左右,纯水通量达40 m3/(m2·h).

关键词: 碳化硅;聚碳硅烷;孔径分布

Abstract: Silicon carbide ( SiC ) powder and a certain amount of polycarbosilane , distilled water , polyacrylamide ,polypropylene acid were mixed together and milled to prepare the SiC aqueous slurry , while the dynamic potential and viscosity were simultaneously measured after obtaining the as -prepared sample .Then , the slurry was uniformly coated on a SiC support and synthesized under 1100℃in vacuum condition to obtain the SiC ceramic membrane .The pore size distribution ,water flux as well as morphology of the obtained SiC ceramic membrane were carefully tested .The experimental results indicate that the Zeta potential can maximum reach to -40 mV, the apparent viscosity minimum reach to 20 mPa· s, the pore size of the as-prepared ceramic membrane concentrate in the 1μm and the water flux capacity reach to 40 m3/(m2· h) when the pH value of the coating slurry was fixed at 11.

Key words: SiC;polycarbosilane;pore size distribution

中图分类号: