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硅酸盐通报 ›› 2017, Vol. 36 ›› Issue (11): 3648-3652.

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SrAl2O4:Eu2+,Dy3+长余辉荧光材料的原位还原制备及其性能研究

朱聪旭;徐辉;杨圆明;潘超全;梁玮   

  1. 许昌学院新材料与能源学院,河南省微纳米能量储存与转换材料重点实验室,许昌 461000
  • 出版日期:2017-11-15 发布日期:2021-01-18
  • 基金资助:
    河南省教育厅指导项目(15B430009,16B430006)%河南省科技厅基础与前沿项目(162300410036)

In-situ Reduction Preparation and Properties of SrAl2O4:Eu2+,Dy3+ Long-lasting Phosphor Materials

ZHU Cong-xu;XU Hui;YANG Yuan-ming;PAN Chao-quan;LIANG Wei   

  • Online:2017-11-15 Published:2021-01-18

摘要: 以Eu和Dy为激发离子,通过在原料中引入不同比例葡萄糖,在空气气氛条件下,利用葡萄糖的不充分燃烧将Eu3+原位还原为Eu2+,制备出具有Eu2+对应绿光发射的SrAl2 O4基长余辉荧光材料.结果表明:采用该方法制备的荧光粉末其物相主要为SrAl2 O4;添加葡萄糖使得样品的粒径细化且分散均匀;伴随葡萄糖添加量的增加,其发光强度先增后减.该方法解决了采用传统固相反应法制备SrAl2 O4基长余辉荧光材料依赖还原气氛且样品粒径较大难于后期处理等问题,为SrAl2 O4基长余辉荧光材料的进一步应用提供了更大的可能性.

关键词: 荧光材料;长余辉;铝酸锶;原位还原

Abstract: Eu and Dy were used as excited ions,and Eu3+ was in-situ reduced to Eu2+ by insufficient combustion of introducing different amounts of glucose in the substrate material under the air atmosphere, and the SrAl2 O4-based long-lasting phosphor materials with Eu2+ corresponding green emission were prepared. The results show that the phase of the phosphor powder prepared by this method is mainly SrAl2 O4 . Addition of glucose makes the particle size of the sample becomes small and evenly distributed. The fluorescent emission intensity of samples firstly increases and then decreases with the increasing of glucose addition. The problem that the SrAl2 O4 based long-lasting phosphorescent material is prepared by the traditional solid-phase reaction method that depend reduction atmosphere and the particle size is difficult to be post-processed is solved by this method,which provides a greater possibility for the further application of the SrAl2 O4 based long-lasting phosphor.

Key words: phosphor material;long-lasting;strontium aluminate;in-situ reduction

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