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硅酸盐通报 ›› 2016, Vol. 35 ›› Issue (9): 2995-3000.

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油井土、废玻璃基多孔陶瓷的制备及结构表征

李进;尚珊珊;陈艳林   

  1. 湖北工业大学材料与化学工程学院,武汉,430068;湖北工业大学绿色轻工材料湖北省重点实验室,武汉 430068; 湖北工业大学绿色轻质材料与加工协同创新中心,武汉 430068
  • 出版日期:2016-09-15 发布日期:2021-01-18
  • 基金资助:
    国家自然科学基金(51302073);湖北省重点实验室开放基金((2013)2-面上-9);湖北省教育厅重点项目(D20131406)

Preparation and Characterization of Porous Ceramics from Oily Soil and Waste Glass

LI Jin;SHANG Shan-shan;CHEN Yan-lin   

  • Online:2016-09-15 Published:2021-01-18

摘要: 利用油井土、废玻璃作为主要原料,同时以碳酸钙作为造孔剂,通过控制烧结过程,最终制备多孔陶瓷材料,并利用XRD、SEM等对样品进行结构表征。本研究的目的是为了研究油井土、废玻璃、碳酸钙的比例以及烧结温度对孔隙率、机械强度、体积密度、吸水率、微观结构和结晶程度的影响。结果表明样品A3呈现大孔均匀的微观结构,是通过添加35wt%油井土、40wt%废玻璃、20wt%碳酸钙、5wt%硅酸钠在较低的烧结温度下来获得,其孔隙率、抗压强度、抗弯强度、体积密度和吸水率的值分别为52.38%、4.43 MPa、12.59 MPa、1.07 g/cm3和29.56%。并观察到其机械强度、吸水率和微观结构(孔径及孔径分布)有良好的相关性。

关键词: 油井土;废玻璃;多孔陶瓷;碳酸钙

Abstract: The porous ceramics were prepared by controlling the sinter process using the oily soil and waste glass consisting of the silica as the main material , and the limestone as the pore forming substance . The samples were characterized by the XRD , SEM and so on .An objective of this research was to investigate the influences of the amounts of oily soil/waste glass and CaCO 3 as well as of the sintering temperature on the porosity , mechanical strength , bulk density , water absorption , microstructure and crystalline phase .The results show that A 3 homogeneous microstructures of large pores could be obtained at low sintering temperature by adding about 35wt% oily soil, 40wt% waste glass, 20wt% CaCO3, 5wt%sodium silicate, leading to foams presenting porosity , compressive strength, flexural strength, bulk density, and water absorption values of about 52.38%, 4.43 MPa, 12.59 MPa, 1.07 g/cm3 , and 29. 56%, respectively .Good correlations among mechanical strength , water absorption and microstructure ( pore size and distribution ) were observed .

Key words: oily soil;waste glass;porous ceramics;CaCO3

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