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硅酸盐通报 ›› 2016, Vol. 35 ›› Issue (9): 2980-2985.

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改性黄磷水淬渣的制备及其对含砷(Ⅲ)废水吸附性能的研究

王翠翠;万荣惠;王六生;陈秋玲;刘树根;何文豪;董国丽;宁平;郜华萍   

  1. 昆明理工大学环境科学与工程学院,昆明,650500;云南江磷集团股份有限公司,玉溪,652600
  • 出版日期:2016-09-15 发布日期:2021-01-18
  • 基金资助:
    国际科技合作与交流专项(2014DFA91000)

Preparation of Modified Phosphorous Slag and Its Adsorption Performance of As(Ⅲ) from Wastewater

WANG Cui-cui;WAN Rong-hui;WANG Liu-sheng;CHEN Qiu-ling;LIU Shu-gen;HE Wen-hao;DONG Guo-li;Ning Ping;GAO Hua-ping   

  • Online:2016-09-15 Published:2021-01-18

摘要: 采用铁盐溶液浸渍的方法对黄磷水淬渣进行改性,以提高其对废水中As (Ⅲ)的去除效率。考察改性过程中铁盐种类、铁盐浓度、熟化温度及熟化时间四个因素对改性黄磷水淬渣吸附砷性能的影响:浸渍铁盐溶液为FeCl3、浓度0.8 mol/L、熟化温度80℃和熟化时间6 h。通过比表面积和孔径测定( BET)、扫描电镜(SEM)和傅里叶红外光谱( FT-IR)对改性前后黄磷水淬渣的表面性能和结构进行表征。在最佳条件下制备的改性黄磷水淬渣比表面积增大、Fe3+和-OH含量升高,对废水中As(Ⅲ)的去除率可达到99.1%。改性后的黄磷水淬渣表面有铁负载,增加了其对废水中As(Ⅲ)的吸附性能。

关键词: 黄磷水淬渣;改性;含砷废水;FeCl3;吸附

Abstract: Phosphorus slag was modified by ferric salts dipping in order to improve the removing efficiency of As(Ⅲ)in wastewater .The effects of the classes and concentrations of ferric salts ,curing temperature , and curing time in the process of modification on the adsorbing capacity for As (Ⅲ) were investigated by using modified phosphorous slag .The optimal preparation conditions are as follows:0.8 mol/L of FeCl 3 dipping , curing temperature 80℃and curing time 6 h.The methods of BET , SEM and FT-IR were used to analyze the difference of surface structure and adsorption performance of the modified and un -modified phosphorous slag .After modification , the specific surface area of phosphorus slag increased , the content of Fe3+and-OH rised, and the removal rate of As (Ⅲ)in wastewater was improved to 99.1%.The surface of modified phosphorous slag with iron load , and adsorbing capacity for As (Ⅲ) in wastewater increased .

Key words: phosphorous slag;modification;wastewater containing Arsenic;FeCl3;adsorption

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