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硅酸盐通报 ›› 2016, Vol. 35 ›› Issue (9): 2922-2924.

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氧化铁纳米材料的制备、表征及磁性研究

杜庆波   

  1. 中国矿业大学化工学院,徐州,221116
  • 出版日期:2016-09-15 发布日期:2021-01-18
  • 基金资助:
    自旋电子与纳米材料安徽省重点实验室开放课题(2014YKF46)

Preparation,Characterization and Magnetic Properties of Iron Oxide Nanomaterials

DU Qing-bo   

  • Online:2016-09-15 Published:2021-01-18

摘要: 采用水热法,以三氯化铁为铁源,以聚乙烯吡咯酮( PVP)和十六烷基三甲基溴化铵( CTAB)为表面活性剂,合成了α-Fe2 O3纳米棒和纳米立方体,并用X-射线衍射仪( XRD)、扫描电子显微镜( SEM)和磁学测量系统( SQUID-VSM)对其进行了表征。结果:以PVP为表面活性剂所制备的α-Fe2 O3纳米材料为平均直径约为70 nm,长度约300 nm纳米棒,以CTAB为表面活性剂所制备的α-Fe2 O3纳米材料为边长700 nm的准立方体,而不加表面活性剂所制备的样品的为无形貌的氧化铁纳米材料;其室温磁化强度和矫顽力分别为Mr 0.07 emu/g, Hc 2300 Oe;Mr 0.2 emu/g, Hc 3600 Oe;Mr 0.15 emu/g, Hc 3100 Oe。结论:表面活性剂对样品的形貌和磁性具有重要影响。

关键词: α-Fe2 O3;纳米材料;水热法;磁学性能

Abstract: Different morphology α-Fe2 O3 nanomaterials were successfully prepared by a facile hydrothermal method with PVP and CTAB as surfactant .The as obtained products were characterized by X-ray diffraction (XRD), scanning electron microscope ( SEM) and magneto-meter ( SQUID-VSM) . The α-Fe2 O3 nanorods and nanocubes can be obtained when used PVP and CTAB as surfactant , respectively , but none-morphology α-Fe2 O3 nanomaterials were synthesized without any surfactant .The results show that the nanorods are 70 nm in diameter and 300 nm in length;the nanocubes are 700 nm in sides.The magnetic investigation shows that the synthesized α-Fe2 O3 nanorod, nanocubes and none-morphology nanomaterials exhibit ferromagnetic property with Mr and Hc 0.07 emu/g, 2300 Oe; 0.2 emu/g, 3600 Oe;0.15 emu/g, 3100 Oe respectively, at room temperature.

Key words: α-Fe2 O3;nanomaterial;hydrothermal method;magnetic property

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