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硅酸盐通报 ›› 2016, Vol. 35 ›› Issue (9): 2860-2865.

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磷石膏在水泥生产中的应用现状与展望

杨志强;陈晴;郭清春;党玉栋;李昕成;钱觉时   

  1. 重庆大学材料科学与工程学院,重庆,400045;云南省建筑结构与新材料企业重点实验室,昆明 650223; 云南省建筑科学研究院,昆明 650223
  • 出版日期:2016-09-15 发布日期:2021-01-18
  • 基金资助:
    国家自然科学基金项目(U1202275);重庆市基础与前沿研究计划项目(cstc2013jj B50002);云南省建筑结构与新材料企业重点实验室2016年开放基金

Current Status and Prospects on Utilization of Phosphogypsum in Cement Production

YANG Zhi-qiang;CHEN Qing;GUO Qing-chun;DANG Yu-dong;LI Xin-cheng;QIAN Jue-shi   

  • Online:2016-09-15 Published:2021-01-18

摘要: 磷石膏( PG)是工业湿法生产磷酸排放出的固体废弃物,在水泥生产中的应用是其资源化利用的主要途径。本文分析了磷石膏用于硅酸盐水泥( OPC)和硫铝酸盐水泥( SAC)生产所面临的问题与挑战,重点分析了磷石膏在硫铝酸盐水泥生产中的应用前景。磷石膏作水泥原料时可为硅酸盐水泥和硫铝酸盐水泥提供钙质,高温煅烧可以降低杂质对水泥性能的不利影响,但提高磷石膏分解率是需要深入研究的问题。通过过量配入磷石膏可以生产高硫型硫铝酸盐水泥,磷石膏的分解率可以控制在较高水平。作后掺石膏时,磷石膏中杂质可以作为功能组分改善硫铝酸盐水泥凝结时间。因此磷石膏在硫铝酸盐水泥生产中的应用是值得关注的方向。

关键词: 磷石膏;硫铝酸盐水泥;杂质;部分分解

Abstract: Phosphogypsum ( PG) is an industrial by-product generated from the manufacture of phosphoric acid by the wet process .Considering a huge amount of PG discharge , and a wide demand of cement in infrastructure construction , utilizing PG in cement manufacture is an encouraging approach .This paper firstly reviewed the current challenges of using PG in ordinary Portland cement ( OPC ) and calcium sulfoaluminate cement (SAC) manufacturing.Then, the application of using PG in SAC production is discussed as a new promising way to utilize PG .When using PG to produce SAC as one of raw materials , PG can render calcareous material for OPC and SAC production .But the negative impact of impurities in PG on properties of SAC can also be eliminated by the calcination processing . However , further researches are needed to increase the decomposition rate of PG . Sulfate-rich SAC cement can be produced by adding excess PG in raw materials , in that way the decomposition rate of PG can be increased .In addition , the impurities in PG can be used as functional component to modify the setting of SAC .

Key words: phosphogypsum;calcium sulfoaluminate cement;impurity;partially decomposition

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